File name: Pandora61s1_AldineTX_20230915_L2Fit_fwvt1c1d20210909p1-8.txt File generation date: 20230919T031908.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v1d20210909.txt Level 1 file used: Pandora61s1_AldineTX_20230915_L1_smca1c1d20210909p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20230915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0066 492.1274 492.2482 492.3690 492.4897 492.6105 492.7312 492.8519 492.9726 493.0933 493.2140 493.3346 493.4553 493.5759 493.6965 493.8171 493.9376 494.0582 494.1787 494.2992 494.4197 494.5402 494.6607 494.7811 494.9016 495.0220 495.1424 495.2628 495.3831 495.5035 495.6238 495.7441 495.8644 495.9847 496.1050 496.2253 496.3455 496.4657 496.5859 496.7061 496.8263 496.9464 497.0665 497.1867 497.3068 497.4269 497.5469 497.6670 497.7870 497.9070 498.0270 498.1470 498.2670 498.3869 498.5069 498.6268 498.7467 498.8666 498.9864 499.1063 499.2261 499.3459 499.4657 499.5855 499.7053 499.8250 499.9448 500.0645 500.1842 500.3039 500.4235 500.5432 500.6628 500.7824 500.9020 501.0216 501.1411 501.2607 501.3802 501.4997 501.6192 501.7387 501.8582 501.9776 502.0970 502.2165 502.3358 502.4552 502.5746 502.6939 502.8133 502.9326 503.0519 503.1711 503.2904 503.4096 503.5288 503.6481 503.7672 503.8864 504.0056 504.1247 504.2438 504.3629 504.4820 504.6011 504.7201 504.8392 504.9582 505.0772 505.1962 505.3152 505.4341 505.5530 505.6719 505.7908 505.9097 506.0286 506.1474 506.2663 506.3851 506.5039 506.6227 506.7414 506.8602 506.9789 507.0976 507.2163 507.3350 507.4536 507.5723 507.6909 507.8095 507.9281 508.0467 508.1652 508.2837 508.4023 508.5208 508.6392 508.7577 508.8762 508.9946 509.1130 509.2314 509.3498 509.4682 509.5865 509.7048 509.8231 509.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230915T123311.0Z 8658.523044 52 1 25.17 2 84.92 89.45 90.51 86.47 0.00 1 0.00 1 0 22 5.171e-03 5.189e-03 3.645e-04 3.633e-04 2.449493e+04 3.269064e+01 1.441734e+03 -6.000000e+00 3.437134e+02 293.58 -2.00 20.00 -2.00 505.43 0.00e+00 2.281724e-03 1.108794e-05 1.631147e-04 -6.000000e+00 1.584163e-04 293.58 -2.00 20.00 -2.00 500.79 0.00e+00 2.407428e-01 7.532777e-03 1.522719e-01 -6.000000e+00 1.089516e-01 228.55 -2.00 3.24 -2.00 502.36 0.00e+00 9.671 0.011 489.00 513.00 1 2.7546e+00 5.8375e-04 1.9253e-02 -6.0000e+00 8.4861e-03 -3.0923e-02 1.3775e-04 3.6466e-03 -6.0000e+00 2.0711e-03 2.8708e-02 1.5921e-03 4.4782e-05 7.9409e-05 -6.0000e+00 7.9197e-04 -2.1245e-03 1.8171e-04 12 8 8 10 0 0 -21.73 18.78 12.21 -0.00212 0.00892 590 234 1 4 0 42.360 22.71 14.99 18.78 28.87 25.7 971.38 927 557 95 -29 144 365 443 260 249 266 166 57 3 4 170 306 264 15 -15 -81 141 347 373 584 413 106 -234 -369 -483 125 501 558 225 -315 -831 -1030 -673 -283 73 238 429 341 202 3 -153 -303 -77 -265 -612 -786 -386 -95 150 118 -285 -691 -821 -604 -141 559 784 361 190 4 239 126 68 268 87 65 161 54 -65 -497 -901 -996 -724 -340 -113 -24 5 -112 -161 -155 -458 -554 -557 -311 202 458 332 -22 -640 -1045 -982 -525 136 299 114 -13 172 194 -127 -872 -1489 -1589 -1135 -123 552 689 368 59 281 704 1098 1478 1256 362 -277 -475 -130 429 1143 1203 678 242 346 -77 -119 -353 -564 -353 102 422 595 465 -4 -211 -132 -209 -295 -328 -273 -279 -314 -440 -280 49 576 839 620 820 498 87 -27 139 360 445 264 254 270 167 57 3 4 165 298 261 15 -15 -84 147 340 367 576 409 106 -232 -363 -469 127 502 561 230 -307 -830 -1042 -681 -285 73 236 426 341 204 3 -158 -314 -80 -272 -621 -784 -376 -91 142 113 -277 -687 -832 -620 -145 575 809 375 198 4 248 129 69 269 86 64 158 53 -64 -495 -903 -995 -716 -331 -108 -23 5 -107 -155 -150 -449 -548 -553 -308 199 448 325 -22 -629 -1019 -936 -483 121 276 103 -12 155 178 -113 -812 -1445 -1587 -1147 -125 557 697 376 60 290 728 1137 1536 1319 387 -279 -479 -138 448 1172 1227 694 249 357 -80 -123 -365 -581 -361 103 426 604 477 -4 -210 -134 -215 -308 -346 -290 -297 -334 -466 -294 51 593 860 640 SQ 20230915T123336.4Z 8658.523338 52 2 25.13 2 84.83 89.51 90.42 86.53 0.00 1 0.00 1 0 22 5.175e-03 5.179e-03 3.519e-04 3.505e-04 2.420863e+04 3.204734e+01 1.423033e+03 -6.000000e+00 3.439768e+02 293.58 -2.00 20.00 -2.00 505.40 0.00e+00 2.278415e-03 1.064008e-05 1.622395e-04 -6.000000e+00 1.585409e-04 293.58 -2.00 20.00 -2.00 500.73 0.00e+00 2.398713e-01 7.258522e-03 1.482779e-01 -6.000000e+00 1.090442e-01 228.55 -2.00 3.24 -2.00 502.27 0.00e+00 9.544 0.010 489.00 513.00 1 2.7197e+00 5.6229e-04 1.8911e-02 -6.0000e+00 8.4932e-03 -3.0632e-02 1.3213e-04 3.5682e-03 -6.0000e+00 2.0732e-03 3.0284e-02 1.4746e-03 4.3152e-05 8.0374e-05 -6.0000e+00 7.9252e-04 -1.2136e-03 1.6647e-04 12 8 8 10 0 0 -15.61 18.78 11.99 -0.00121 0.00901 590 234 1 4 0 42.360 22.71 14.99 18.78 28.89 25.7 971.56 944 538 140 -68 110 350 446 298 264 239 206 101 21 -9 174 335 247 40 1 -42 75 355 424 591 459 42 -203 -439 -433 83 531 494 216 -270 -830 -993 -670 -239 49 292 343 382 212 26 -130 -305 -97 -207 -628 -808 -456 -115 214 98 -247 -714 -812 -644 -164 464 743 387 176 10 164 118 77 313 123 91 197 102 -66 -467 -920 -962 -730 -358 -110 -19 11 -68 -120 -86 -470 -559 -541 -339 157 434 375 34 -654 -1040 -933 -503 35 311 103 97 254 188 -132 -842 -1482 -1584 -1053 -146 613 754 392 32 262 657 1150 1453 1286 494 -269 -498 -96 463 1124 1191 719 312 369 -65 -107 -306 -519 -288 172 399 667 527 75 -216 -117 -202 -237 -318 -356 -262 -338 -460 -296 42 550 811 665 848 489 130 -65 108 351 455 307 255 246 210 102 21 -9 172 331 248 41 1 -41 74 353 424 592 462 42 -205 -439 -427 80 505 470 208 -266 -840 -1019 -688 -244 49 295 346 387 217 27 -136 -321 -101 -215 -647 -819 -452 -111 206 95 -243 -720 -835 -670 -172 485 777 408 186 10 172 123 79 319 124 91 196 102 -66 -471 -934 -975 -733 -354 -108 -18 11 -66 -117 -84 -467 -561 -544 -340 156 431 372 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