File name: Pandora61s1_AldineTX_20231215_L2Fit_fout2c1d20210909p1-8.txt File generation date: 20240208T114551.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v1d20210909.txt Level 1 file used: Pandora61s1_AldineTX_20231215_L1_smca1c1d20210909p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20231215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0902 305.2311 305.3721 305.5130 305.6539 305.7949 305.9357 306.0766 306.2175 306.3584 306.4992 306.6400 306.7809 306.9217 307.0625 307.2032 307.3440 307.4848 307.6255 307.7662 307.9070 308.0477 308.1884 308.3290 308.4697 308.6103 308.7510 308.8916 309.0322 309.1728 309.3134 309.4540 309.5946 309.7351 309.8756 310.0162 310.1567 310.2972 310.4377 310.5781 310.7186 310.8591 310.9995 311.1399 311.2803 311.4207 311.5611 311.7015 311.8418 311.9822 312.1225 312.2628 312.4031 312.5434 312.6837 312.8240 312.9643 313.1045 313.2447 313.3849 313.5252 313.6654 313.8055 313.9457 314.0859 314.2260 314.3661 314.5062 314.6464 314.7864 314.9265 315.0666 315.2066 315.3467 315.4867 315.6267 315.7667 315.9067 316.0467 316.1867 316.3266 316.4666 316.6065 316.7464 316.8863 317.0262 317.1661 317.3060 317.4458 317.5856 317.7255 317.8653 318.0051 318.1449 318.2847 318.4244 318.5642 318.7039 318.8436 318.9834 319.1231 319.2628 319.4024 319.5421 319.6817 319.8214 319.9610 320.1006 320.2402 320.3798 320.5194 320.6590 320.7985 320.9381 321.0776 321.2171 321.3566 321.4961 321.6356 321.7750 321.9145 322.0539 322.1934 322.3328 322.4722 322.6116 322.7509 322.8903 323.0297 323.1690 323.3083 323.4477 323.5870 323.7262 323.8655 324.0048 324.1440 324.2833 324.4225 324.5617 324.7009 324.8401 324.9793 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231215T144949.5Z 8749.617934 93 1 2.73 2 72.71 131.02 103.54 112.32 0.00 1 0.00 1 0 25 1.311e-01 1.659e-02 1.011e-01 1.342e-02 4.029681e-01 6.892961e-03 4.405661e-03 -6.000000e+00 7.666686e-02 224.27 -2.00 3.24 -2.00 319.21 0.00e+00 3.307783e-03 1.765323e-03 5.032574e-04 -6.000000e+00 3.496884e-03 286.24 -2.00 20.00 -2.00 318.43 0.00e+00 3.315 0.000 302.00 328.00 3 3.1157e+00 1.9219e-02 3.7996e-02 -6.0000e+00 1.8849e-01 1.2213e-01 2.2386e-02 1.9025e-02 -6.0000e+00 2.0512e-01 -1.1029e-01 1.5305e-02 9.7456e-03 -6.0000e+00 1.2288e-01 4.4694e-02 7.8628e-03 3.9903e-03 -6.0000e+00 5.1755e-02 5.2038e-04 5.4732e-04 4.2476e-04 4.6866e-05 -6.0000e+00 3.9702e-03 7.7864e-03 2.4219e-04 12 9 9 12 1 1 -440.29 18.80 1.11 0.00779 0.01190 4 31 1 5 0 543.950 22.71 15.00 18.80 19.92 26.1 939.54 -61132 -40372 -14990 -36174 7758 -58011 33571 -55252 -252 -50003 -14797 -32276 4877 -2829 -25222 27779 -25635 17413 -4053 20100 7420 21814 -11016 13939 -9178 16497 -1850 -3928 1231 -10711 3257 -8031 3974 -7408 2474 -7412 2121 -10645 -2958 3082 3807 4445 1003 5150 1878 4814 -901 5877 -325 7368 -219 7067 3063 2013 6030 1798 5198 1320 5215 -4605 5132 1627 7980 -1551 1621 1708 1709 1022 -1052 3505 -2519 651 -3741 -1245 -1560 335 -2607 -1965 -314 -2010 -2 -1743 -567 -2246 -1285 -2573 365 -1294 -576 282 141 -615 760 -426 -2736 3398 149 860 -2505 1131 -2993 279 979 -1388 439 -1253 -5 -884 87 -851 -173 -14 797 799 1623 -266 -29 -1 29 475 -33 259 856 1999 -80 229 1425 896 1811 1204 421 -92 1542 -322 -840 -217 308 -993 -949 -759 -341 739 -953 -3840 -2295 -686 -1900 253 -3405 895 -3664 -11 -3553 -781 -2183 274 -201 -2544 1922 -3095 1499 -444 1823 766 1978 -1390 1469 -1244 1821 -239 -498 146 -1484 435 -1326 633 -1333 394 -1313 378 -2465 -749 836 1112 1358 326 1638 618 1556 -306 1888 -112 2445 -83 2699 1293 901 2683 849 2410 626 2368 -2291 2443 863 4328 -966 983 990 962 590 -669 2349 -1899 490 -2875 -899 -1049 204 -1536 -1160 -197 -1436 -2 -1501 -512 -2160 -1293 -2742 395 -1446 -633 298 141 -579 682 -391 -2737 3573 177 1091 -3381 1461 -3786 323 1094 -1624 533 -1608 -6 -1231 127 -1326 -281 -23 1266 1218 2342 -378 -41 -1 46 757 -53 408 1312 2947 -115 321 1947 1264 2699 1914 702 -159 2702 -593 -1613 -428 617 -2020 -1924 -1504 -653 1366 -1774 SS 20231215T145401.6Z 8749.620852 96 1 42.98 2 72.02 131.74 102.73 112.74 0.00 1 0.00 1 0 25 9.519e-02 7.585e-03 4.018e-02 4.418e-03 3.981509e-01 2.290256e-03 4.348742e-03 -6.000000e+00 5.564006e-02 224.27 -2.00 3.24 -2.00 319.72 0.00e+00 1.884181e-03 6.657280e-04 3.330690e-04 -6.000000e+00 2.539765e-03 286.24 -2.00 20.00 -2.00 318.94 0.00e+00 3.197 0.000 302.00 328.00 3 2.5154e+00 6.5919e-03 3.6932e-02 -6.0000e+00 1.3679e-01 7.4501e-02 7.7925e-03 1.8869e-02 -6.0000e+00 1.4889e-01 -3.0204e-02 5.6300e-03 9.4301e-03 -6.0000e+00 8.9193e-02 6.4106e-03 2.8884e-03 2.9801e-03 -6.0000e+00 3.7546e-02 1.0712e-03 -1.4624e-03 1.4383e-04 3.9366e-05 -6.0000e+00 2.8838e-03 6.9040e-03 4.8973e-05 11 8 0 10 0 0 99.75 18.83 0.90 0.00690 -0.00409 537 213 1 5 0 80.020 22.71 15.00 18.83 20.09 26.1 940.86 -43317 -11042 -32897 -33704 -26377 -35359 -29523 -40805 -2438 -36272 -1874 -30669 -1211 -18687 6611 -11705 -5333 -2525 -1304 7697 -5241 11593 -3732 9140 -5785 826 -6284 7294 866 1741 -1093 -988 9101 -5354 6982 -3642 5519 -865 4246 -1249 1250 -915 2456 3565 -74 1819 -915 1081 121 3518 -868 3125 -1518 205 902 1919 1401 -324 816 -1176 1120 1808 3528 1098 1356 633 1037 275 1362 -92 164 567 -475 501 -555 434 -1138 1305 -1572 -154 -303 -1451 -1540 -1460 -536 -1226 124 -1043 12 -130 4 -187 1018 457 -233 884 302 166 -958 -145 -1081 945 -360 65 -602 -1349 -852 55 160 -534 27 -22 497 -58 343 555 617 285 315 -189 43 328 -69 443 -166 722 1034 1119 119 729 -264 294 223 59 -347 -259 165 -400 50 -720 -273 -89 296 -1672 -356 -1303 -1279 -895 -1292 -1089 -1812 -84 -1785 -70 -1616 -56 -1181 395 -911 -421 -207 -107 623 -473 925 -347 823 -617 85 -692 700 83 172 -123 -124 1127 -757 877 -515 787 -150 834 -289 310 -245 658 959 -21 505 -260 302 35 1010 -280 1048 -572 80 365 790 588 -137 337 -496 482 839 1707 580 716 321 522 141 729 -56 108 383 -320 318 -328 237 -588 655 -881 -97 -209 -1122 -1280 -1285 -499 -1222 128 -1113 13 -130 4 -161 849 387 -208 876 339 205 -1257 -186 -1305 1031 -381 70 -701 -1672 -1106 75 234 -846 45 -38 816 -90 496 769 859 416 488 -307 70 523 -108 655 -236 1005 1397 1558 180 1153 -449 517 407 114 -704 -550 357 -885 110 -1539 -556 -175 570 SS 20231215T151056.8Z 8749.632601 106 1 43.71 2 69.35 134.73 99.50 114.48 0.00 1 0.00 1 0 25 4.515e-02 5.465e-03 1.186e-02 1.694e-03 3.512862e-01 8.725759e-04 3.848489e-03 -6.000000e+00 2.639312e-02 224.27 -2.00 3.24 -2.00 319.27 0.00e+00 1.114693e-03 2.196649e-04 1.611546e-04 -6.000000e+00 1.204581e-03 286.24 -2.00 20.00 -2.00 318.47 0.00e+00 2.808 0.000 302.00 328.00 3 1.4847e+00 2.4383e-03 3.2460e-02 -6.0000e+00 6.4886e-02 6.2474e-02 2.8394e-03 1.6604e-02 -6.0000e+00 7.0626e-02 -2.5286e-02 1.9287e-03 8.2035e-03 -6.0000e+00 4.2309e-02 5.2063e-03 9.9042e-04 2.4562e-03 -6.0000e+00 1.7809e-02 4.6902e-03 -9.9112e-04 5.5346e-05 3.2027e-05 -6.0000e+00 1.3677e-03 8.9117e-03 1.3390e-04 10 0 0 10 0 0 99.92 18.76 1.06 0.00891 0.00146 1327 526 1 5 0 32.350 22.71 15.02 18.76 20.83 26.1 946.59 -16603 -11468 -14775 -15774 -15810 -18728 -16456 -13930 -6048 -15120 -8271 -17156 -5846 -4709 -4270 -1237 -1976 1783 -92 1793 -566 4615 -897 1552 -3157 49 -1965 -1164 -1163 -1679 -4 -1032 2631 -1996 -57 -2566 430 -329 1043 -215 756 139 -551 578 374 821 -65 439 -287 1647 1180 2035 1788 876 1706 614 858 540 1082 680 1544 1662 2395 651 818 -174 -400 644 626 262 -121 300 -174 -423 -955 -307 -861 442 -654 -727 -717 -1647 -1181 -1158 -651 -815 -339 -211 -118 -74 134 234 504 797 326 850 463 57 -490 -404 -851 601 315 -313 -755 -767 -391 -301 71 -214 -51 -214 225 56 597 480 628 373 -143 -146 1 315 -101 362 -37 681 1131 987 331 243 -226 113 242 -24 -24 -202 240 -468 -255 -422 -247 151 42 -733 -527 -715 -727 -739 -885 -813 -682 -301 -863 -452 -1105 -388 -364 -380 -119 -204 187 -10 204 -67 522 -111 198 -447 7 -280 -157 -152 -225 -1 -165 440 -355 -10 -449 81 -73 250 -60 228 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