File name: Pandora61s1_AldineTX_20240813_L2Fit_fwvt1c7d20240530p1-8.txt File generation date: 20241210T204146.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c7p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v7d20240530.txt Level 1 file used: Pandora61s1_AldineTX_20240813_L1_smca1c7d20240530p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20240813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0304 492.1513 492.2720 492.3928 492.5136 492.6343 492.7551 492.8758 492.9965 493.1172 493.2378 493.3585 493.4791 493.5997 493.7203 493.8409 493.9615 494.0821 494.2026 494.3231 494.4436 494.5641 494.6846 494.8050 494.9254 495.0459 495.1663 495.2866 495.4070 495.5274 495.6477 495.7680 495.8883 496.0086 496.1289 496.2491 496.3694 496.4896 496.6098 496.7300 496.8501 496.9703 497.0904 497.2105 497.3306 497.4507 497.5708 497.6908 497.8109 497.9309 498.0509 498.1709 498.2909 498.4108 498.5307 498.6507 498.7706 498.8904 499.0103 499.1302 499.2500 499.3698 499.4896 499.6094 499.7291 499.8489 499.9686 500.0883 500.2080 500.3277 500.4474 500.5670 500.6867 500.8063 500.9259 501.0455 501.1650 501.2846 501.4041 501.5236 501.6431 501.7626 501.8820 502.0015 502.1209 502.2403 502.3597 502.4791 502.5984 502.7178 502.8371 502.9564 503.0757 503.1950 503.3142 503.4335 503.5527 503.6719 503.7911 503.9103 504.0294 504.1486 504.2677 504.3868 504.5059 504.6250 504.7440 504.8630 504.9821 505.1011 505.2200 505.3390 505.4580 505.5769 505.6958 505.8147 505.9336 506.0524 506.1713 506.2901 506.4089 506.5277 506.6465 506.7653 506.8840 507.0027 507.1214 507.2401 507.3588 507.4775 507.5961 507.7147 507.8333 507.9519 508.0705 508.1891 508.3076 508.4261 508.5446 508.6631 508.7816 508.9000 509.0184 509.1369 509.2553 509.3736 509.4920 509.6104 509.7287 509.8470 509.9653 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240813T120034.5Z 8991.500399 40 1 38.91 2 88.24 74.35 169.17 297.38 0.00 1 0.00 1 0 29 9.654e-03 9.538e-03 1.352e-03 1.344e-03 3.122411e+04 1.261077e+02 1.842784e+03 -6.000000e+00 6.442362e+02 294.65 -2.00 20.00 -2.00 505.50 0.00e+00 6.131855e-03 4.131351e-05 3.600294e-04 -6.000000e+00 2.965040e-04 294.65 -2.00 20.00 -2.00 500.94 0.00e+00 5.818472e-01 2.779050e-02 1.871157e-01 -6.000000e+00 2.035907e-01 229.57 -2.00 3.24 -2.00 502.48 0.00e+00 16.528 0.055 489.00 513.00 1 4.5937e+00 2.1582e-03 3.0675e-02 -6.0000e+00 1.5861e-02 -1.9245e-02 5.0253e-04 4.6193e-03 -6.0000e+00 3.8737e-03 1.5688e-03 5.5004e-03 1.5984e-04 1.8933e-04 -6.0000e+00 1.4785e-03 1.0414e-02 -8.4445e-05 12 9 9 12 1 1 -65.55 17.06 26.09 0.01041 0.04857 71 32 1 4 0 539.730 20.35 14.99 17.06 33.39 30.3 1019.23 -1108 -911 -525 503 1224 2239 1869 1765 1290 836 738 169 -265 -914 -549 -581 280 163 527 265 218 457 979 1534 1217 885 248 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9 12 1 1 75.47 17.06 17.49 0.00338 0.02777 202 87 1 4 0 195.320 20.35 15.02 17.06 33.45 30.2 1019.45 501 260 91 92 536 980 977 814 612 736 479 270 -140 -109 -135 311 174 104 -19 205 246 375 681 867 680 219 -164 -592 -572 -228 127 -102 -63 -594 -825 -753 -667 -121 -72 140 -33 249 195 293 62 -57 64 -121 -515 -1013 -734 -620 -195 -267 -443 -828 -712 -505 84 630 913 604 231 142 415 437 24 372 -75 -95 -44 -164 -274 -505 -861 -1022 -774 -764 -375 -197 0 -48 206 -80 -449 -771 -765 -395 30 896 433 138 -691 -880 -847 -222 509 537 -209 -752 -347 -393 -468 -1061 -1556 -1644 -983 -78 598 362 45 -92 192 916 1665 2224 1862 779 -345 -774 -508 185 1284 1517 1014 644 844 62 -96 -437 -522 -320 183 267 332 172 -130 -181 84 -44 -349 -351 -397 -78 -28 101 -13 83 345 560 503 451 237 85 88 489 910 922 777 585 699 451 252 -130 -100 -124 286 162 99 -19 200 242 371 675 863 681 221 -165 -592 -563 -221 121 -98 -62 -593 -840 -775 -688 -124 -74 143 -34 256 203 308 66 -61 68 -128 -541 -1051 -745 -620 -193 -266 -450 -862 -754 -542 85 634 919 613 236 145 420 438 24 390 -78 -99 -45 -169 -284 -526 -902 -1068 -800 -780 -377 -196 0 -48 205 -80 -456 -789 -783 -402 30 892 432 137 -688 -861 -806 -202 444 454 -175 -626 -290 -337 -418 -995 -1527 -1557 -944 -76 577 353 44 -91 190 906 1643 2203 1870 799 -359 -809 -525 187 1271 1489 998 638 837 62 -97 -439 -522 -318 180 263 330 173 -133 -189 89 -48 -383 -389 -442 -87 -31 112 -14 90 374 608 550 SQ 20240813T120828.6Z 8991.505886 48 1 42.90 2 86.59 75.32 170.59 302.82 0.00 1 0.00 1 0 22 5.567e-03 5.574e-03 3.467e-04 3.453e-04 3.223267e+04 3.274394e+01 1.902300e+03 -6.000000e+00 3.715018e+02 294.65 -2.00 20.00 -2.00 505.45 0.00e+00 3.565517e-03 1.057337e-05 2.299438e-04 -6.000000e+00 1.709879e-04 294.65 -2.00 20.00 -2.00 500.79 0.00e+00 4.800724e-01 7.181775e-03 1.791575e-01 -6.000000e+00 1.174279e-01 229.57 -2.00 3.24 -2.00 502.34 0.00e+00 12.547 0.024 489.00 513.00 1 2.8309e+00 5.5617e-04 2.4323e-02 -6.0000e+00 9.1479e-03 -2.4527e-02 1.3026e-04 4.4653e-03 -6.0000e+00 2.2351e-03 1.6807e-02 3.5930e-03 3.9789e-05 1.1326e-04 -6.0000e+00 8.5242e-04 1.2686e-02 -1.2640e-04 12 8 8 10 0 0 -14.17 17.06 13.64 0.01269 0.03761 666 264 1 4 0 64.400 20.35 15.02 17.06 33.51 30.2 1019.80 825 690 239 113 367 595 615 542 474 276 274 74 -55 -22 117 248 282 5 -28 9 160 405 459 651 437 129 -191 -438 -547 22 426 413 81 -372 -882 -1036 -686 -245 23 179 258 283 150 24 -132 -351 -143 -318 -679 -895 -506 -234 13 71 -381 -759 -816 -624 -141 573 777 423 186 -3 259 190 64 191 60 -27 76 23 -77 -506 -904 -1053 -787 -415 -166 -9 115 83 31 85 -399 -636 -699 -340 188 540 466 42 -733 -1110 -871 -356 336 414 -2 -151 -72 -35 -398 -1058 -1677 -1622 -1080 -77 563 547 239 -41 214 720 1352 1722 1504 427 -416 -770 -415 249 1154 1335 860 460 503 -50 -135 -372 -622 -391 88 333 453 332 -63 -196 -63 -122 -306 -377 -338 -247 -106 -81 -17 113 519 836 648 728 615 218 106 354 586 616 549 480 279 274 73 -54 -21 114 241 277 5 -28 9 155 396 451 641 432 128 -190 -431 -531 21 428 416 78 -363 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