File name: Pandora61s1_AldineTX_20241024_L2Fit_fout2c8d20241003p1-8.txt File generation date: 20241210T214015.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v8d20241003.txt Level 1 file used: Pandora61s1_AldineTX_20241024_L1_smca1c8d20241003p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20241024 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0886 305.2296 305.3705 305.5115 305.6524 305.7933 305.9342 306.0751 306.2160 306.3569 306.4978 306.6386 306.7794 306.9203 307.0611 307.2019 307.3427 307.4834 307.6242 307.7649 307.9057 308.0464 308.1871 308.3278 308.4685 308.6091 308.7498 308.8904 309.0311 309.1717 309.3123 309.4529 309.5934 309.7340 309.8746 310.0151 310.1556 310.2961 310.4366 310.5771 310.7176 310.8581 310.9985 311.1390 311.2794 311.4198 311.5602 311.7006 311.8410 311.9813 312.1217 312.2620 312.4023 312.5426 312.6829 312.8232 312.9635 313.1038 313.2440 313.3842 313.5245 313.6647 313.8049 313.9450 314.0852 314.2254 314.3655 314.5057 314.6458 314.7859 314.9260 315.0661 315.2061 315.3462 315.4862 315.6263 315.7663 315.9063 316.0463 316.1863 316.3262 316.4662 316.6062 316.7461 316.8860 317.0259 317.1658 317.3057 317.4456 317.5854 317.7253 317.8651 318.0049 318.1447 318.2845 318.4243 318.5641 318.7038 318.8436 318.9833 319.1230 319.2627 319.4024 319.5421 319.6818 319.8214 319.9611 320.1007 320.2403 320.3799 320.5195 320.6591 320.7987 320.9382 321.0778 321.2173 321.3568 321.4964 321.6359 321.7753 321.9148 322.0543 322.1937 322.3331 322.4726 322.6120 322.7514 322.8908 323.0301 323.1695 323.3088 323.4482 323.5875 323.7268 323.8661 324.0054 324.1447 324.2839 324.4232 324.5624 324.7016 324.8409 324.9801 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241024T125830.0Z 9063.540625 262 1 42.56 2 84.81 107.09 7.80 218.03 0.00 1 0.00 1 0 25 1.866e-01 8.426e-02 1.552e-01 6.741e-02 6.868520e-01 3.592728e-02 7.552435e-03 -6.000000e+00 1.098171e-01 226.35 -2.00 3.24 -2.00 317.93 0.00e+00 -1.356813e-02 4.614693e-03 1.713753e-03 -6.000000e+00 5.070292e-03 290.44 -2.00 20.00 -2.00 316.62 0.00e+00 9.530 0.010 302.00 328.00 3 -2.5501e-01 9.3897e-02 1.0190e-01 -6.0000e+00 2.7085e-01 2.1001e+00 1.0777e-01 4.6072e-02 -6.0000e+00 2.9429e-01 -1.5653e+00 5.9717e-02 1.5447e-02 -6.0000e+00 1.7645e-01 4.1165e-01 2.7534e-02 1.2624e-02 -6.0000e+00 7.4197e-02 2.0855e-05 -1.8871e-05 1.9963e-03 1.5886e-04 -6.0000e+00 5.6602e-03 6.3814e-03 -2.7714e-04 12 8 8 10 0 0 10.82 17.17 7.20 0.00638 0.00624 49 19 1 5 0 868.390 20.46 15.02 17.17 23.67 30.3 944.21 49591 41823 -2383 11587 -8030 16895 -38038 19529 -29513 25084 971 22001 -147 10420 18085 17136 23553 -7919 16395 -16546 20460 -16652 54267 16572 43619 -12600 8378 -23076 -27505 -4222 -44416 35726 -4449 43729 -36807 30737 -31963 -6087 -10054 25806 23902 28511 37197 19280 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-3717 -2224 6700 -14014 11711 -3100 16495 -133 19035 398 -1755 -3936 7482 3030 3253 11190 1963 11472 3593 12314 -9413 11096 -9976 989 -8661 2534 2561 -6516 11699 416 9269 7053 16316 -5425 14029 -3609 397 -5967 -1598 -1991 -12090 4777 1081 4216 -6538 9033 -22278 -76 -12664 2208 -2237 863 1719 -5475 -7122 -8278 6040 -9997 10118 -6531 5313 3191 5941 11241 SS 20241024T130827.8Z 9063.547544 265 1 42.92 2 82.75 108.40 9.29 229.35 0.00 1 0.00 1 0 25 2.340e-01 3.495e-02 1.032e-01 1.534e-02 7.167216e-01 8.298709e-03 7.736968e-03 -6.000000e+00 1.377254e-01 226.35 -2.00 3.24 -2.00 321.37 0.00e+00 -7.425362e-03 2.874216e-03 4.181015e-04 -6.000000e+00 6.355934e-03 290.44 -2.00 20.00 -2.00 320.58 0.00e+00 7.303 0.005 302.00 328.00 3 2.4082e-01 2.6583e-02 8.0309e-02 -6.0000e+00 3.3969e-01 1.1279e+00 3.1689e-02 3.6834e-02 -6.0000e+00 3.6903e-01 -1.4787e+00 1.7956e-02 1.6257e-02 -6.0000e+00 2.2127e-01 5.9669e-01 9.3046e-03 7.8128e-03 -6.0000e+00 9.3078e-02 1.4015e-04 -4.0882e-03 4.5855e-04 1.1277e-04 -6.0000e+00 7.0953e-03 5.0448e-03 -2.2477e-04 12 8 8 10 0 0 3.79 17.17 2.46 0.00504 -0.02568 210 83 1 5 0 204.340 20.46 15.02 17.17 24.43 30.3 950.23 13646 10598 14684 -14358 21094 -57080 6779 -61930 6466 -55306 -2730 -33634 4425 22509 25642 42840 9978 66210 -5667 78247 -25195 59457 -8331 48671 10823 30817 22874 -17898 -11793 -21820 32036 -42680 56821 -22497 24083 -29448 22940 2299 45535 28030 35490 58984 13213 69730 -7424 58837 -4391 35921 -9335 25098 10738 20278 24267 20139 47717 16165 50003 74 31920 -7885 26680 4092 25689 6296 12494 14046 508 11664 -3753 28369 -523 19749 -3245 14779 -7271 -2220 -18232 -5983 -9188 -11063 5223 -7931 5037 -5172 6054 -4828 6595 -3813 7435 -4772 -2135 -2414 -4590 -1386 -7746 926 -6357 2835 -4947 482 -4914 -535 -5838 -3550 -1801 -4200 1195 -3868 1989 -2649 3556 -2046 2314 -1800 396 -704 -1890 -331 -561 3089 190 5416 379 4618 -159 4682 -82 1414 -255 1032 629 265 1433 -675 801 -1167 1527 -599 277 -779 -807 -650 -1617 1283 1031 1369 -1427 1335 -6710 460 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-6.000000e+00 7.154028e-03 290.43 -2.00 20.00 -2.00 320.62 0.00e+00 5.811 0.002 302.00 328.00 3 1.2843e-01 9.3327e-03 6.5662e-02 -6.0000e+00 3.8246e-01 5.3690e-01 1.1517e-02 3.1904e-02 -6.0000e+00 4.1546e-01 -7.3843e-01 7.8606e-03 1.6699e-02 -6.0000e+00 2.4912e-01 3.1390e-01 3.8595e-03 5.7766e-03 -6.0000e+00 1.0481e-01 7.3131e-04 -3.8513e-03 1.5567e-04 1.2338e-04 -6.0000e+00 7.9867e-03 4.1329e-03 -2.0364e-04 12 8 8 10 0 0 -4.58 17.17 1.80 0.00413 -0.02481 592 235 1 5 0 72.460 20.46 15.02 17.17 25.40 30.3 957.41 -53407 -70803 -58345 -85333 -75188 -98119 -96169 -103619 -74794 -81731 -82200 -50645 -65991 -27244 -35367 -7205 -9213 11226 1124 7556 3694 -5061 -2878 -4527 -2773 -17334 -7644 -34900 -17147 -24814 -3966 740 16394 8878 14129 4858 2849 23120 12943 26605 22655 25402 22879 24138 22203 25976 19642 13606 20047 16666 23652 15078 13157 13238 18555 12618 11349 9795 10529 8516 10848 10254 8254 12430 7833 7776 2843 6411 4500 5715 4045 4565 3177 1262 1295 -2370 -2328 -4260 -5084 -4455 -1902 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