File name: Pandora61s1_AldineTX_20241108_L2Fit_fwvt1c8d20241003p1-8.txt File generation date: 20241210T215919.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v8d20241003.txt Level 1 file used: Pandora61s1_AldineTX_20241108_L1_smca1c8d20241003p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20241108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0336 492.1544 492.2753 492.3961 492.5168 492.6376 492.7583 492.8791 492.9998 493.1205 493.2411 493.3618 493.4825 493.6031 493.7237 493.8443 493.9649 494.0854 494.2060 494.3265 494.4470 494.5675 494.6880 494.8085 494.9289 495.0493 495.1698 495.2901 495.4105 495.5309 495.6512 495.7716 495.8919 496.0122 496.1325 496.2527 496.3730 496.4932 496.6134 496.7336 496.8538 496.9740 497.0941 497.2142 497.3344 497.4545 497.5745 497.6946 497.8147 497.9347 498.0547 498.1747 498.2947 498.4146 498.5346 498.6545 498.7744 498.8943 499.0142 499.1341 499.2539 499.3738 499.4936 499.6134 499.7331 499.8529 499.9727 500.0924 500.2121 500.3318 500.4515 500.5711 500.6908 500.8104 500.9300 501.0496 501.1692 501.2887 501.4083 501.5278 501.6473 501.7668 501.8863 502.0058 502.1252 502.2446 502.3640 502.4834 502.6028 502.7222 502.8415 502.9608 503.0801 503.1994 503.3187 503.4379 503.5572 503.6764 503.7956 503.9148 504.0340 504.1531 504.2723 504.3914 504.5105 504.6296 504.7486 504.8677 504.9867 505.1057 505.2247 505.3437 505.4627 505.5816 505.7006 505.8195 505.9384 506.0572 506.1761 506.2949 506.4138 506.5326 506.6514 506.7701 506.8889 507.0076 507.1264 507.2451 507.3638 507.4824 507.6011 507.7197 507.8384 507.9570 508.0755 508.1941 508.3127 508.4312 508.5497 508.6682 508.7867 508.9051 509.0236 509.1420 509.2604 509.3788 509.4972 509.6156 509.7339 509.8522 509.9705 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241108T144629.3Z 9078.615616 112 1 42.92 2 66.87 127.50 142.19 88.70 0.00 1 0.00 1 0 29 5.729e-03 5.652e-03 1.224e-03 1.218e-03 6.253710e+03 9.316105e+01 3.930801e+02 -6.000000e+00 3.744477e+02 289.09 -2.00 20.00 -2.00 505.20 0.00e+00 6.235475e-04 3.612032e-05 4.730207e-05 -6.000000e+00 1.736764e-04 289.09 -2.00 20.00 -2.00 500.26 0.00e+00 -7.103076e-02 2.582407e-02 4.373094e-02 -6.000000e+00 1.206738e-01 225.41 -2.00 3.24 -2.00 501.85 0.00e+00 2.525 0.000 489.00 513.00 1 6.6333e+00 2.0053e-03 5.2678e-03 -6.0000e+00 9.3836e-03 1.8864e-02 4.8638e-04 1.0092e-03 -6.0000e+00 2.2942e-03 1.7735e-03 3.3081e-03 1.7445e-04 2.0246e-05 -6.0000e+00 8.7659e-04 -8.0893e-03 -2.9378e-05 12 8 8 10 0 0 99.82 17.70 3.75 -0.00809 0.01486 146 58 1 4 0 293.900 20.77 14.98 17.70 31.49 30.8 1002.78 1048 794 270 -176 -56 185 -443 -353 -526 -307 -186 52 -93 66 377 554 787 187 -78 -479 -294 -97 312 401 271 -115 -465 -781 -522 681 1107 998 579 -37 -779 -838 -714 129 196 420 248 33 96 -185 32 -363 105 -407 -372 -203 7 259 973 757 12 -415 -1142 -738 -507 287 506 278 -583 -755 -106 275 220 547 610 486 863 -3 -34 -286 -709 -805 -232 -302 108 80 38 4 -232 356 -174 -111 -518 -44 312 889 594 313 -496 -927 -1072 -1069 44 255 515 237 739 693 264 -470 -1430 -1279 -953 466 1175 850 -85 218 -69 19 272 221 194 -162 -239 -408 -105 259 1039 507 14 -361 317 257 129 -254 -312 50 251 1208 1047 1181 385 -135 -803 -591 -660 -558 -365 -401 -783 -953 -524 -181 1055 1162 1158 1049 750 262 -175 -57 192 -471 -378 -565 -326 -195 54 -95 67 379 557 798 194 -82 -514 -317 -105 337 434 293 -125 -503 -836 -548 694 1111 1002 590 -38 -831 -904 -771 137 207 441 260 35 102 -198 34 -393 112 -433 -389 -208 7 254 940 735 12 -420 -1184 -771 -533 300 530 292 -618 -799 -111 284 224 548 603 477 840 -3 -33 -283 -707 -801 -228 -294 104 77 36 4 -225 346 -171 -109 -517 -43 310 883 595 316 -505 -947 -1087 -1066 43 242 478 218 675 640 249 -457 -1433 -1220 -910 466 1166 848 -81 208 -67 18 266 218 192 -160 -236 -400 -101 247 977 478 13 -342 298 241 121 -238 -290 46 229 1084 942 1067 354 -127 -768 -570 -643 -547 -358 -394 -770 -934 -506 -172 982 1075 1071 SQ 20241108T151155.8Z 9078.633285 132 1 42.70 2 62.64 132.35 136.91 91.63 0.00 1 0.00 1 0 22 8.878e-03 8.777e-03 2.342e-03 2.327e-03 7.785607e+03 1.834715e+02 4.950256e+02 -6.000000e+00 5.802900e+02 289.09 -2.00 20.00 -2.00 505.22 0.00e+00 6.642866e-04 6.940569e-05 4.977029e-05 -6.000000e+00 2.690708e-04 289.09 -2.00 20.00 -2.00 500.18 0.00e+00 -6.212406e-02 4.982017e-02 5.301789e-02 -6.000000e+00 1.867966e-01 225.41 -2.00 3.24 -2.00 501.80 0.00e+00 2.164 0.000 489.00 513.00 1 7.9797e+00 3.8766e-03 5.5455e-03 -6.0000e+00 1.4529e-02 2.2052e-02 9.3282e-04 1.2342e-03 -6.0000e+00 3.5452e-03 4.8394e-04 1.5864e-03 3.2853e-04 1.8228e-05 -6.0000e+00 1.3602e-03 -6.5713e-03 9.8927e-05 12 8 8 10 0 0 65.76 17.73 3.87 -0.00657 0.00443 25 10 1 4 0 1707.540 20.77 14.99 17.73 31.53 30.8 1000.75 385 97 -288 -438 923 958 -237 -455 -993 -620 409 583 -301 -997 260 667 1790 791 -613 -1038 -991 -523 798 1297 298 -320 -1261 -1619 121 1522 1892 -48 1200 -192 -366 -865 -220 693 548 -99 -140 -859 -135 347 513 564 -42 -585 70 324 -1245 -550 611 983 224 -376 -940 -636 -387 -231 1125 590 -1633 -2001 583 542 634 851 901 299 935 -444 -124 432 -772 -484 -122 -858 -953 -36 -272 321 673 723 356 -604 -1078 -301 682 1879 1342 -518 -871 -1289 -1253 -867 1333 1256 -155 -1213 -8 906 327 347 -2366 -2043 -670 1440 1892 226 -523 -402 -454 109 1222 335 1140 292 187 -1306 -689 890 1606 231 -856 -151 83 -162 -714 -358 210 998 792 2203 1188 440 362 -1022 -234 -1251 -1800 -739 98 -870 -264 -661 128 216 431 1042 955 369 94 -285 -445 948 1004 -255 -495 -1085 -671 432 607 -313 -1032 265 679 1822 825 -660 -1134 -1091 -575 869 1407 326 -352 -1389 -1767 127 1555 1904 -49 1230 -203 -394 -944 -238 741 583 -106 -149 -924 -145 373 555 609 -46 -629 74 333 -1271 -549 597 961 224 -384 -981 -671 -409 -245 1179 622 -1657 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3.3818e-03 4.4279e-04 1.5879e-03 3.4722e-04 1.6135e-05 -6.0000e+00 1.2962e-03 -4.5529e-03 5.3516e-05 12 8 8 10 0 0 73.80 17.73 3.67 -0.00455 0.00646 21 8 1 4 0 2002.280 20.77 14.97 17.73 30.35 30.9 992.57 705 -27 -179 478 217 1574 -680 -699 -1189 -497 374 565 -656 -515 251 578 1199 28 -556 -1046 -857 54 755 1175 285 -279 -996 -1427 -67 1515 1551 -249 1760 -154 -523 -937 -412 810 692 76 -598 -743 110 879 521 415 -53 -513 276 -23 -920 -419 652 918 227 -383 -1281 -669 -373 -22 864 435 -1382 -1501 325 678 433 622 636 596 847 -658 -23 89 -633 -375 88 -1064 -772 167 200 990 391 640 -244 -428 -677 -754 494 1882 939 -619 -614 -1279 -1306 -822 1820 672 -178 -1488 332 1138 533 274 -2602 -1815 -446 994 1770 99 -508 566 -159 44 1157 313 918 470 -241 -926 -625 845 1209 291 -1314 -12 13 -249 -688 -72 373 835 1111 2112 908 587 323 -783 -602 -1032 -1755 -366 -108 -743 -248 -547 122 -309 381 1105 896 673 -26 -176 480 224 1636 -734 -760 -1301 -537 396 588 -683 -530 255 588 1226 29 -597 -1143 -942 59 821 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