File name: Pandora61s1_AldineTX_20241204_L2Fit_fout2c1d20210909p1-8.txt File generation date: 20241205T063945.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v1d20210909.txt Level 1 file used: Pandora61s1_AldineTX_20241204_L1_smca1c1d20210909p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20241204 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0902 305.2311 305.3721 305.5130 305.6539 305.7949 305.9357 306.0766 306.2175 306.3584 306.4992 306.6400 306.7809 306.9217 307.0625 307.2032 307.3440 307.4848 307.6255 307.7662 307.9070 308.0477 308.1884 308.3290 308.4697 308.6103 308.7510 308.8916 309.0322 309.1728 309.3134 309.4540 309.5946 309.7351 309.8756 310.0162 310.1567 310.2972 310.4377 310.5781 310.7186 310.8591 310.9995 311.1399 311.2803 311.4207 311.5611 311.7015 311.8418 311.9822 312.1225 312.2628 312.4031 312.5434 312.6837 312.8240 312.9643 313.1045 313.2447 313.3849 313.5252 313.6654 313.8055 313.9457 314.0859 314.2260 314.3661 314.5062 314.6464 314.7864 314.9265 315.0666 315.2066 315.3467 315.4867 315.6267 315.7667 315.9067 316.0467 316.1867 316.3266 316.4666 316.6065 316.7464 316.8863 317.0262 317.1661 317.3060 317.4458 317.5856 317.7255 317.8653 318.0051 318.1449 318.2847 318.4244 318.5642 318.7039 318.8436 318.9834 319.1231 319.2628 319.4024 319.5421 319.6817 319.8214 319.9610 320.1006 320.2402 320.3798 320.5194 320.6590 320.7985 320.9381 321.0776 321.2171 321.3566 321.4961 321.6356 321.7750 321.9145 322.0539 322.1934 322.3328 322.4722 322.6116 322.7509 322.8903 323.0297 323.1690 323.3083 323.4477 323.5870 323.7262 323.8655 324.0048 324.1440 324.2833 324.4225 324.5617 324.7009 324.8401 324.9793 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241204T144651.2Z 9104.615870 96 1 43.02 2 71.79 130.61 107.62 111.11 0.00 1 0.00 1 0 25 8.896e-02 7.468e-03 3.294e-02 3.902e-03 3.832370e-01 2.014777e-03 4.160238e-03 -6.000000e+00 5.197079e-02 224.53 -2.00 3.24 -2.00 319.65 0.00e+00 2.449157e-03 5.766632e-04 1.366377e-04 -6.000000e+00 2.381804e-03 287.01 -2.00 20.00 -2.00 318.85 0.00e+00 3.158 0.000 302.00 328.00 3 2.8928e+00 5.7803e-03 3.6263e-02 -6.0000e+00 1.2780e-01 6.2844e-02 6.8157e-03 1.8391e-02 -6.0000e+00 1.3914e-01 -5.4923e-02 4.8460e-03 9.0341e-03 -6.0000e+00 8.3366e-02 1.8751e-02 2.4847e-03 3.3300e-03 -6.0000e+00 3.5042e-02 7.9205e-04 -1.1286e-03 1.2729e-04 3.9434e-05 -6.0000e+00 2.6960e-03 1.7422e-02 3.5550e-05 11 8 0 10 0 0 99.54 17.27 1.02 0.01742 0.00894 181 72 1 5 0 237.620 21.48 15.00 17.27 21.71 30.2 944.49 -38686 -22101 -33534 -21511 -34444 -40326 -18899 -35257 -15292 -35421 -16247 -19773 667 -13977 -6644 -5354 93 113 4650 4440 -472 4593 -2398 4243 -4872 -755 -3621 572 -6242 180 701 2719 2722 -2716 3627 -5634 1980 -538 1649 488 2640 1057 616 88 1358 1737 2940 725 1157 3952 422 2932 -1117 2884 2519 633 247 1117 1024 704 2338 2323 2795 -208 1592 -141 -391 1249 861 -644 -17 -257 -609 373 -2102 -496 -1755 720 -1006 -977 -888 -1684 -1331 -1610 -144 -1190 -34 -595 146 -511 263 -202 1145 519 698 742 1175 -170 -580 -334 -897 881 35 -45 -1013 -394 -519 -278 -119 -455 69 -136 225 166 665 551 654 107 120 -743 -326 562 278 230 7 922 1477 1128 113 173 -343 291 230 225 -344 -404 368 -306 -351 -383 -227 97 -2 -1605 -851 -1471 -813 -1327 -1626 -680 -1610 -644 -1845 -721 -997 32 -902 -465 -413 7 9 389 385 -44 405 -235 411 -544 -83 -405 59 -673 19 81 344 373 -398 483 -838 303 -97 345 118 684 285 172 25 396 507 844 213 342 1183 141 1029 -424 1110 1008 264 105 465 421 292 1002 1084 1419 -115 861 -74 -198 633 479 -405 -11 -179 -419 241 -1278 -277 -927 371 -576 -637 -635 -1338 -1129 -1451 -137 -1213 -35 -626 155 -521 248 -176 939 435 634 756 1338 -210 -748 -419 -1090 972 38 -50 -1216 -496 -690 -380 -174 -719 114 -229 364 252 942 774 928 155 185 -1205 -529 885 426 348 10 1266 1969 1565 172 282 -580 507 416 427 -696 -852 790 -652 -765 -809 -459 189 -5 SS 20241204T150314.5Z 9104.627251 106 1 3.01 2 69.16 133.50 104.44 112.70 0.00 1 0.00 1 0 17 6.739e-02 1.126e-02 3.428e-02 6.343e-03 3.356300e-01 3.238698e-03 3.753343e-03 -6.000000e+00 3.937430e-02 224.52 -2.00 3.24 -2.00 318.57 0.00e+00 2.540386e-03 6.833763e-04 4.156098e-04 -6.000000e+00 1.804428e-03 287.01 -2.00 20.00 -2.00 317.74 0.00e+00 2.783 0.000 302.00 328.00 3 2.6076e+00 8.7855e-03 3.1893e-02 -6.0000e+00 9.6824e-02 4.1247e-02 1.0097e-02 1.5933e-02 -6.0000e+00 1.0541e-01 -3.0734e-02 6.5371e-03 8.0161e-03 -6.0000e+00 6.3158e-02 1.1019e-02 3.3362e-03 2.8258e-03 -6.0000e+00 2.6553e-02 1.6176e-03 -7.7355e-04 2.0127e-04 3.3142e-05 -6.0000e+00 2.0425e-03 1.4452e-02 -4.8660e-05 12 9 9 12 1 1 -82.18 17.30 1.19 0.01445 0.00864 13 80 1 5 0 214.080 21.48 15.01 17.30 22.81 30.1 952.29 -12400 -16768 6757 -34444 7971 -37709 5947 -32493 -11988 -16076 -13039 -8350 -1770 1745 -6498 14832 -7300 10628 -5806 9479 -5600 8306 -5912 3296 -30 -3069 267 -7864 9241 -9593 6691 -3366 4475 -5269 1568 -4945 582 -517 1260 1385 -1972 4978 -1406 4943 -2711 1141 760 1977 -837 2094 3210 2125 2009 -523 3874 322 590 -857 1408 315 1829 1317 1757 819 978 1522 -1088 3388 -737 902 -1351 738 -808 470 -1821 -383 -117 -369 1751 -1527 58 -4426 -567 -1203 598 -1440 -84 -592 -763 -536 -780 153 635 1991 -283 805 -469 -476 -1134 -492 -1486 320 589 -485 -416 -1471 523 -1253 566 -438 839 602 655 479 721 1056 -663 814 -504 59 -568 1195 109 645 37 660 1476 434 367 88 935 -107 825 -26 59 -423 149 -1043 -789 -608 -556 311 183 -745 -1144 374 -2609 382 -2719 306 -2635 -860 -1246 -1003 -666 -153 169 -778 1611 -1038 1333 -883 1298 -888 1169 -974 529 -5 -555 47 -1425 1393 -1774 1149 -694 917 -1199 322 -1103 136 -142 397 491 -773 1911 -593 1980 -1163 478 317 808 -353 889 1440 1020 1027 -284 2080 180 333 -493 782 179 1072 831 1183 577 680 1006 -716 2162 -520 688 -1120 617 -675 373 -1380 -266 -77 -241 1196 -1187 49 -4153 -547 -1222 630 -1607 -97 -691 -894 -604 -827 152 600 1873 -291 890 -566 -622 -1531 -644 -1877 377 678 -580 -519 -1936 703 -1787 827 -677 1340 959 1015 712 1019 1445 -933 1173 -765 93 -897 1842 165 950 53 906 1981 601 540 137 1496 -177 1379 -45 107 -784 282 -2007 -1505 -1135 -1017 550 322 SS 20241204T150753.5Z 9104.630481 109 1 1.08 2 68.43 134.35 103.55 113.16 0.00 1 0.00 1 0 17 1.387e-01 1.818e-02 1.366e-01 2.110e-02 3.301979e-01 1.077165e-02 3.631420e-03 -6.000000e+00 8.101986e-02 224.52 -2.00 3.24 -2.00 318.39 0.00e+00 5.777292e-03 2.178362e-03 1.079535e-04 -6.000000e+00 3.712837e-03 287.01 -2.00 20.00 -2.00 317.58 0.00e+00 2.695 0.000 302.00 328.00 3 3.4579e+00 2.9037e-02 3.1109e-02 -6.0000e+00 1.9923e-01 8.2907e-02 3.3229e-02 1.6748e-02 -6.0000e+00 2.1690e-01 -3.8736e-02 2.1264e-02 8.1862e-03 -6.0000e+00 1.2996e-01 1.0329e-02 1.0861e-02 5.0959e-03 -6.0000e+00 5.4638e-02 7.3312e-04 -1.0599e-03 6.6563e-04 4.9717e-05 -6.0000e+00 4.2026e-03 1.4507e-02 -4.0296e-05 12 9 9 12 1 1 999.00 17.32 0.75 0.01451 0.00654 1 32 1 5 0 534.250 21.48 15.00 17.32 23.09 30.2 954.09 33685 -14592 85398 -42281 95447 -29995 4077 -15368 -22248 -7644 -19455 40710 -24628 10578 9879 6377 -7326 7339 -806 -3527 -7376 14948 -12695 5196 12783 -6266 12401 -9424 13084 289 3066 -3604 2506 -10532 -741 8490 5884 1412 -7024 5658 -4137 -1654 1164 3045 -3808 -241 -1861 2674 4130 -1405 6949 1998 6010 2105 6776 -861 1295 2851 -438 839 3939 5038 279 -528 -2550 4576 299 -1230 -5689 -1604 -2342 -872 -1968 1059 259 -3657 1413 -1286 549 -1850 251 -2955 95 -1642 -823 1317 -909 361 -2627 -1765 -995 2878 919 3252 1415 1784 2202 -302 -683 633 -1243 1562 256 -58 -868 -2755 -317 -136 -1113 321 1313 391 -2035 -865 2269 1113 -98 -289 1903 -334 651 688 -88 371 1713 -1415 2872 400 -1433 915 -1301 -994 1211 97 -828 -133 1089 -834 -2222 17 759 1697 -875 1522 -1110 2657 -3969 2373 -2276 237 -1155 -1901 -587 -1695 2229 -2835 1038 1123 827 -1146 1058 -131 -604 -1320 2180 -2424 872 2066 -1227 2027 -1817 2025 52 589 -807 569 -2708 -169 1805 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