File name: Pandora61s1_AldineTX_20241224_L2Fit_fwvt1c8d20241003p1-8.txt File generation date: 20241225T063212.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v8d20241003.txt Level 1 file used: Pandora61s1_AldineTX_20241224_L1_smca1c8d20241003p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20241224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0336 492.1544 492.2753 492.3961 492.5168 492.6376 492.7583 492.8791 492.9998 493.1205 493.2411 493.3618 493.4825 493.6031 493.7237 493.8443 493.9649 494.0854 494.2060 494.3265 494.4470 494.5675 494.6880 494.8085 494.9289 495.0493 495.1698 495.2901 495.4105 495.5309 495.6512 495.7716 495.8919 496.0122 496.1325 496.2527 496.3730 496.4932 496.6134 496.7336 496.8538 496.9740 497.0941 497.2142 497.3344 497.4545 497.5745 497.6946 497.8147 497.9347 498.0547 498.1747 498.2947 498.4146 498.5346 498.6545 498.7744 498.8943 499.0142 499.1341 499.2539 499.3738 499.4936 499.6134 499.7331 499.8529 499.9727 500.0924 500.2121 500.3318 500.4515 500.5711 500.6908 500.8104 500.9300 501.0496 501.1692 501.2887 501.4083 501.5278 501.6473 501.7668 501.8863 502.0058 502.1252 502.2446 502.3640 502.4834 502.6028 502.7222 502.8415 502.9608 503.0801 503.1994 503.3187 503.4379 503.5572 503.6764 503.7956 503.9148 504.0340 504.1531 504.2723 504.3914 504.5105 504.6296 504.7486 504.8677 504.9867 505.1057 505.2247 505.3437 505.4627 505.5816 505.7006 505.8195 505.9384 506.0572 506.1761 506.2949 506.4138 506.5326 506.6514 506.7701 506.8889 507.0076 507.1264 507.2451 507.3638 507.4824 507.6011 507.7197 507.8384 507.9570 508.0755 508.1941 508.3127 508.4312 508.5497 508.6682 508.7867 508.9051 509.0236 509.1420 509.2604 509.3788 509.4972 509.6156 509.7339 509.8522 509.9705 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241224T141634.5Z 9124.594844 257 1 1.36 2 79.29 125.10 42.37 200.11 0.00 1 0.00 1 0 22 5.763e-03 5.720e-03 2.235e-03 2.231e-03 9.383249e+03 1.740153e+02 6.069536e+02 -6.000000e+00 3.720407e+02 285.80 -2.00 20.00 -2.00 505.30 0.00e+00 7.888620e-04 6.639151e-05 6.731559e-05 -6.000000e+00 1.732810e-04 285.80 -2.00 20.00 -2.00 500.50 0.00e+00 1.358271e-01 4.690853e-02 6.611889e-02 -6.000000e+00 1.214122e-01 224.29 -2.00 3.24 -2.00 502.10 0.00e+00 5.175 0.002 489.00 513.00 1 4.6173e+00 3.6415e-03 9.4151e-03 -6.0000e+00 9.4307e-03 1.3446e-02 8.7169e-04 1.6000e-03 -6.0000e+00 2.3053e-03 8.9073e-03 1.5335e-05 3.1033e-04 3.2606e-05 -6.0000e+00 8.8219e-04 5.0298e-03 -3.0368e-05 12 9 9 12 1 1 -82.87 18.59 4.54 0.00503 0.00514 7 101 1 4 0 168.760 22.50 15.01 18.59 22.51 30.5 961.01 942 1056 596 62 377 101 71 -76 -95 -226 -152 -125 -7 212 161 414 280 321 -89 -341 -185 172 361 257 198 -29 -289 -719 -314 243 1314 856 595 81 -575 -1054 -736 -482 35 443 352 276 223 185 -416 -803 -447 -612 -700 -588 -61 325 1080 553 -32 -718 -1043 -1223 -354 -408 594 -147 -197 -237 -255 54 -47 455 83 265 656 691 233 -256 -967 -782 -491 277 555 574 395 -168 280 74 -158 -637 -267 57 105 502 15 149 -708 -757 -1038 -693 -197 309 681 579 759 556 -130 -1053 -1881 -1544 -792 58 1187 532 406 137 171 229 289 541 446 3 -398 -87 -2 610 604 788 45 -100 -92 -342 -76 -481 -82 -276 535 583 1140 932 578 -282 -218 -811 -521 156 -21 -209 -691 -717 -760 151 765 1274 1043 897 1009 583 62 388 102 73 -79 -99 -235 -157 -127 -7 210 159 408 279 325 -92 -358 -196 182 383 273 211 -30 -307 -759 -325 246 1299 849 598 84 -605 -1084 -756 -492 36 461 366 288 234 189 -429 -832 -460 -625 -733 -602 -61 318 1039 536 -31 -726 -1077 -1232 -356 -412 596 -148 -200 -240 -256 54 -48 457 83 261 641 673 229 -254 -968 -780 -485 269 533 547 377 -162 270 72 -155 -634 -266 56 104 500 15 149 -693 -767 -1043 -682 -188 288 647 545 711 528 -122 -1022 -1884 -1506 -773 56 1184 515 395 134 170 228 289 544 450 4 -406 -88 -2 599 589 763 43 -97 -90 -334 -74 -467 -78 -264 523 568 1105 912 552 -275 -216 -816 -529 159 -22 -214 -711 -734 -772 151 750 1237 1015 SQ 20241224T142026.9Z 9124.597533 260 1 12.36 2 78.60 125.68 42.68 201.42 0.00 1 0.00 1 0 22 6.094e-03 6.054e-03 1.920e-03 1.913e-03 8.119201e+03 1.493094e+02 5.185613e+02 -6.000000e+00 3.934592e+02 285.80 -2.00 20.00 -2.00 505.28 0.00e+00 9.862487e-04 5.644471e-05 6.947559e-05 -6.000000e+00 1.832329e-04 285.80 -2.00 20.00 -2.00 500.40 0.00e+00 3.147162e-01 4.037322e-02 5.852286e-02 -6.000000e+00 1.283345e-01 224.29 -2.00 3.24 -2.00 501.99 0.00e+00 4.890 0.001 489.00 513.00 1 6.4382e+00 3.1259e-03 8.7179e-03 -6.0000e+00 9.9697e-03 1.8961e-02 7.5382e-04 1.3969e-03 -6.0000e+00 2.4348e-03 1.4814e-03 1.1754e-03 2.7036e-04 3.3552e-05 -6.0000e+00 9.3339e-04 -5.0729e-03 9.1635e-05 12 9 9 12 1 1 99.38 18.58 3.99 -0.00507 0.00308 15 22 1 4 0 771.370 22.50 15.00 18.58 22.60 30.5 962.10 978 768 308 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-534 -597 -183 -247 -95 103 154 -153 148 -18 406 -126 -403 -316 285 756 549 325 -547 -935 -1128 -905 369 654 271 -41 423 873 10 -382 -1978 -1435 -954 576 1520 527 90 -256 -258 -270 605 538 418 382 -319 -243 -19 856 690 745 -436 -213 -424 9 -552 -364 -123 381 536 1249 1280 1106 449 -495 -555 -481 -1049 -485 -403 -742 -808 -528 -398 235 617 1099 990 SQ 20241224T142513.8Z 9124.600854 263 1 3.05 2 77.76 126.40 43.08 203.02 0.00 1 0.00 1 0 22 5.614e-03 5.579e-03 2.314e-03 2.309e-03 8.301697e+03 1.785281e+02 5.312756e+02 -6.000000e+00 3.624759e+02 285.80 -2.00 20.00 -2.00 505.28 0.00e+00 7.804526e-04 6.847479e-05 6.371070e-05 -6.000000e+00 1.688616e-04 285.80 -2.00 20.00 -2.00 500.45 0.00e+00 1.859727e-01 4.854318e-02 5.923994e-02 -6.000000e+00 1.183807e-01 224.29 -2.00 3.24 -2.00 502.05 0.00e+00 4.580 0.001 489.00 513.00 1 5.5508e+00 3.7661e-03 8.3793e-03 -6.0000e+00 9.1936e-03 1.3900e-02 9.0457e-04 1.4151e-03 -6.0000e+00 2.2503e-03 3.8065e-03 2.4576e-03 3.2484e-04 3.0425e-05 -6.0000e+00 8.5875e-04 -6.4496e-04 -8.8561e-05 12 9 9 12 1 1 -5.89 18.59 4.40 -0.00064 0.01640 7 45 1 4 0 380.320 22.50 15.01 18.59 22.78 30.6 963.45 1294 637 189 -105 -290 212 194 -269 -244 -301 -84 314 362 -238 570 209 629 80 -362 -39 101 -161 379 645 -110 -297 -696 -674 -726 737 1437 595 558 -42 -860 -721 -500 33 280 473 2 57 -66 181 131 -196 -626 -354 -222 -924 -266 310 569 627 46 -441 -881 -980 -331 216 887 158 -190 -787 -350 -109 9 264 173 734 461 40 -212 -357 -580 -584 129 -230 122 290 511 0 -2 118 -89 -300 -342 -151 150 677 533 -28 -803 -901 -1093 -1198 23 431 620 567 732 506 50 -781 -1540 -1525 -768 345 1105 687 177 214 -295 -222 192 125 815 291 -73 -55 -88 281 1097 518 -16 55 203 -253 -246 75 -439 -258 230 1101 1105 885 362 -84 -156 -484 -566 -29 -435 -341 -559 -854 -705 -310 736 1008 1231 1240 617 187 -107 -291 216 201 -282 -257 -315 -87 319 363 -238 563 207 628 82 -377 -41 107 -172 404 687 -113 -306 -746 -714 -757 744 1424 594 563 -43 -911 -738 -512 35 294 493 2 60 -70 184 134 -201 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