File name: Pandora61s1_AldineTX_20250327_L2Fit_fout2c8d20241003p1-8.txt File generation date: 20250328T070029.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v8d20241003.txt Level 1 file used: Pandora61s1_AldineTX_20250327_L1_smca1c8d20241003p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20250327 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0886 305.2296 305.3705 305.5115 305.6524 305.7933 305.9342 306.0751 306.2160 306.3569 306.4978 306.6386 306.7794 306.9203 307.0611 307.2019 307.3427 307.4834 307.6242 307.7649 307.9057 308.0464 308.1871 308.3278 308.4685 308.6091 308.7498 308.8904 309.0311 309.1717 309.3123 309.4529 309.5934 309.7340 309.8746 310.0151 310.1556 310.2961 310.4366 310.5771 310.7176 310.8581 310.9985 311.1390 311.2794 311.4198 311.5602 311.7006 311.8410 311.9813 312.1217 312.2620 312.4023 312.5426 312.6829 312.8232 312.9635 313.1038 313.2440 313.3842 313.5245 313.6647 313.8049 313.9450 314.0852 314.2254 314.3655 314.5057 314.6458 314.7859 314.9260 315.0661 315.2061 315.3462 315.4862 315.6263 315.7663 315.9063 316.0463 316.1863 316.3262 316.4662 316.6062 316.7461 316.8860 317.0259 317.1658 317.3057 317.4456 317.5854 317.7253 317.8651 318.0049 318.1447 318.2845 318.4243 318.5641 318.7038 318.8436 318.9833 319.1230 319.2627 319.4024 319.5421 319.6818 319.8214 319.9611 320.1007 320.2403 320.3799 320.5195 320.6591 320.7987 320.9382 321.0778 321.2173 321.3568 321.4964 321.6359 321.7753 321.9148 322.0543 322.1937 322.3331 322.4726 322.6120 322.7514 322.8908 323.0301 323.1695 323.3088 323.4482 323.5875 323.7268 323.8661 324.0054 324.1447 324.2839 324.4232 324.5624 324.7016 324.8409 324.9801 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250327T161337.8Z 9217.676132 202 1 43.47 2 41.48 124.27 40.05 162.77 0.00 1 0.00 1 0 17 1.544e-02 8.242e-03 1.115e-02 5.264e-03 1.879326e-01 2.739966e-03 2.085358e-03 -6.000000e+00 9.158254e-03 228.00 -2.00 3.24 -2.00 316.45 0.00e+00 1.766649e-04 3.247875e-04 6.022116e-05 -6.000000e+00 4.125754e-04 286.66 -2.00 20.00 -2.00 315.66 0.00e+00 1.333 0.000 302.00 328.00 3 5.9821e+00 7.1420e-03 1.6049e-02 -6.0000e+00 2.2708e-02 8.2922e-02 8.0075e-03 8.8986e-03 -6.0000e+00 2.4641e-02 1.8686e-04 4.6058e-03 4.3498e-03 -6.0000e+00 1.4722e-02 -3.1814e-03 2.1035e-03 1.2052e-03 -6.0000e+00 6.1594e-03 2.8178e-04 -1.8281e-04 1.6667e-04 1.6384e-05 -6.0000e+00 4.6799e-04 -1.7512e-03 2.0401e-05 11 8 0 10 0 0 99.06 19.02 1.44 -0.00175 -0.00312 23 9 1 5 0 1889.790 22.90 14.98 19.02 24.13 31.1 1000.52 4093 -4241 4194 -5806 1652 -3216 3196 -3630 -2070 -3578 354 -2544 -531 364 -2759 2916 -1275 3624 1048 1364 -1476 1466 -819 1004 1649 -650 1482 -845 1888 -1654 3342 184 1765 -3951 -274 -3515 -2202 -1614 237 458 -225 455 -1093 508 -422 803 -1348 -87 -2139 -575 859 896 1486 1998 887 -517 592 -975 2064 446 1635 1319 1358 239 42 -750 -222 358 -761 1578 -441 695 -396 677 -1034 -1144 -1324 -1838 -650 -1297 -69 -2704 -433 -1399 187 -1129 875 501 826 249 410 -779 -201 802 -1216 798 -94 1106 469 698 -807 -177 -640 -481 -962 -974 -316 -475 839 444 526 397 526 -410 -110 -546 -460 -156 -501 182 82 1194 525 383 -1063 219 611 883 -6 56 -339 106 229 -100 50 -108 824 -804 -59 -254 343 -104 -590 759 -901 819 -1161 280 -553 545 -729 -443 -800 76 -576 -128 97 -836 892 -418 1166 354 472 -530 511 -297 373 633 -260 570 -313 642 -571 1138 68 675 -1590 -102 -1353 -913 -767 129 280 -149 310 -768 353 -295 549 -915 -56 -1388 -369 565 620 1069 1485 680 -407 466 -774 1575 347 1301 1116 1218 223 38 -642 -177 280 -638 1421 -432 697 -398 651 -945 -955 -1017 -1368 -498 -1097 -63 -2733 -452 -1543 216 -1396 1109 649 1065 310 475 -841 -201 778 -1253 872 -113 1410 621 902 -1001 -206 -729 -567 -1212 -1285 -431 -672 1220 676 821 617 784 -577 -144 -684 -578 -203 -693 263 121 1729 747 525 -1411 275 740 1074 -8 75 -471 149 328 -149 77 -174 1349 -1356 -99 -418 547 -163 -920 SS 20250327T164858.5Z 9217.700677 224 1 11.62 2 35.55 134.81 38.50 176.11 0.00 1 0.00 1 0 17 6.933e-03 5.440e-03 1.472e-03 9.220e-04 1.642060e-01 4.849476e-04 1.829288e-03 -6.000000e+00 4.113680e-03 228.00 -2.00 3.24 -2.00 315.33 0.00e+00 3.049834e-04 4.557197e-05 2.045901e-05 -6.000000e+00 1.852971e-04 286.66 -2.00 20.00 -2.00 314.63 0.00e+00 1.228 0.000 302.00 328.00 3 2.3166e+00 1.2480e-03 1.4530e-02 -6.0000e+00 1.0200e-02 4.6808e-02 1.3906e-03 7.7711e-03 -6.0000e+00 1.1068e-02 6.2069e-04 7.9441e-04 3.7896e-03 -6.0000e+00 6.6124e-03 -3.3872e-03 3.4768e-04 1.0577e-03 -6.0000e+00 2.7671e-03 1.3017e-02 -1.8711e-04 2.8883e-05 1.5373e-05 -6.0000e+00 2.1016e-04 -3.0455e-03 2.0015e-05 12 1 1 12 1 1 81.39 19.05 1.45 -0.00305 -0.00445 193 285 1 5 0 59.840 22.90 15.02 19.05 24.97 31.2 1007.09 -222 -1388 -1477 -2288 -1075 -1356 -275 788 144 -200 -1052 -26 -598 135 -318 -198 370 479 1027 746 937 1043 1108 621 659 -353 -191 -358 582 649 1058 1682 260 -939 -1714 -804 -901 -173 -597 -836 -845 -611 -933 -510 -448 -415 -502 -789 -211 189 460 714 1066 615 834 656 547 685 962 1207 1257 1498 1106 288 -290 -240 -279 596 388 197 24 -48 78 -106 -71 -89 -164 239 -71 -683 -984 -1678 -1184 -937 -622 -640 -430 -217 -324 -25 13 240 705 1038 410 619 594 -20 -360 -636 -523 115 460 -204 -595 -667 -433 -380 -4 -104 -95 -147 34 -44 220 509 458 552 340 40 111 258 177 256 244 335 1171 793 484 179 -191 13 331 195 11 -141 204 -237 -529 -351 -526 -100 -354 -63 -418 -441 -636 -293 -356 -75 235 43 -61 -319 -8 -200 50 -130 -86 163 215 471 351 443 491 530 310 341 -188 -99 -174 263 284 475 790 130 -470 -823 -382 -468 -103 -386 -615 -669 -500 -781 -426 -371 -339 -399 -605 -156 139 350 571 888 534 738 544 457 567 851 1069 1066 1349 1064 288 -283 -215 -251 521 361 188 25 -51 83 -108 -67 -82 -138 191 -59 -631 -930 -1734 -1289 -1072 -704 -773 -543 -281 -417 -31 14 265 712 1015 421 691 676 -24 -464 -802 -619 136 528 -246 -716 -849 -574 -524 -5 -146 -138 -211 47 -60 271 640 576 674 446 55 158 364 244 336 304 425 1416 969 621 224 -250 17 447 273 16 -203 302 -359 -805 -522 -761 -150 -527 SS 20250327T165305.7Z 9217.703538 227 1 12.19 2 34.92 136.22 38.44 177.71 0.00 1 0.00 1 0 17 6.868e-03 5.448e-03 8.572e-04 5.371e-04 1.617005e-01 2.821197e-04 1.799184e-03 -6.000000e+00 4.075369e-03 228.00 -2.00 3.24 -2.00 315.33 0.00e+00 3.579357e-04 2.649713e-05 1.960804e-05 -6.000000e+00 1.835613e-04 286.66 -2.00 20.00 -2.00 314.63 0.00e+00 1.219 0.000 302.00 328.00 3 1.2868e+00 7.2664e-04 1.4385e-02 -6.0000e+00 1.0105e-02 3.8954e-02 8.0950e-04 7.6538e-03 -6.0000e+00 1.0964e-02 1.3925e-03 4.6266e-04 3.7314e-03 -6.0000e+00 6.5507e-03 -3.9092e-03 2.0253e-04 1.0562e-03 -6.0000e+00 2.7415e-03 3.7087e-02 -1.0316e-04 1.6848e-05 1.4987e-05 -6.0000e+00 2.0817e-04 -3.0621e-03 4.0383e-05 12 1 1 12 1 1 96.07 19.06 1.61 -0.00306 -0.00384 586 833 1 5 0 20.440 22.90 14.98 19.06 25.20 31.3 1010.05 -506 -1138 -1835 -2195 -1497 -1223 -171 746 145 -689 -655 -301 -282 386 -37 -114 13 505 965 676 745 1141 1149 860 569 -116 -357 -325 504 819 1093 1415 481 -1142 -1162 -1017 -593 -182 -504 -770 -976 -743 -881 -453 -447 -530 -536 -748 -185 410 610 649 766 646 895 730 547 392 713 1288 1208 1351 1067 283 -159 -369 -154 537 695 10 -88 -166 13 -114 -68 -77 -94 336 -131 -779 -1005 -1569 -1299 -995 -841 -564 -453 -115 -252 6 31 217 763 1034 482 572 620 -63 -384 -568 -620 175 582 -135 -616 -624 -526 -301 59 -136 -160 -202 -55 -54 364 559 542 642 279 -85 95 275 126 214 237 333 1148 839 454 100 -159 54 286 242 -32 -54 171 -230 -479 -431 -538 -143 -258 -144 -343 -551 -611 -411 -322 -47 223 43 -211 -198 -92 -94 142 -15 -49 6 227 442 318 352 536 548 427 294 -61 -185 -158 227 357 489 664 238 -571 -553 -482 -306 -109 -325 -564 -770 -607 -734 -377 -369 -432 -423 -570 -136 299 462 517 637 558 787 652 493 352 629 1135 1104 1213 1022 282 -154 -329 -138 467 641 9 -90 -176 14 -116 -64 -71 -79 267 -109 -717 -946 -1611 -1409 -1134 -949 -677 -571 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