File name: Pandora61s1_AldineTX_20250517_L2Fit_fout2c8d20241003p1-8.txt File generation date: 20250518T063226.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v8d20241003.txt Level 1 file used: Pandora61s1_AldineTX_20250517_L1_smca1c8d20241003p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20250517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0886 305.2296 305.3705 305.5115 305.6524 305.7933 305.9342 306.0751 306.2160 306.3569 306.4978 306.6386 306.7794 306.9203 307.0611 307.2019 307.3427 307.4834 307.6242 307.7649 307.9057 308.0464 308.1871 308.3278 308.4685 308.6091 308.7498 308.8904 309.0311 309.1717 309.3123 309.4529 309.5934 309.7340 309.8746 310.0151 310.1556 310.2961 310.4366 310.5771 310.7176 310.8581 310.9985 311.1390 311.2794 311.4198 311.5602 311.7006 311.8410 311.9813 312.1217 312.2620 312.4023 312.5426 312.6829 312.8232 312.9635 313.1038 313.2440 313.3842 313.5245 313.6647 313.8049 313.9450 314.0852 314.2254 314.3655 314.5057 314.6458 314.7859 314.9260 315.0661 315.2061 315.3462 315.4862 315.6263 315.7663 315.9063 316.0463 316.1863 316.3262 316.4662 316.6062 316.7461 316.8860 317.0259 317.1658 317.3057 317.4456 317.5854 317.7253 317.8651 318.0049 318.1447 318.2845 318.4243 318.5641 318.7038 318.8436 318.9833 319.1230 319.2627 319.4024 319.5421 319.6818 319.8214 319.9611 320.1007 320.2403 320.3799 320.5195 320.6591 320.7987 320.9382 321.0778 321.2173 321.3568 321.4964 321.6359 321.7753 321.9148 322.0543 322.1937 322.3331 322.4726 322.6120 322.7514 322.8908 323.0301 323.1695 323.3088 323.4482 323.5875 323.7268 323.8661 324.0054 324.1447 324.2839 324.4232 324.5624 324.7016 324.8409 324.9801 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250517T130618.3Z 9268.546045 254 1 42.96 2 70.25 78.36 70.44 220.62 0.00 1 0.00 1 0 17 6.357e-02 6.364e-03 3.945e-02 5.052e-03 3.549190e-01 2.665259e-03 3.843806e-03 -6.000000e+00 3.814404e-02 231.04 -2.00 3.24 -2.00 319.56 0.00e+00 1.958252e-03 7.211715e-04 3.683191e-04 -6.000000e+00 1.724790e-03 290.23 -2.00 20.00 -2.00 318.68 0.00e+00 2.926 0.000 302.00 328.00 3 3.2741e+00 7.6630e-03 3.3932e-02 -6.0000e+00 9.5163e-02 2.1599e-02 8.9760e-03 1.7285e-02 -6.0000e+00 1.0296e-01 -2.2976e-02 6.1297e-03 8.4968e-03 -6.0000e+00 6.1494e-02 4.6549e-03 3.1203e-03 2.7253e-03 -6.0000e+00 2.5666e-02 7.0501e-04 -9.4060e-04 1.6676e-04 3.4567e-05 -6.0000e+00 1.9288e-03 -1.6739e-03 5.8931e-05 10 0 0 10 0 0 99.76 18.22 1.28 -0.00167 -0.00874 384 152 1 5 0 111.860 21.69 15.00 18.22 32.27 32.2 1048.62 -10264 -33510 -24042 -24967 -23085 -19397 -23771 -9453 -10852 -17571 -18565 -12930 -13723 -2079 -3253 -1331 -51 2760 7324 2581 5870 702 2497 -1069 51 -4319 -2067 -8348 -1585 -3141 -3083 2809 1616 351 -810 4604 -1990 351 -351 1280 -2818 -724 697 -600 3428 123 737 28 341 -194 1846 1268 1077 141 3660 1552 2082 1602 -369 3644 1483 1891 767 1313 -39 785 -51 339 836 378 435 -335 -66 -864 -68 -240 -706 209 -43 -1214 -62 -1577 -1322 -876 -1287 -362 -838 -62 75 -10 114 343 517 896 290 680 709 -391 -708 -663 -802 355 478 -713 -1034 -1250 -170 -248 212 -18 -183 155 -28 164 266 160 475 611 129 -222 256 490 66 -77 448 504 1440 417 587 53 -289 -64 153 178 93 13 66 -36 -466 -252 -575 273 -193 -384 -1591 -1066 -1169 -978 -774 -1054 -405 -519 -944 -940 -666 -824 -131 -242 -108 -4 246 656 252 565 72 258 -121 6 -551 -256 -1058 -182 -374 -400 381 241 54 -123 666 -339 63 -76 313 -787 -209 205 -182 1005 38 221 9 103 -61 605 451 410 57 1489 662 897 690 -160 1525 661 909 407 735 -22 419 -26 175 464 236 294 -237 -46 -583 -42 -135 -368 107 -24 -763 -44 -1241 -1114 -779 -1230 -366 -893 -67 81 -10 110 303 429 742 259 676 789 -485 -924 -851 -970 394 507 -790 -1228 -1574 -223 -343 312 -29 -305 262 -47 253 383 220 655 881 199 -360 419 787 103 -116 639 687 1888 566 855 84 -484 -111 274 334 185 27 142 -80 -1018 -534 -1176 534 -376 SS 20250517T131649.3Z 9268.553348 257 1 42.99 2 68.01 79.50 71.89 222.49 0.00 1 0.00 1 0 17 3.785e-02 5.834e-03 1.382e-02 2.150e-03 3.219402e-01 1.125714e-03 3.483755e-03 -6.000000e+00 2.271322e-02 231.04 -2.00 3.24 -2.00 319.18 0.00e+00 1.469589e-03 2.733435e-04 2.028060e-04 -6.000000e+00 1.026951e-03 290.23 -2.00 20.00 -2.00 318.28 0.00e+00 2.647 0.000 302.00 328.00 3 2.5162e+00 3.1767e-03 3.0713e-02 -6.0000e+00 5.6666e-02 1.9318e-02 3.6826e-03 1.5676e-02 -6.0000e+00 6.1305e-02 -2.2323e-02 2.4227e-03 7.6161e-03 -6.0000e+00 3.6616e-02 3.7965e-03 1.2289e-03 2.3881e-03 -6.0000e+00 1.5285e-02 2.0703e-03 -3.1419e-04 7.0735e-05 2.9489e-05 -6.0000e+00 1.1483e-03 -2.2411e-03 7.0925e-05 10 0 0 10 0 0 99.94 18.24 1.42 -0.00224 -0.00460 520 206 1 5 0 82.660 21.69 14.99 18.24 32.42 32.3 1049.90 -5209 -16944 -5244 -18226 -10588 -17639 -12293 -11973 -11926 -5044 -12325 -3228 -7314 915 -4470 -794 -3808 -363 -556 722 -160 2322 1490 -1519 1653 -2118 352 -4016 -710 -3547 831 -353 769 -1941 -2232 254 -825 1504 -317 978 -419 426 -439 748 653 1033 -160 -1024 999 -365 1479 344 5110 844 1385 172 542 394 249 1261 1412 2201 1790 1557 112 324 -7 1075 681 374 253 -142 -607 -444 -633 -1017 -688 -891 -342 -1032 -249 -1616 -1317 -1293 -822 -598 -369 44 -102 434 64 489 169 968 267 768 689 -55 -473 -714 -829 197 654 -451 -526 -829 -394 -486 112 -304 -94 -253 282 136 345 754 293 689 -108 -272 -107 436 155 300 182 339 1385 914 397 76 -163 -146 263 38 18 -195 231 -77 -480 -211 -442 138 -197 -246 -984 -276 -1032 -511 -891 -626 -678 -740 -306 -819 -209 -564 76 -410 -78 -409 -40 -64 85 -19 274 183 -202 225 -308 49 -563 -93 -483 117 -55 128 -338 -376 42 -152 318 -81 285 -135 144 -154 262 230 363 -56 -359 343 -130 553 140 2107 383 646 83 265 192 120 604 704 1176 1042 959 69 189 -4 595 409 252 184 -107 -459 -320 -423 -618 -385 -491 -200 -685 -185 -1338 -1164 -1210 -819 -633 -410 50 -116 467 64 449 147 828 246 783 785 -69 -626 -930 -1015 222 706 -509 -636 -1064 -529 -688 168 -488 -158 -430 462 209 492 1023 402 986 -166 -440 -175 700 243 449 260 462 1810 1227 573 118 -268 -248 459 69 35 -395 482 -150 -937 -437 -883 266 -375 SS 20250517T132504.1Z 9268.559075 260 1 3.61 2 66.25 80.39 73.07 223.91 0.00 1 0.00 1 0 17 1.337e-01 2.616e-02 1.534e-01 2.638e-02 3.034411e-01 1.382103e-02 3.404211e-03 -6.000000e+00 8.016396e-02 231.04 -2.00 3.24 -2.00 318.27 0.00e+00 3.591698e-03 2.669938e-03 5.958548e-04 -6.000000e+00 3.629004e-03 290.23 -2.00 20.00 -2.00 317.38 0.00e+00 2.465 0.000 302.00 328.00 3 5.1943e+00 3.7551e-02 2.8693e-02 -6.0000e+00 1.9998e-01 1.0292e-01 4.2690e-02 1.4751e-02 -6.0000e+00 2.1644e-01 -1.3351e-02 2.6565e-02 7.3873e-03 -6.0000e+00 1.2926e-01 -4.4210e-03 1.3426e-02 2.8287e-03 -6.0000e+00 5.3899e-02 1.6435e-04 -2.1934e-03 8.4080e-04 3.2261e-05 -6.0000e+00 4.0595e-03 -1.7470e-03 -2.1551e-04 12 9 9 12 1 1 999.00 18.26 2.07 -0.00175 -0.01823 1 10 1 5 0 1804.750 21.69 14.99 18.26 32.76 32.3 1052.70 34041 -9602 46606 -23313 53617 -14331 18450 -14696 39945 4398 -18984 95747 -2335 -812 -909 21640 -23793 -416 -8664 16411 -10038 5511 3396 -8599 5946 -2138 35986 2314 197 -4349 18762 -20456 10108 -5144 -6903 14373 -9363 2791 -4383 8766 -1197 12818 -5309 -1271 -12112 2317 -4481 5737 3149 1510 7944 3500 1259 1797 2573 -3652 9399 -4685 473 -7633 -1947 5755 1948 4701 709 5774 -1835 4977 -5937 6164 -1324 3692 -4962 84 2085 -1057 -2567 -5108 7326 -1198 -113 -4504 330 -3094 563 -2933 -606 -1391 535 6295 686 2072 -548 6218 -711 2349 -2624 -2267 555 -1985 -867 -2503 -962 -2639 -528 -1926 2379 -991 1248 835 -654 465 -88 -1404 959 233 5493 1380 -1565 2426 312 -893 644 1564 -3692 302 235 -446 1910 -1029 798 -350 1558 -691 -709 86 515 538 -473 -64 -1691 2349 -1751 1660 -768 2253 -2053 2126 -1041 1035 -1229 2173 345 -1879 3454 -239 -95 -122 2598 -4625 -68 -1605 2490 -1977 941 603 -1775 1117 -443 5191 439 37 -865 3237 -5531 2209 -1313 -1731 2975 -2628 807 -1582 3176 -514 5071 -2548 -597 -6314 1064 -2170 2506 1404 697 3653 1781 690 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