File name: Pandora61s1_AldineTX_20250606_L2Fit_fwvt1c8d20241003p1-8.txt File generation date: 20250607T062804.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v8d20241003.txt Level 1 file used: Pandora61s1_AldineTX_20250606_L1_smca1c8d20241003p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20250606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0336 492.1544 492.2753 492.3961 492.5168 492.6376 492.7583 492.8791 492.9998 493.1205 493.2411 493.3618 493.4825 493.6031 493.7237 493.8443 493.9649 494.0854 494.2060 494.3265 494.4470 494.5675 494.6880 494.8085 494.9289 495.0493 495.1698 495.2901 495.4105 495.5309 495.6512 495.7716 495.8919 496.0122 496.1325 496.2527 496.3730 496.4932 496.6134 496.7336 496.8538 496.9740 497.0941 497.2142 497.3344 497.4545 497.5745 497.6946 497.8147 497.9347 498.0547 498.1747 498.2947 498.4146 498.5346 498.6545 498.7744 498.8943 499.0142 499.1341 499.2539 499.3738 499.4936 499.6134 499.7331 499.8529 499.9727 500.0924 500.2121 500.3318 500.4515 500.5711 500.6908 500.8104 500.9300 501.0496 501.1692 501.2887 501.4083 501.5278 501.6473 501.7668 501.8863 502.0058 502.1252 502.2446 502.3640 502.4834 502.6028 502.7222 502.8415 502.9608 503.0801 503.1994 503.3187 503.4379 503.5572 503.6764 503.7956 503.9148 504.0340 504.1531 504.2723 504.3914 504.5105 504.6296 504.7486 504.8677 504.9867 505.1057 505.2247 505.3437 505.4627 505.5816 505.7006 505.8195 505.9384 506.0572 506.1761 506.2949 506.4138 506.5326 506.6514 506.7701 506.8889 507.0076 507.1264 507.2451 507.3638 507.4824 507.6011 507.7197 507.8384 507.9570 508.0755 508.1941 508.3127 508.4312 508.5497 508.6682 508.7867 508.9051 509.0236 509.1420 509.2604 509.3788 509.4972 509.6156 509.7339 509.8522 509.9705 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250606T113239.9Z 9288.481017 105 1 10.96 2 88.39 64.58 133.12 283.04 0.00 1 0.00 1 0 22 9.259e-03 9.112e-03 3.676e-03 3.658e-03 3.431409e+04 3.551651e+02 2.082543e+03 -6.000000e+00 6.120283e+02 291.88 -2.00 20.00 -2.00 505.43 0.00e+00 4.171324e-03 1.120093e-04 2.512720e-04 -6.000000e+00 2.824194e-04 291.88 -2.00 20.00 -2.00 500.74 0.00e+00 7.858511e-01 7.686823e-02 1.799763e-01 -6.000000e+00 1.961597e-01 231.01 -2.00 3.24 -2.00 502.29 0.00e+00 16.964 0.059 489.00 513.00 1 5.4649e+00 5.9579e-03 3.0585e-02 -6.0000e+00 1.5258e-02 -2.2541e-03 1.3853e-03 4.7715e-03 -6.0000e+00 3.7366e-03 6.1896e-04 6.2967e-03 4.0813e-04 1.2289e-04 -6.0000e+00 1.4169e-03 2.1081e-02 -2.7346e-04 12 9 9 12 1 1 -13.12 17.97 14.26 0.02108 0.06476 6 11 1 4 0 1565.480 20.96 14.98 17.97 31.47 32.8 1033.73 179 -764 -342 18 731 1966 -66 385 -545 125 698 1456 -833 -446 -184 546 1443 404 -200 -698 -293 83 962 1556 773 -110 -973 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-865 -1479 -413 -545 1984 1015 -140 -1965 -465 -193 508 -679 -2414 -1305 -809 1223 1549 99 -1382 -370 -807 701 2868 2027 2582 1205 -97 -1509 -747 -95 1990 403 672 -242 1039 -748 -408 -547 -25 497 355 890 -646 268 -475 -314 228 -317 -1166 -819 474 -99 -100 66 1411 -56 -79 -617 754 SQ 20250606T113656.5Z 9288.483987 110 1 43.12 2 87.55 65.10 133.99 283.73 0.00 1 0.00 1 0 22 6.019e-03 5.958e-03 8.088e-04 8.051e-04 3.247536e+04 7.663960e+01 1.933495e+03 -6.000000e+00 3.978983e+02 291.88 -2.00 20.00 -2.00 505.46 0.00e+00 3.671735e-03 2.447047e-05 2.365072e-04 -6.000000e+00 1.835466e-04 291.88 -2.00 20.00 -2.00 500.72 0.00e+00 5.559729e-01 1.693454e-02 1.878810e-01 -6.000000e+00 1.273720e-01 231.01 -2.00 3.24 -2.00 502.30 0.00e+00 14.790 0.039 489.00 513.00 1 4.1545e+00 1.3098e-03 2.7609e-02 -6.0000e+00 9.9103e-03 -3.0784e-03 3.0694e-04 4.7348e-03 -6.0000e+00 2.4219e-03 3.2150e-03 3.1134e-03 9.1664e-05 1.2109e-04 -6.0000e+00 9.2218e-04 3.4351e-03 -2.1279e-05 12 8 8 10 0 0 43.29 17.96 10.90 0.00344 0.02503 138 55 1 4 0 312.400 20.87 15.02 17.96 31.81 32.6 1035.18 950 585 391 132 416 845 440 158 282 223 220 218 40 -67 170 456 597 330 31 -118 -120 211 587 665 353 -76 -453 -739 -489 233 676 241 336 -473 -864 -1057 -570 -84 127 227 11 -3 -199 151 -142 -39 -159 -401 -791 -735 -634 -210 173 214 -283 -632 -865 -596 -128 277 628 370 -139 -503 60 135 162 415 246 353 174 -118 -160 -450 -886 -807 -651 -445 -234 37 147 167 152 228 -208 -648 -663 -250 369 990 796 -63 -931 -1268 -1100 -398 704 820 64 -510 -120 -30 -511 -948 -1871 -1784 -987 162 848 426 -27 -130 -6 612 1453 1682 1423 329 -611 -897 -607 403 1343 1350 605 439 523 -132 -380 -350 -524 -61 432 606 761 337 -141 -261 -110 -181 -513 -571 -527 -345 -235 -177 151 304 736 937 801 833 520 356 124 400 827 439 159 284 224 219 215 39 -65 163 440 582 329 31 -121 -124 220 612 697 372 -80 -479 -775 -504 235 673 242 341 -493 -859 -1065 -574 -84 126 225 11 -3 -202 154 -147 -40 -165 -413 -806 -735 -622 -216 177 220 -277 -633 -886 -618 -133 289 654 388 -147 -532 63 140 166 419 246 349 172 -116 -159 -450 -891 -808 -644 -434 -225 36 139 158 145 218 -202 -635 -651 -244 356 945 759 -61 -891 -1196 -1006 -374 630 710 54 -435 -103 -26 -468 -851 -1766 -1736 -972 160 835 424 -27 -131 -7 620 1467 1707 1462 345 -650 -954 -637 413 1350 1348 608 442 528 -135 -388 -356 -532 -61 431 604 763 343 -147 -276 -118 -197 -534 -601 -558 -366 -248 -186 157 313 754 959 827 SQ 20250606T114129.2Z 9288.487144 115 1 13.64 2 86.66 65.65 134.92 284.49 0.00 1 0.00 1 0 22 5.583e-03 5.558e-03 5.991e-04 5.974e-04 2.812860e+04 5.498406e+01 1.684501e+03 -6.000000e+00 3.690515e+02 291.88 -2.00 20.00 -2.00 505.37 0.00e+00 3.124133e-03 1.818429e-05 2.067751e-04 -6.000000e+00 1.702462e-04 291.88 -2.00 20.00 -2.00 500.66 0.00e+00 3.952963e-01 1.251764e-02 1.621419e-01 -6.000000e+00 1.181557e-01 231.01 -2.00 3.24 -2.00 502.22 0.00e+00 12.709 0.025 489.00 513.00 1 3.0687e+00 9.7122e-04 2.3590e-02 -6.0000e+00 9.1929e-03 1.9989e-03 2.2801e-04 4.0575e-03 -6.0000e+00 2.2471e-03 1.3157e-02 2.1142e-03 7.0575e-05 1.0335e-04 -6.0000e+00 8.5523e-04 9.9451e-03 -7.6490e-05 12 9 9 12 1 1 -42.41 17.97 8.50 0.00995 0.02461 143 180 1 4 0 94.710 20.87 14.98 17.97 32.03 32.7 1036.78 1238 858 483 59 288 352 294 4 116 -20 100 27 37 71 270 510 350 214 -145 46 4 326 226 419 234 -138 -319 -537 -322 234 751 622 448 -304 -810 -1054 -756 -127 151 294 400 340 71 -78 -399 -448 -356 -362 -749 -864 -362 60 505 268 -44 -657 -819 -777 -202 307 540 160 -155 -165 29 7 30 243 53 174 248 367 -45 -284 -692 -833 -511 -292 173 234 357 88 167 17 -267 -517 -406 -227 343 674 443 -49 -904 -1103 -1019 -452 134 492 274 310 408 262 -189 -1130 -1814 -1744 -1008 -64 797 743 477 -10 145 628 1042 1310 947 125 -638 -594 -319 479 1083 1218 662 295 238 -153 -420 -516 -535 -64 490 547 838 527 110 -285 -142 -353 -394 -391 -557 -378 -508 -329 -140 255 736 1116 916 1121 786 453 58 286 357 287 4 114 -20 97 27 37 71 268 507 352 208 -144 46 4 331 230 428 240 -142 -328 -548 -322 229 726 602 440 -306 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