File name: Pandora61s1_AldineTX_20250703_L2Fit_fout2c8d20241003p1-8.txt File generation date: 20250704T063805.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v8d20241003.txt Level 1 file used: Pandora61s1_AldineTX_20250703_L1_smca1c8d20241003p1-8.txt Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20250703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0886 305.2296 305.3705 305.5115 305.6524 305.7933 305.9342 306.0751 306.2160 306.3569 306.4978 306.6386 306.7794 306.9203 307.0611 307.2019 307.3427 307.4834 307.6242 307.7649 307.9057 308.0464 308.1871 308.3278 308.4685 308.6091 308.7498 308.8904 309.0311 309.1717 309.3123 309.4529 309.5934 309.7340 309.8746 310.0151 310.1556 310.2961 310.4366 310.5771 310.7176 310.8581 310.9985 311.1390 311.2794 311.4198 311.5602 311.7006 311.8410 311.9813 312.1217 312.2620 312.4023 312.5426 312.6829 312.8232 312.9635 313.1038 313.2440 313.3842 313.5245 313.6647 313.8049 313.9450 314.0852 314.2254 314.3655 314.5057 314.6458 314.7859 314.9260 315.0661 315.2061 315.3462 315.4862 315.6263 315.7663 315.9063 316.0463 316.1863 316.3262 316.4662 316.6062 316.7461 316.8860 317.0259 317.1658 317.3057 317.4456 317.5854 317.7253 317.8651 318.0049 318.1447 318.2845 318.4243 318.5641 318.7038 318.8436 318.9833 319.1230 319.2627 319.4024 319.5421 319.6818 319.8214 319.9611 320.1007 320.2403 320.3799 320.5195 320.6591 320.7987 320.9382 321.0778 321.2173 321.3568 321.4964 321.6359 321.7753 321.9148 322.0543 322.1937 322.3331 322.4726 322.6120 322.7514 322.8908 323.0301 323.1695 323.3088 323.4482 323.5875 323.7268 323.8661 324.0054 324.1447 324.2839 324.4232 324.5624 324.7016 324.8409 324.9801 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250703T121224.2Z 9315.508613 64 1 37.57 2 81.50 68.41 159.11 339.37 0.00 1 0.00 1 0 17 2.963e-01 2.990e-02 1.299e-01 1.169e-02 6.770871e-01 6.454931e-03 7.656520e-03 -6.000000e+00 1.771902e-01 230.49 -2.00 3.24 -2.00 321.49 0.00e+00 3.646379e-03 2.754059e-03 5.972374e-03 -6.000000e+00 8.157691e-03 293.59 -2.00 20.00 -2.00 320.74 0.00e+00 6.360 0.003 302.00 328.00 3 8.9748e-01 2.2454e-02 7.7845e-02 -6.0000e+00 4.4089e-01 8.4070e-01 2.7322e-02 5.1983e-02 -6.0000e+00 4.7719e-01 -1.1625e+00 1.6497e-02 1.9317e-02 -6.0000e+00 2.8573e-01 4.8843e-01 8.3006e-03 4.7347e-03 -6.0000e+00 1.1961e-01 1.8242e-04 -3.5653e-03 3.5999e-04 9.7744e-05 -6.0000e+00 8.9968e-03 4.5605e-03 -1.4654e-04 12 9 9 12 1 1 82.32 17.72 1.97 0.00456 -0.02223 146 67 1 5 0 255.530 20.56 14.99 17.72 33.75 32.8 1037.08 -45410 95843 -36440 35058 -74361 -38635 -71176 -21244 -28066 -66271 7349 -70440 16021 -38345 110200 -41369 116771 -15033 90108 -1792 33239 10112 781 19176 -19567 41526 -26621 61648 -47779 37671 -25157 53317 2899 16797 8024 -7524 27841 -4685 36119 17229 61610 13298 70721 18863 64241 13955 35226 7118 18767 33931 13186 42917 4921 43686 10611 45865 7114 32278 12909 16667 11461 8283 15408 5087 25945 1757 16916 1003 14973 3808 15022 5432 6058 6343 -1881 20 -13343 1608 -14224 5366 -9666 4661 -4773 141 -2941 -839 -1772 -2700 431 -5638 2616 -6927 1630 -9730 -1588 -6247 -603 -3711 -2785 -3679 -3603 -473 -5361 -426 -5975 624 -3412 391 -1808 988 138 -212 -351 273 1823 -1249 2244 -789 2863 215 3735 1553 3485 1038 1607 1390 1255 2421 -870 2439 -911 1531 -163 426 -985 671 -5 62 -474 -960 -255 -1831 -262 -3483 2076 -2606 1199 -5935 -1962 -4943 -925 -1338 -4602 268 -5476 676 -3021 2513 -4331 2929 -1325 3082 -137 1895 692 58 1203 -1829 2083 -2519 2249 -5012 1761 -2496 2736 268 1360 668 -712 1968 -523 3130 2043 5058 1835 5564 2473 5274 1878 3816 1031 2482 4062 2105 5530 903 6326 2013 6851 1423 5373 2502 3041 2261 1832 3531 1281 6005 461 4147 271 3864 1232 4687 1914 2066 2012 -587 6 -3969 466 -4925 1791 -4348 2054 -2518 76 -1728 -511 -1139 -1788 275 -3659 1464 -4021 850 -5960 -1008 -4812 -508 -3655 -2915 -3875 -3566 -414 -4618 -353 -5568 578 -3509 418 -2187 1301 202 -328 -547 410 2580 -1773 3122 -1186 4380 348 5806 2392 5090 1500 2224 1866 1667 3363 -1397 4249 -1798 3154 -361 999 -2491 1746 -12 168 -1277 -2486 -617 -4254 -585 SS 20250703T122523.4Z 9315.517632 69 1 43.00 2 78.87 69.85 159.92 347.83 0.00 1 0.00 1 0 17 2.848e-01 1.527e-02 7.858e-02 5.896e-03 5.667032e-01 3.191371e-03 6.461342e-03 -6.000000e+00 1.703299e-01 230.49 -2.00 3.24 -2.00 321.02 0.00e+00 4.855208e-03 1.409292e-03 3.578701e-03 -6.000000e+00 7.838013e-03 293.59 -2.00 20.00 -2.00 320.24 0.00e+00 4.993 0.001 302.00 328.00 3 1.4783e+00 1.0861e-02 5.9033e-02 -6.0000e+00 4.2383e-01 3.1524e-01 1.3601e-02 3.4207e-02 -6.0000e+00 4.5866e-01 -4.0588e-01 9.9681e-03 1.5640e-02 -6.0000e+00 2.7464e-01 1.6577e-01 4.8831e-03 3.7977e-03 -6.0000e+00 1.1502e-01 4.3908e-04 -2.1999e-03 1.8462e-04 9.2106e-05 -6.0000e+00 8.6439e-03 4.3205e-03 -5.5368e-05 12 8 8 10 0 0 95.43 17.71 1.55 0.00432 -0.01221 235 93 1 5 0 182.930 20.56 15.00 17.71 35.05 32.8 1046.82 -53881 -108104 -65126 -113055 -105206 -96381 -97929 -94877 -107893 -68960 -89856 -45713 -62532 -3196 -18337 -9234 -21702 -9570 9242 -21375 1192 -29971 13715 -16115 25612 -9631 -7590 -26047 -11849 -13346 -13418 -8451 5800 19029 -12626 4902 -3127 11215 2604 21685 12694 14794 16208 14933 16744 13394 9306 4503 14713 9614 17968 4439 15189 8868 9679 6591 6376 6693 1308 6271 5011 11212 4716 9220 3491 5033 2271 4163 2138 2422 1740 1336 2271 -819 929 -2403 -2983 -5112 -1364 -3398 -2661 -1265 -1941 -1602 -2166 134 -1622 77 -532 621 -1664 -1448 -2713 -1954 -1387 -1647 -288 -1109 -928 -1649 -1088 -961 -738 -2522 -801 -1515 -571 -408 311 605 -439 616 435 610 -436 635 304 369 262 569 1001 1213 1129 503 746 -234 1752 474 793 239 351 286 169 -191 -283 46 -126 247 -518 -344 -416 -176 -663 -1115 -3899 -1723 -4550 -3569 -2882 -3097 -3164 -4405 -1983 -3307 -1209 -2373 -83 -664 -350 -1023 -429 361 -1168 52 -1775 536 -890 972 -532 -406 -1617 -634 -775 -895 -617 407 1204 -1060 347 -263 954 261 2282 1460 1763 1974 1873 2083 1743 1274 659 2007 1462 2743 849 2819 1868 2110 1523 1493 1543 311 1416 1197 2760 1381 2805 1152 1592 726 1349 777 986 773 615 1017 -357 364 -882 -1038 -1854 -531 -1568 -1404 -739 -1238 -1084 -1574 101 -1304 62 -429 475 -1219 -991 -1818 -1345 -1052 -1435 -283 -1235 -1096 -1942 -1195 -966 -699 -2481 -825 -1666 -659 -505 418 892 -709 1020 714 959 -656 916 445 566 425 953 1666 1960 1768 763 1082 -330 2384 685 1261 423 671 579 360 -395 -623 105 -297 588 -1232 -787 -984 -397 -1476 SS 20250703T123017.9Z 9315.521041 72 1 43.00 2 77.87 70.39 160.12 351.17 0.00 1 0.00 1 0 25 2.692e-01 1.546e-02 1.360e-01 8.858e-03 5.362777e-01 4.792959e-03 5.880025e-03 -6.000000e+00 1.610420e-01 230.49 -2.00 3.24 -2.00 320.85 0.00e+00 8.459557e-04 1.988413e-03 2.483589e-03 -6.000000e+00 7.407107e-03 293.59 -2.00 20.00 -2.00 320.04 0.00e+00 4.613 0.001 302.00 328.00 3 2.2648e+00 1.5845e-02 5.4404e-02 -6.0000e+00 4.0072e-01 1.8113e-01 1.9854e-02 3.1726e-02 -6.0000e+00 4.3361e-01 -2.5811e-01 1.4821e-02 1.3475e-02 -6.0000e+00 2.5965e-01 1.1289e-01 7.2720e-03 3.7058e-03 -6.0000e+00 1.0877e-01 3.0677e-04 -1.9784e-03 2.8323e-04 5.1135e-05 -6.0000e+00 8.1689e-03 4.7169e-03 4.0714e-05 12 8 8 10 0 0 98.47 17.71 1.31 0.00472 -0.01015 271 107 1 5 0 158.650 20.56 15.00 17.71 35.31 32.8 1049.04 -73538 -54762 -97034 -28859 -106216 439 -137249 -77057 -115206 -78354 -67040 -84326 -44301 -33576 -30588 -30929 23297 -35923 15449 -24539 470 -20239 -8245 7326 4120 -8252 -27420 -11304 -22772 -3694 -16247 16267 4452 16015 89 11351 2909 3696 3456 8122 19492 5056 18945 2949 10852 3639 13036 -2144 7448 1689 7932 4226 8839 11360 6005 7970 3012 11299 1111 8001 3949 7666 2345 4748 4320 2881 3717 -2406 5246 914 4717 1663 3594 -667 1195 -2332 -2664 -3798 -3655 -2764 -3748 -667 -3402 -793 -2207 173 -953 295 -516 -382 -730 -2596 -34 -2802 -455 -1700 297 -807 -493 -1938 -818 -1102 -131 -1774 -2304 -1168 -1348 238 -761 970 -153 1309 499 170 193 -176 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