File name: Pandora129s1_AliceSprings_20241108_L2Fit_fout2c2d20240111p1-8.txt File generation date: 20250327T121620.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Medhavy Thankappan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 129 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora129_OF_v3d20201201.txt Instrument calibration file used: Pandora129s1_CF_v2d20240111.txt Level 1 file used: Pandora129s1_AliceSprings_20241108_L1_smca1c2d20240111p1-8.txt Full location name: Geoscience Australia, Kilgariff NT Short location name: AliceSprings Country of location: Australia Location latitude [deg]: -23.7580 Location longitude [deg]: 133.8826 Location altitude [m]: 567 Local noon date: 20241108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 238 379 Nominal wavelengths inside fitting window [nm]: 305.1271 305.2680 305.4089 305.5498 305.6907 305.8316 305.9724 306.1133 306.2541 306.3949 306.5357 306.6765 306.8173 306.9581 307.0989 307.2396 307.3804 307.5211 307.6618 307.8025 307.9432 308.0839 308.2245 308.3652 308.5059 308.6465 308.7871 308.9277 309.0683 309.2089 309.3495 309.4901 309.6306 309.7711 309.9117 310.0522 310.1927 310.3332 310.4737 310.6141 310.7546 310.8950 311.0355 311.1759 311.3163 311.4567 311.5971 311.7375 311.8778 312.0182 312.1585 312.2989 312.4392 312.5795 312.7198 312.8601 313.0003 313.1406 313.2808 313.4211 313.5613 313.7015 313.8417 313.9819 314.1221 314.2622 314.4024 314.5425 314.6826 314.8227 314.9628 315.1029 315.2430 315.3831 315.5231 315.6632 315.8032 315.9432 316.0832 316.2232 316.3632 316.5032 316.6432 316.7831 316.9230 317.0630 317.2029 317.3428 317.4827 317.6226 317.7624 317.9023 318.0421 318.1820 318.3218 318.4616 318.6014 318.7412 318.8809 319.0207 319.1604 319.3002 319.4399 319.5796 319.7193 319.8590 319.9987 320.1383 320.2780 320.4176 320.5573 320.6969 320.8365 320.9761 321.1157 321.2552 321.3948 321.5343 321.6739 321.8134 321.9529 322.0924 322.2319 322.3714 322.5108 322.6503 322.7897 322.9291 323.0685 323.2080 323.3473 323.4867 323.6261 323.7654 323.9048 324.0441 324.1834 324.3228 324.4620 324.6013 324.7406 324.8799 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241107T205237.4Z 9077.869878 45 1 49.07 2 82.42 104.86 130.44 165.21 0.00 1 0.00 1 0 25 5.941e-01 1.392e-02 2.735e-01 4.730e-03 7.620269e-01 2.681002e-03 7.263837e-03 -6.000000e+00 3.439600e-01 228.75 -2.00 3.04 -2.00 321.63 0.00e+00 5.854809e-03 1.125044e-03 8.433066e-04 -6.000000e+00 1.806796e-02 287.45 -2.00 20.00 -2.00 321.32 0.00e+00 7.035 0.002 302.00 328.00 3 1.0173e+00 8.6437e-03 7.4797e-02 -6.0000e+00 8.6648e-01 9.9212e-02 1.3798e-02 3.7741e-02 -6.0000e+00 9.4215e-01 -3.0654e-01 1.7258e-02 2.2297e-02 -6.0000e+00 5.4744e-01 1.4576e-01 8.2391e-03 7.8864e-03 -6.0000e+00 2.4158e-01 1.4083e-04 -9.6751e-04 1.3777e-04 8.6633e-05 -6.0000e+00 1.5928e-02 -5.7790e-02 0.0000e+00 12 8 8 10 0 0 20.27 14.10 0.37 -0.05779 -0.06506 70 16 4 8 0 700.900 15.00 14.10 26.70 21.38 20.96 14.3 949.78 900000 -238885 900000 900000 -187049 900000 -302899 -136294 900000 900000 900000 900000 35557 900000 -61051 -1011 13151 -146545 34462 -52423 -43712 58352 900000 -34318 -70713 900000 -28287 77524 264 373148 56148 -64248 19428 30777 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-828 -422 148 -563 -928 -249 -351 -899 -96 -233 29 1712 1761 132 -1496 618 -20 1016 -1208 -826 460 1118 1499 1630 1839 922 1375 -1989 -932 -1597 -868 -34 -236 1186 -747 2081 -870 -283 -115 -106 447 -631 -1016 204 -6 -656 -926 -424 -889 1949 1527 410 473 -683 -1090 SS 20241107T205859.4Z 9077.874299 48 1 48.90 2 81.01 104.27 130.08 163.47 0.00 1 0.00 1 0 17 3.728e-01 9.806e-03 1.432e-01 2.390e-03 6.759264e-01 1.274392e-03 6.519415e-03 -6.000000e+00 2.129571e-01 228.75 -2.00 3.04 -2.00 321.11 0.00e+00 1.420004e-03 4.809948e-04 5.945964e-04 -6.000000e+00 8.428005e-03 287.45 -2.00 20.00 -2.00 320.83 0.00e+00 6.061 0.001 302.00 328.00 3 7.8390e-01 3.8815e-03 6.4612e-02 -6.0000e+00 5.3505e-01 -1.7032e-02 5.5243e-03 3.2389e-02 -6.0000e+00 5.8006e-01 -1.0751e-01 6.6576e-03 1.8360e-02 -6.0000e+00 3.4041e-01 5.1528e-02 3.3164e-03 6.2745e-03 -6.0000e+00 1.4603e-01 4.6113e-04 -3.6035e-04 6.6164e-05 6.6060e-05 -6.0000e+00 9.5549e-03 -5.8943e-02 0.0000e+00 12 8 8 10 0 0 -10.51 14.10 0.36 -0.05894 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-206 -272 106 628 -684 131 255 805 991 629 361 119 171 527 225 165 311 297 93 1026 921 827 380 766 101 -38 -277 481 1234 2141 1909 939 722 289 463 698 617 1300 527 226 -321 -2160 -1280 -1992 -1598 -1563 -1515 -1620 -2210 -2813 -1461 -729 -21 -253 40 55 -582 -1211 -1021 -657 -630 -372 951 1730 1471 928 61 -196 -422 528 -2 -22 276 1244 1615 1756 2006 2296 1171 -40 -1246 -759 -1124 -553 -241 -54 231 -192 1241 -606 -483 -1557 -851 68 -672 -1218 -1005 -727 -1250 -916 -553 -514 1616 1971 958 634 60 -714 SS 20241107T211131.0Z 9077.882998 53 1 50.90 2 78.22 103.14 129.26 160.12 0.00 1 0.00 1 0 17 1.314e-01 1.006e-02 2.423e-02 9.354e-04 5.490940e-01 4.840654e-04 5.450851e-03 -6.000000e+00 7.506715e-02 228.75 -2.00 3.04 -2.00 320.14 0.00e+00 -1.654305e-04 1.420886e-04 3.074485e-04 -6.000000e+00 2.970874e-03 287.45 -2.00 20.00 -2.00 319.86 0.00e+00 4.745 0.000 302.00 328.00 3 4.2827e-01 1.3695e-03 5.0786e-02 -6.0000e+00 1.8860e-01 -3.8175e-02 1.6680e-03 2.5238e-02 -6.0000e+00 2.0447e-01 -3.2393e-02 1.7015e-03 1.3320e-02 -6.0000e+00 1.2000e-01 1.3440e-02 9.0457e-04 4.2388e-03 -6.0000e+00 5.1476e-02 2.3557e-03 -1.9082e-04 2.5508e-05 4.1333e-05 -6.0000e+00 3.3682e-03 -5.8857e-02 0.0000e+00 12 8 8 10 0 0 6.16 14.10 0.28 -0.05886 -0.06029 367 83 2 8 0 133.580 15.00 14.10 28.84 21.38 20.96 14.3 961.57 -52391 -37068 -24204 -58561 -35222 -73633 -45838 -41561 -21951 -30854 -32065 -14300 -23836 1278 -11434 -1888 -6121 -7922 3938 -6550 4951 -4179 4956 -687 -2656 8110 -3568 947 -6737 -115 -2199 -1898 4969 329 -1782 -5102 -1887 384 -24508 4981 2072 4961 3227 3904 2118 946 1532 -733 71 -1346 965 -55 541 1360 583 2432 1164 1437 325 750 1292 1929 4344 3972 3303 1255 664 -183 858 2175 1375 1770 1078 793 -338 -2788 -3058 -4687 -3289 -3593 -2752 -2502 -3541 -2722 -1978 -862 -507 133 468 300 -246 -1146 -1287 -1178 -590 -126 880 1738 1203 839 306 -140 -190 516 470 235 475 670 1220 1557 1535 1209 689 164 -771 -531 -771 -593 -197 -306 -159 -48 230 -359 -450 -978 -865 61 -575 -532 -567 -571 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