File name: Pandora285s1_AmesIA_20250802_L2Fit_fout2c2d20250320p1-8.txt File generation date: 20250828T142739.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 285 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora285_OF_v1d20240703.txt Instrument calibration file used: Pandora285s1_CF_v2d20250320.txt Level 1 file used: Pandora285s1_AmesIA_20250802_L1_smca1c2d20250320p1-8.txt Full location name: AmesIowa-KelleyFields Short location name: AmesIA Country of location: USA Location latitude [deg]: 42.0250 Location longitude [deg]: -93.7152 Location altitude [m]: 5 Local noon date: 20250802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0768 305.2175 305.3583 305.4990 305.6397 305.7804 305.9211 306.0618 306.2024 306.3431 306.4837 306.6244 306.7650 306.9056 307.0462 307.1868 307.3274 307.4680 307.6085 307.7491 307.8896 308.0301 308.1706 308.3111 308.4516 308.5921 308.7326 308.8730 309.0135 309.1539 309.2943 309.4347 309.5751 309.7155 309.8559 309.9963 310.1366 310.2770 310.4173 310.5576 310.6979 310.8382 310.9785 311.1188 311.2591 311.3993 311.5396 311.6798 311.8200 311.9602 312.1004 312.2406 312.3808 312.5210 312.6611 312.8013 312.9414 313.0815 313.2216 313.3617 313.5018 313.6419 313.7820 313.9220 314.0621 314.2021 314.3421 314.4821 314.6221 314.7621 314.9021 315.0420 315.1820 315.3219 315.4619 315.6018 315.7417 315.8816 316.0215 316.1613 316.3012 316.4411 316.5809 316.7207 316.8605 317.0003 317.1401 317.2799 317.4197 317.5595 317.6992 317.8389 317.9787 318.1184 318.2581 318.3978 318.5375 318.6771 318.8168 318.9564 319.0961 319.2357 319.3753 319.5149 319.6545 319.7941 319.9336 320.0732 320.2127 320.3523 320.4918 320.6313 320.7708 320.9103 321.0498 321.1892 321.3287 321.4681 321.6076 321.7470 321.8864 322.0258 322.1652 322.3045 322.4439 322.5832 322.7226 322.8619 323.0012 323.1405 323.2798 323.4191 323.5584 323.6976 323.8369 323.9761 324.1153 324.2545 324.3937 324.5329 324.6721 324.8113 324.9504 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250802T121756.6Z 9345.512461 84 1 30.27 2 78.90 76.22 160.24 345.52 0.00 1 0.00 1 0 25 3.686e-01 2.220e-02 3.241e-01 1.444e-02 6.045611e-01 7.766954e-03 7.193656e-03 -6.000000e+00 2.149498e-01 232.38 -2.00 3.53 -2.00 321.13 0.00e+00 5.530059e-03 3.654624e-03 3.636016e-03 -6.000000e+00 1.010065e-02 289.25 -2.00 20.00 -2.00 320.48 0.00e+00 5.006 0.002 302.00 328.00 3 4.1494e+00 2.6923e-02 6.1351e-02 -6.0000e+00 5.3866e-01 3.2215e-01 3.4291e-02 3.6450e-02 -6.0000e+00 5.8241e-01 -4.5372e-01 2.8220e-02 1.8593e-02 -6.0000e+00 3.4690e-01 1.8835e-01 1.3671e-02 5.8604e-03 -6.0000e+00 1.4712e-01 2.8629e-05 2.5348e-04 4.1977e-04 1.1911e-04 -6.0000e+00 1.0190e-02 3.7751e-03 0.0000e+00 12 8 8 10 0 0 57.84 25.25 1.00 0.00378 0.00568 10 10 1 5 0 3026.540 34.25 20.21 25.25 21.08 0.0 1009.96 -155942 -12472 -57944 -118113 -170388 -54679 -180800 -163771 -23148 -48552 900000 -16947 74271 -12944 -5355 -68400 53352 60995 -14693 -31704 53757 900000 47209 1278 -2437 -28525 51842 35393 28177 -27605 412 6611 -4042 -9321 -15511 33998 13917 -11550 21501 19085 40674 33950 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1283 1612 -2941 -2031 741 -330 -2175 -1240 1123 -502 -1689 304 847 -2074 -601 -2242 848 66 496 1137 700 -1185 3338 2369 3832 1089 2932 615 1607 786 -18 36 1281 642 648 -2279 -933 1597 602 404 -195 -357 -2090 -3432 SS 20250802T122326.1Z 9345.516274 87 1 29.81 2 77.90 77.09 160.47 349.05 0.00 1 0.00 1 0 25 3.368e-01 1.307e-02 2.699e-01 8.549e-03 5.815981e-01 4.642887e-03 7.134261e-03 -6.000000e+00 1.976348e-01 232.38 -2.00 3.53 -2.00 320.90 0.00e+00 4.996432e-03 2.070428e-03 3.821409e-03 -6.000000e+00 9.218706e-03 289.25 -2.00 20.00 -2.00 320.20 0.00e+00 4.627 0.002 302.00 328.00 3 3.9073e+00 1.5554e-02 5.8238e-02 -6.0000e+00 4.9567e-01 1.1817e-01 2.0100e-02 3.7520e-02 -6.0000e+00 5.3652e-01 -1.4691e-01 1.8109e-02 1.8738e-02 -6.0000e+00 3.1790e-01 5.2821e-02 8.8606e-03 5.2444e-03 -6.0000e+00 1.3487e-01 5.4733e-05 2.5360e-04 2.5188e-04 1.0247e-04 -6.0000e+00 9.3187e-03 2.3096e-03 0.0000e+00 12 8 8 10 0 0 -2.10 25.31 0.55 0.00231 0.00422 14 14 1 5 0 2128.960 34.25 19.87 25.31 21.58 0.0 1012.14 900000 -145209 -121143 35054 -164945 900000 -146720 -25456 -70946 900000 64105 -97492 -24457 -35903 -14104 31173 -20322 -30290 25242 140179 -41846 87921 -8885 -28291 35917 28637 -29988 -20143 -23158 -32883 -19608 -10487 -31199 2802 -8288 -53420 -9957 -13237 6478 2629 12290 1885 -1016 5075 4721 -2769 1678 1298 5698 5975 8807 8219 -2941 -1903 13840 577 8339 -3786 5930 292 517 3236 4342 5723 2085 388 91 3659 1376 4800 319 1008 4509 1586 2167 -6782 -2907 -2703 -2914 671 -634 -1156 -1763 -296 -1115 957 807 1904 1169 145 933 -1092 -2289 947 -780 -2345 1163 -191 -80 1555 -1691 -1825 -2466 -3843 -2551 -916 -659 -1381 290 457 392 894 1892 -618 -445 -153 -398 -781 373 -303 1081 526 468 1056 1493 526 -695 782 1118 -7 153 -321 138 352 -1 -137 -155 379 -468 -601 343 -298 -383 900000 -2640 -1835 292 -3374 900000 -2667 -212 -752 900000 534 -1699 -259 -544 -214 354 -431 -780 402 1168 -1395 879 -244 -1014 718 644 -1224 -722 -849 -1452 -899 -516 -2158 145 -456 -4629 -622 -1015 497 248 1167 212 -124 596 566 -367 217 173 755 841 1336 1390 -605 -419 2733 135 1841 -937 1300 67 125 839 1259 1817 709 130 30 1195 508 1964 150 488 2078 711 883 -2718 -1049 -986 -1192 312 -347 -719 -1200 -211 -857 769 682 1636 1010 121 722 -804 -1632 671 -626 -2203 1104 -209 -94 1781 -1874 -1836 -2546 -4099 -2630 -982 -745 -1683 378 661 621 1471 3057 -981 -664 -219 -575 -1188 595 -508 1781 845 727 1572 2118 725 -940 1087 1727 -12 289 -644 288 712 -3 -313 -362 898 -1114 -1378 738 -611 -837 SS 20250802T122846.8Z 9345.519986 90 1 30.66 2 76.94 77.94 160.63 352.56 0.00 1 0.00 1 0 17 2.244e-01 8.384e-03 2.271e-01 5.646e-03 5.569691e-01 2.988688e-03 6.515210e-03 -6.000000e+00 1.307967e-01 232.38 -2.00 3.53 -2.00 320.63 0.00e+00 1.570035e-03 1.213010e-03 2.208558e-03 -6.000000e+00 5.832262e-03 289.25 -2.00 20.00 -2.00 319.90 0.00e+00 4.308 0.001 302.00 328.00 3 3.7074e+00 9.4517e-03 5.3318e-02 -6.0000e+00 3.2784e-01 5.8189e-02 1.2118e-02 3.2509e-02 -6.0000e+00 3.5440e-01 -7.7967e-02 1.0942e-02 1.5756e-02 -6.0000e+00 2.1114e-01 2.3750e-02 5.4324e-03 4.1923e-03 -6.0000e+00 8.9157e-02 9.4762e-05 -1.1491e-04 1.6450e-04 5.8404e-05 -6.0000e+00 6.1550e-03 1.9990e-03 0.0000e+00 11 8 0 10 0 0 2.94 25.38 0.84 0.00200 0.00114 20 20 1 5 0 1532.680 34.50 20.03 25.38 22.09 0.0 1013.70 -75147 -20939 -80200 -19598 59343 -109255 9990 -86337 35864 -105927 -79459 -15267 -49069 28550 -51582 -21341 -17432 23234 -24953 -9226 -39143 -35865 -686 8080 8524 -273 -10227 -20489 -20184 -9289 -2675 -6999 -9405 -14745 -17734 11270 -9166 -18855 3359 3238 -1109 3768 3168 2991 10884 -3070 -317 -189 439 2532 3051 973 2736 2943 3075 4258 -10 -586 2311 1466 -397 1148 4819 5847 1114 200 -1137 -882 19 1850 3219 1231 1830 912 403 -39 -2979 -2195 -1790 -2511 -1557 -507 -1074 -2208 -1429 -434 508 279 229 540 148 186 -1505 -777 -974 -991 844 737 514 -112 -931 -1187 -816 -1077 -1459 -1123 -413 719 -361 775 679 963 1005 357 -705 -734 -310 351 184 26 186 -90 689 693 252 -468 62 201 258 234 -97 -281 -337 -386 -58 140 -37 357 259 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