File name: Pandora285s1_AmesIA_20250807_L2Fit_fout2c2d20250320p1-8.txt File generation date: 20250828T142732.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 285 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora285_OF_v1d20240703.txt Instrument calibration file used: Pandora285s1_CF_v2d20250320.txt Level 1 file used: Pandora285s1_AmesIA_20250807_L1_smca1c2d20250320p1-8.txt Full location name: AmesIowa-KelleyFields Short location name: AmesIA Country of location: USA Location latitude [deg]: 42.0250 Location longitude [deg]: -93.7152 Location altitude [m]: 5 Local noon date: 20250807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0768 305.2175 305.3583 305.4990 305.6397 305.7804 305.9211 306.0618 306.2024 306.3431 306.4837 306.6244 306.7650 306.9056 307.0462 307.1868 307.3274 307.4680 307.6085 307.7491 307.8896 308.0301 308.1706 308.3111 308.4516 308.5921 308.7326 308.8730 309.0135 309.1539 309.2943 309.4347 309.5751 309.7155 309.8559 309.9963 310.1366 310.2770 310.4173 310.5576 310.6979 310.8382 310.9785 311.1188 311.2591 311.3993 311.5396 311.6798 311.8200 311.9602 312.1004 312.2406 312.3808 312.5210 312.6611 312.8013 312.9414 313.0815 313.2216 313.3617 313.5018 313.6419 313.7820 313.9220 314.0621 314.2021 314.3421 314.4821 314.6221 314.7621 314.9021 315.0420 315.1820 315.3219 315.4619 315.6018 315.7417 315.8816 316.0215 316.1613 316.3012 316.4411 316.5809 316.7207 316.8605 317.0003 317.1401 317.2799 317.4197 317.5595 317.6992 317.8389 317.9787 318.1184 318.2581 318.3978 318.5375 318.6771 318.8168 318.9564 319.0961 319.2357 319.3753 319.5149 319.6545 319.7941 319.9336 320.0732 320.2127 320.3523 320.4918 320.6313 320.7708 320.9103 321.0498 321.1892 321.3287 321.4681 321.6076 321.7470 321.8864 322.0258 322.1652 322.3045 322.4439 322.5832 322.7226 322.8619 323.0012 323.1405 323.2798 323.4191 323.5584 323.6976 323.8369 323.9761 324.1153 324.2545 324.3937 324.5329 324.6721 324.8113 324.9504 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250807T145943.7Z 9350.624812 285 1 29.44 2 49.96 105.43 151.07 295.05 0.00 1 0.00 1 0 17 1.210e-02 7.427e-03 5.501e-03 2.506e-03 2.145656e-01 1.295915e-03 2.584346e-03 -6.000000e+00 7.068126e-03 232.19 -2.00 3.53 -2.00 316.45 0.00e+00 6.829862e-04 1.522826e-04 1.339221e-04 -6.000000e+00 3.150119e-04 289.36 -2.00 20.00 -2.00 315.65 0.00e+00 1.551 0.000 302.00 328.00 3 5.5554e+00 3.4066e-03 1.9285e-02 -6.0000e+00 1.7707e-02 3.5635e-02 3.7993e-03 1.1277e-02 -6.0000e+00 1.9128e-02 4.4248e-04 2.1879e-03 5.4455e-03 -6.0000e+00 1.1399e-02 -5.4323e-03 1.0179e-03 1.5080e-03 -6.0000e+00 4.8297e-03 3.3501e-04 -1.2983e-04 7.2779e-05 1.7787e-05 -6.0000e+00 3.3174e-04 -1.6080e-02 0.0000e+00 11 8 0 10 0 0 97.35 27.55 0.33 -0.01608 -0.01706 16 16 1 5 0 1839.640 36.00 20.00 27.55 27.10 0.0 1033.15 1493 1011 -434 -3440 -2133 -5696 -2590 1327 2484 98 -2892 -2238 -118 765 602 582 -184 1081 1459 1832 415 294 1295 1686 -575 -921 1447 -1509 -850 118 109 1188 1891 -592 -2583 -4346 -1628 -1457 748 -381 -459 -312 -969 -5 86 -493 -909 -882 -2204 -529 579 618 100 841 859 1079 1351 -452 -10 -238 842 1520 1818 2258 751 -28 -46 -796 536 1002 289 939 490 1264 345 -740 -182 -1528 -1717 -1625 -1633 -1166 -1487 -1203 -692 -532 -4 656 982 665 506 1 -838 -330 -176 -12 402 676 243 -381 -434 -885 -1466 -302 -932 -761 -942 -503 -93 781 960 683 521 238 -369 -176 -250 -440 -31 285 74 313 341 324 411 452 52 685 195 351 -269 -258 -311 191 -94 210 252 510 314 -107 39 -882 -856 258 190 -84 -641 -347 -912 -423 232 475 20 -599 -466 -26 194 172 182 -60 357 497 642 150 105 466 633 -210 -348 533 -591 -306 41 40 454 771 -254 -1054 -1754 -694 -652 391 -235 -309 -200 -642 -4 57 -326 -642 -603 -1484 -349 394 447 70 615 646 823 1043 -354 -7 -182 654 1252 1614 2114 709 -24 -37 -623 435 910 290 905 475 1275 328 -641 -141 -1229 -1423 -1372 -1543 -1207 -1521 -1284 -785 -647 -5 800 1199 847 599 1 -901 -336 -186 -13 474 877 312 -486 -562 -1065 -1675 -350 -1178 -1018 -1226 -682 -132 1154 1485 1071 788 336 -478 -229 -322 -591 -41 405 108 455 485 442 571 597 66 850 257 490 -368 -362 -445 280 -146 343 395 817 509 -171 64 -1423 -1347 SS 20250807T150521.4Z 9350.628720 289 1 2.76 2 48.95 106.62 151.96 296.77 0.00 1 0.00 1 0 25 1.348e-02 8.361e-03 6.603e-03 4.115e-03 2.060395e-01 2.143822e-03 2.531383e-03 -6.000000e+00 7.874210e-03 232.19 -2.00 3.53 -2.00 315.39 0.00e+00 3.823852e-04 2.004747e-04 2.491806e-05 -6.000000e+00 3.509477e-04 289.36 -2.00 20.00 -2.00 314.64 0.00e+00 1.520 0.000 302.00 328.00 3 4.2287e+00 5.5580e-03 1.8810e-02 -6.0000e+00 1.9727e-02 1.0087e-02 6.1680e-03 1.0927e-02 -6.0000e+00 2.1309e-02 5.9383e-04 3.5273e-03 5.2913e-03 -6.0000e+00 1.2699e-02 -4.6681e-03 1.5685e-03 1.4625e-03 -6.0000e+00 5.3804e-03 1.3403e-03 -1.7631e-04 1.1771e-04 1.9395e-05 -6.0000e+00 3.6959e-04 -1.5893e-02 0.0000e+00 12 9 1 12 1 1 999.00 27.55 0.28 -0.01589 -0.01722 2 33 1 5 0 917.260 36.00 20.00 27.55 27.08 0.0 1033.36 3199 -1190 -2057 -1492 -5687 -5693 1294 -663 -191 -868 -1443 -2777 -1237 600 1896 1284 210 1131 1697 954 1755 4 131 1376 890 1901 174 342 -1168 1803 3554 1376 858 -344 -3265 -4270 -4008 -2125 -1170 115 -856 -231 -436 -415 969 -482 34 -515 -888 -463 886 722 358 490 618 1242 917 -121 217 211 65 1418 1746 2380 1173 -117 -401 -527 482 440 23 847 23 426 101 -490 -1695 -1974 -1477 -873 -698 -1742 -1911 -1241 -601 -655 -62 332 1060 693 722 435 -818 -586 -333 332 788 322 465 287 -29 -841 -785 -102 -905 -867 -523 -963 64 428 1078 -63 313 -62 289 -545 -377 -225 -430 471 -6 621 264 42 486 239 347 968 570 842 167 561 514 -565 -411 10 351 482 91 34 -962 -680 -769 877 -341 -603 -439 -1538 -1464 327 -190 -61 -267 -438 -862 -416 224 731 541 93 507 782 426 791 2 60 656 447 976 91 167 -571 832 1676 659 442 -184 -1678 -2154 -2188 -1237 -758 81 -628 -175 -341 -327 749 -377 26 -380 -674 -347 649 564 295 402 521 1057 796 -106 186 179 57 1248 1654 2262 1120 -109 -362 -459 435 426 24 858 23 440 98 -452 -1492 -1634 -1249 -778 -662 -1758 -2061 -1334 -686 -772 -74 407 1299 824 826 473 -856 -609 -343 372 932 390 595 364 -36 -979 -900 -119 -1111 -1085 -682 -1270 87 592 1553 -89 442 -84 374 -691 -472 -282 -576 646 -9 875 365 55 633 309 425 1168 727 1095 229 758 706 -810 -600 15 533 749 139 52 -1455 -1029 -1137 SS 20250807T151022.3Z 9350.632203 292 1 20.65 2 48.06 107.70 152.74 298.38 0.00 1 0.00 1 0 17 1.250e-02 8.346e-03 6.741e-03 3.295e-03 2.071376e-01 1.706492e-03 2.486809e-03 -6.000000e+00 7.297219e-03 232.19 -2.00 3.53 -2.00 316.26 0.00e+00 5.872402e-04 1.926116e-04 1.236012e-04 -6.000000e+00 3.252607e-04 289.36 -2.00 20.00 -2.00 315.45 0.00e+00 1.494 0.000 302.00 328.00 3 5.7286e+00 4.4742e-03 1.8572e-02 -6.0000e+00 1.8281e-02 3.3117e-02 4.9909e-03 1.0855e-02 -6.0000e+00 1.9748e-02 -4.5211e-05 2.8698e-03 5.2527e-03 -6.0000e+00 1.1769e-02 -4.3233e-03 1.3223e-03 1.4506e-03 -6.0000e+00 4.9858e-03 3.0277e-04 -4.3752e-05 9.5911e-05 1.7227e-05 -6.0000e+00 3.4255e-04 -1.5276e-02 0.0000e+00 12 9 1 12 1 1 99.79 27.56 0.07 -0.01528 -0.01560 6 10 1 5 0 2949.160 36.00 20.00 27.56 27.10 0.0 1033.44 -2370 2889 -827 -1334 -2039 -2013 156 -550 3829 -3402 -1627 206 -3263 -352 -948 -1271 1402 497 107 1322 2506 668 1469 1039 525 784 585 -550 -1067 -176 1030 2285 1374 -1410 -2132 -3210 -3996 -2106 -533 714 -384 -1299 -589 660 144 432 -309 -1624 -1755 -605 780 1452 1183 225 934 1394 2022 -35 58 -121 398 1025 1867 1821 47 -625 -367 -303 784 1086 952 272 589 328 168 -338 -1403 -2333 -2915 -1276 -1298 -1995 -1573 -1189 -1014 211 -34 505 675 1429 70 33 -932 -1316 102 97 343 1050 1060 -32 40 -1332 -1207 -262 -985 -573 -510 -675 -106 636 1570 821 449 80 -397 -757 -733 -207 -65 442 574 217 344 705 519 476 -93 378 142 -382 -401 -187 -360 -300 323 -92 -56 748 -122 172 20 -406 -794 -480 602 -181 -273 -371 -348 28 -110 810 -808 -372 47 -844 -100 -305 -405 450 165 37 465 884 237 526 391 208 319 238 -212 -420 -67 402 853 554 -598 -850 -1258 -1713 -1026 -305 430 -255 -905 -418 466 102 303 -214 -1099 -1153 -391 519 1021 876 176 748 1127 1649 -29 47 -98 330 903 1625 1677 43 -538 -313 -249 670 961 924 278 602 325 156 -307 -1160 -1828 -2360 -1130 -1187 -2020 -1691 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