File name: Pandora285s1_AmesIA_20250813_L2Fit_fwvt1c2d20250320p1-8.txt File generation date: 20250828T143452.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 285 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora285_OF_v1d20240703.txt Instrument calibration file used: Pandora285s1_CF_v2d20250320.txt Level 1 file used: Pandora285s1_AmesIA_20250813_L1_smca1c2d20250320p1-8.txt Full location name: AmesIowa-KelleyFields Short location name: AmesIA Country of location: USA Location latitude [deg]: 42.0250 Location longitude [deg]: -93.7152 Location altitude [m]: 5 Local noon date: 20250813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1615 1764 Nominal wavelengths inside fitting window [nm]: 492.0531 492.1741 492.2951 492.4161 492.5370 492.6579 492.7789 492.8998 493.0206 493.1415 493.2623 493.3832 493.5040 493.6248 493.7456 493.8663 493.9871 494.1078 494.2285 494.3492 494.4699 494.5905 494.7112 494.8318 494.9524 495.0730 495.1936 495.3141 495.4347 495.5552 495.6757 495.7962 495.9167 496.0371 496.1576 496.2780 496.3984 496.5188 496.6391 496.7595 496.8798 497.0002 497.1205 497.2407 497.3610 497.4813 497.6015 497.7217 497.8419 497.9621 498.0823 498.2024 498.3226 498.4427 498.5628 498.6829 498.8029 498.9230 499.0430 499.1630 499.2830 499.4030 499.5229 499.6429 499.7628 499.8827 500.0026 500.1225 500.2424 500.3622 500.4820 500.6018 500.7216 500.8414 500.9612 501.0809 501.2006 501.3203 501.4400 501.5597 501.6793 501.7990 501.9186 502.0382 502.1578 502.2773 502.3969 502.5164 502.6359 502.7554 502.8749 502.9944 503.1138 503.2333 503.3527 503.4721 503.5915 503.7108 503.8302 503.9495 504.0688 504.1881 504.3074 504.4266 504.5459 504.6651 504.7843 504.9035 505.0227 505.1418 505.2610 505.3801 505.4992 505.6183 505.7373 505.8564 505.9754 506.0944 506.2134 506.3324 506.4514 506.5703 506.6893 506.8082 506.9271 507.0459 507.1648 507.2836 507.4025 507.5213 507.6401 507.7588 507.8776 507.9963 508.1151 508.2338 508.3525 508.4711 508.5898 508.7084 508.8270 508.9456 509.0642 509.1828 509.3013 509.4199 509.5384 509.6569 509.7753 509.8938 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250813T113401.1Z 9356.481957 203 1 16.80 2 88.56 71.67 43.43 225.53 0.00 1 0.00 1 0 22 7.663e-03 7.508e-03 6.912e-04 6.878e-04 2.197819e+04 5.264333e+01 1.407164e+03 -6.000000e+00 4.447735e+02 289.49 -2.00 20.00 -2.00 505.45 0.00e+00 2.764303e-03 1.968241e-05 1.879068e-04 -6.000000e+00 2.202138e-04 289.49 -2.00 20.00 -2.00 501.08 0.00e+00 1.302395e+00 1.339003e-02 1.314647e-01 -6.000000e+00 1.538980e-01 231.98 -2.00 3.53 -2.00 502.57 0.00e+00 17.398 0.099 489.00 513.00 1 3.8308e+00 1.0260e-03 3.1162e-02 -6.0000e+00 1.1828e-02 -7.3165e-02 2.5581e-04 3.6188e-03 -6.0000e+00 3.0634e-03 2.9992e-03 1.9664e-04 6.3194e-05 1.5426e-04 -6.0000e+00 8.2815e-04 2.2601e-03 1.0496e-05 12 9 9 12 1 1 -2.01 25.28 6.27 0.00226 0.00362 29 54 1 4 0 559.670 34.25 19.89 25.28 21.00 0.0 1009.32 -142 93 570 1095 1516 1841 2046 2027 1823 1432 1016 513 77 119 -252 -186 55 120 386 454 444 477 492 586 602 392 437 -80 -501 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620 529 -8 -498 -967 -1328 -1650 -1460 -1112 -862 -610 -640 -737 -665 -552 -426 -301 -71 186 579 1045 1329 1476 1486 1108 856 635 510 663 662 917 848 900 866 611 418 431 3 -37 -235 -187 -101 113 361 416 586 554 507 614 608 533 368 39 -358 -765 -731 SQ 20250813T113824.5Z 9356.485006 208 1 29.96 2 87.79 72.40 43.98 226.85 0.00 1 0.00 1 0 22 5.391e-03 5.298e-03 2.443e-04 2.435e-04 1.901710e+04 1.836504e+01 1.222493e+03 -6.000000e+00 3.128982e+02 289.49 -2.00 20.00 -2.00 505.41 0.00e+00 2.167160e-03 6.953228e-06 1.494431e-04 -6.000000e+00 1.549208e-04 289.49 -2.00 20.00 -2.00 500.96 0.00e+00 1.254120e+00 4.769368e-03 1.149018e-01 -6.000000e+00 1.082683e-01 231.98 -2.00 3.53 -2.00 502.47 0.00e+00 15.380 0.069 489.00 513.00 1 2.6996e+00 3.6579e-04 2.6295e-02 -6.0000e+00 8.3211e-03 -5.9883e-02 9.1516e-05 3.1253e-03 -6.0000e+00 2.1551e-03 1.2591e-02 1.7462e-04 2.2863e-05 1.3350e-04 -6.0000e+00 5.8261e-04 4.4942e-03 -3.8621e-06 12 8 8 10 0 0 51.17 25.28 3.71 0.00449 0.00571 204 204 1 4 0 146.820 34.25 19.88 25.28 21.21 0.0 1009.72 -229 -45 282 649 947 1351 1431 1365 1203 1019 669 343 77 -74 -156 -133 19 96 273 235 229 260 342 376 471 461 231 -11 -283 -709 -798 -655 -480 -179 -104 -149 -247 -317 -434 -438 -310 -215 -9 195 348 369 184 40 -287 -602 -941 -1114 -1154 -1023 -659 -341 -200 -42 107 235 263 407 338 302 259 123 -94 -273 -404 -494 -515 -515 -331 -240 -239 -338 -552 -616 -608 -717 -747 -642 -529 -419 -420 -457 -411 -380 -213 -49 159 311 462 500 444 373 85 -357 -677 -1072 -1204 -1126 -938 -607 -436 -478 -463 -416 -347 -272 -207 -94 141 465 754 987 1023 944 753 531 478 412 434 525 607 554 579 548 340 349 298 14 -94 -126 -212 8 168 178 276 378 336 306 377 394 321 213 23 -259 -515 -532 -201 -40 259 599 876 1277 1378 1298 1146 966 644 327 72 -70 -146 -126 18 92 267 228 223 255 336 373 470 461 231 -11 -276 -692 -769 -634 -462 -178 -103 -150 -249 -317 -431 -433 -307 -215 -10 195 352 375 187 41 -285 -600 -917 -1091 -1122 -1004 -646 -343 -202 -42 109 240 269 419 343 306 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1.6743e-05 1.1916e-04 -6.0000e+00 4.7715e-04 4.9217e-03 -4.3846e-06 11 8 0 10 0 0 47.19 25.28 2.73 0.00492 0.00504 347 347 1 4 0 86.330 34.25 19.88 25.28 21.29 0.0 1010.21 -256 -67 185 460 761 1078 1180 1047 979 854 505 260 56 -89 -159 -195 -14 100 212 201 178 227 240 358 447 419 194 -25 -241 -582 -656 -509 -353 -158 -60 -148 -204 -224 -351 -396 -271 -118 13 150 267 333 177 22 -201 -482 -718 -871 -954 -825 -548 -319 -204 -41 85 199 294 308 311 260 232 150 -10 -257 -285 -372 -426 -380 -311 -212 -189 -289 -436 -547 -541 -562 -645 -573 -507 -388 -344 -380 -383 -298 -174 12 172 234 399 467 400 296 53 -279 -561 -906 -988 -873 -721 -476 -386 -390 -391 -318 -300 -167 -138 -79 145 377 603 795 877 813 560 411 376 357 369 439 494 406 478 468 324 259 234 32 -86 -60 -187 -79 103 113 204 329 295 275 316 337 280 123 8 -259 -443 -435 -232 -60 171 429 715 1034 1130 1014 950 823 483 252 54 -85 -150 -186 -13 97 206 198 177 227 240 360 442 416 192 -24 -238 -561 -636 -496 -344 -155 -61 -148 -208 -227 -352 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