File name: Pandora285s1_AmesIA_20250818_L2Fit_fout2c2d20250320p1-8.txt File generation date: 20250828T142708.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 285 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora285_OF_v1d20240703.txt Instrument calibration file used: Pandora285s1_CF_v2d20250320.txt Level 1 file used: Pandora285s1_AmesIA_20250818_L1_smca1c2d20250320p1-8.txt Full location name: AmesIowa-KelleyFields Short location name: AmesIA Country of location: USA Location latitude [deg]: 42.0250 Location longitude [deg]: -93.7152 Location altitude [m]: 5 Local noon date: 20250818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0768 305.2175 305.3583 305.4990 305.6397 305.7804 305.9211 306.0618 306.2024 306.3431 306.4837 306.6244 306.7650 306.9056 307.0462 307.1868 307.3274 307.4680 307.6085 307.7491 307.8896 308.0301 308.1706 308.3111 308.4516 308.5921 308.7326 308.8730 309.0135 309.1539 309.2943 309.4347 309.5751 309.7155 309.8559 309.9963 310.1366 310.2770 310.4173 310.5576 310.6979 310.8382 310.9785 311.1188 311.2591 311.3993 311.5396 311.6798 311.8200 311.9602 312.1004 312.2406 312.3808 312.5210 312.6611 312.8013 312.9414 313.0815 313.2216 313.3617 313.5018 313.6419 313.7820 313.9220 314.0621 314.2021 314.3421 314.4821 314.6221 314.7621 314.9021 315.0420 315.1820 315.3219 315.4619 315.6018 315.7417 315.8816 316.0215 316.1613 316.3012 316.4411 316.5809 316.7207 316.8605 317.0003 317.1401 317.2799 317.4197 317.5595 317.6992 317.8389 317.9787 318.1184 318.2581 318.3978 318.5375 318.6771 318.8168 318.9564 319.0961 319.2357 319.3753 319.5149 319.6545 319.7941 319.9336 320.0732 320.2127 320.3523 320.4918 320.6313 320.7708 320.9103 321.0498 321.1892 321.3287 321.4681 321.6076 321.7470 321.8864 322.0258 322.1652 322.3045 322.4439 322.5832 322.7226 322.8619 323.0012 323.1405 323.2798 323.4191 323.5584 323.6976 323.8369 323.9761 324.1153 324.2545 324.3937 324.5329 324.6721 324.8113 324.9504 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250818T143452.0Z 9361.607546 332 1 30.94 2 56.31 103.90 14.34 199.19 0.00 1 0.00 1 0 25 1.935e-02 9.205e-03 1.360e-02 4.703e-03 2.276421e-01 2.407356e-03 2.761307e-03 -6.000000e+00 1.127551e-02 231.66 -2.00 3.53 -2.00 317.28 0.00e+00 8.326398e-04 3.443292e-04 1.810668e-04 -6.000000e+00 5.037451e-04 289.34 -2.00 20.00 -2.00 316.43 0.00e+00 1.797 0.000 302.00 328.00 3 6.2303e+00 6.3909e-03 2.1689e-02 -6.0000e+00 2.8210e-02 3.2613e-02 7.1788e-03 1.2060e-02 -6.0000e+00 3.0492e-02 5.0724e-03 4.2305e-03 5.8410e-03 -6.0000e+00 1.8179e-02 -6.6458e-03 2.0612e-03 1.6441e-03 -6.0000e+00 7.7055e-03 1.3154e-04 -2.4588e-05 1.3858e-04 1.8404e-05 -6.0000e+00 5.3058e-04 -1.1744e-02 0.0000e+00 11 8 0 10 0 0 99.64 27.30 0.43 -0.01174 -0.01193 9 9 1 5 0 3436.490 35.75 20.00 27.30 26.58 0.0 1031.39 4483 6117 -4644 -8639 -4893 -5862 3724 -2036 -3967 -1073 -2203 6049 -1615 904 2737 780 442 2528 -491 -2652 2719 -703 1670 -2903 607 1815 803 1011 -64 -1264 421 -1296 2349 541 -3548 -5437 -3922 880 -339 91 -966 -175 -1088 -19 -204 881 743 -1387 -1021 -472 276 336 1051 -38 621 1560 1339 -2103 518 248 956 1451 2662 2558 1003 439 -750 -1814 -781 1053 1371 1411 611 792 919 -1625 -1165 -2303 -293 -1471 -1964 -1603 -2203 -733 -1206 53 644 -90 911 1226 573 383 -2184 -1230 -1010 -1132 520 750 483 215 320 -1377 -1926 -909 -189 -1324 -316 -181 383 604 1872 1228 472 502 -567 -591 -338 -507 -251 -316 -162 305 567 186 248 225 -508 27 206 278 655 223 -626 255 607 -137 159 467 107 -85 -521 -250 -887 537 783 -673 -1212 -586 -678 413 -267 -588 -161 -329 849 -273 170 571 181 107 619 -129 -733 724 -192 453 -867 183 560 249 294 -17 -342 118 -395 743 178 -1139 -1738 -1346 334 -156 48 -515 -96 -623 -11 -116 546 451 -835 -597 -274 167 217 645 -25 414 1047 915 -1482 349 167 658 1065 2090 2131 843 342 -545 -1291 -581 866 1232 1325 579 724 782 -1277 -904 -1706 -220 -1249 -1707 -1529 -2256 -774 -1370 64 813 -118 1191 1541 671 409 -2184 -1169 -1001 -1233 618 982 673 296 414 -1674 -2227 -1069 -240 -1798 -444 -243 537 895 2877 1920 716 708 -807 -788 -446 -697 -369 -455 -240 446 808 278 351 304 -656 35 278 400 986 346 -996 382 957 -230 273 819 190 -148 -879 -407 -1421 SS 20250818T154005.5Z 9361.652842 375 1 12.83 2 45.03 118.46 21.96 238.20 0.00 1 0.00 1 0 17 9.686e-03 7.354e-03 2.548e-03 1.698e-03 1.786592e-01 8.869472e-04 2.155115e-03 -6.000000e+00 5.647175e-03 231.65 -2.00 3.53 -2.00 315.09 0.00e+00 4.571997e-04 7.826421e-05 3.640006e-05 -6.000000e+00 2.520978e-04 289.34 -2.00 20.00 -2.00 314.38 0.00e+00 1.413 0.000 302.00 328.00 3 4.4483e+00 2.2900e-03 1.6985e-02 -6.0000e+00 1.4129e-02 1.0953e-02 2.5373e-03 9.3486e-03 -6.0000e+00 1.5268e-02 7.2565e-04 1.4506e-03 4.5118e-03 -6.0000e+00 9.1025e-03 -3.9527e-03 6.3940e-04 1.2508e-03 -6.0000e+00 3.8618e-03 1.2641e-03 -8.9297e-05 4.8509e-05 1.6496e-05 -6.0000e+00 2.6546e-04 -1.7375e-02 0.0000e+00 12 9 1 12 1 1 99.78 27.74 0.36 -0.01737 -0.01805 14 35 1 5 0 854.520 36.25 20.01 27.74 29.28 0.0 1042.27 338 354 -33 -1876 -3859 -1449 -858 -125 924 -378 -1736 -2022 -1104 474 60 136 268 231 1219 1302 1597 852 1209 1175 397 1278 603 -929 -634 135 975 1552 1716 -1284 -2917 -2358 -2382 -1481 -327 256 -678 -510 -171 -592 70 19 -665 -276 -589 -512 201 535 756 1091 675 624 998 60 118 54 844 1236 1820 1993 679 -540 -722 -1104 104 586 768 670 236 754 430 -244 -1564 -1520 -1335 -1507 -1312 -1496 -1878 -1256 -935 -338 37 684 906 936 692 32 -761 -295 -461 -157 280 796 459 212 -307 -1054 -1074 -150 -572 -696 -835 -563 -36 689 828 831 439 446 -173 -344 -140 -92 231 180 64 240 154 402 586 201 6 503 255 185 -83 -281 -377 -36 201 -8 143 642 124 -16 -98 -652 -952 105 118 -11 -599 -1105 -418 -258 -38 308 -133 -604 -706 -417 183 26 63 129 113 608 621 771 409 586 595 212 696 329 -481 -324 66 490 819 894 -703 -1514 -1271 -1291 -919 -223 189 -518 -404 -139 -485 57 15 -525 -209 -460 -394 160 423 626 942 567 532 860 52 101 45 730 1136 1696 1956 668 -521 -637 -993 91 575 782 679 241 783 421 -228 -1410 -1279 -1144 -1354 -1312 -1559 -1988 -1383 -1044 -403 45 844 1122 1121 806 36 -819 -299 -486 -171 319 993 580 265 -382 -1225 -1242 -177 -700 -863 -1084 -728 -48 966 1160 1174 624 588 -220 -426 -171 -117 299 240 88 330 207 542 745 255 8 598 319 234 -110 -383 -520 -49 288 -11 214 977 191 -25 -145 -938 -1401 SS 20250818T154918.4Z 9361.659240 378 1 30.15 2 43.55 120.88 23.40 241.69 0.00 1 0.00 1 0 17 9.417e-03 7.203e-03 1.513e-03 9.909e-04 1.743203e-01 5.149286e-04 2.111871e-03 -6.000000e+00 5.491277e-03 231.65 -2.00 3.53 -2.00 315.16 0.00e+00 5.761178e-04 4.623667e-05 3.529341e-05 -6.000000e+00 2.450996e-04 289.34 -2.00 20.00 -2.00 314.45 0.00e+00 1.378 0.000 302.00 328.00 3 4.2765e+00 1.3323e-03 1.6580e-02 -6.0000e+00 1.3739e-02 1.9359e-02 1.4777e-03 9.1581e-03 -6.0000e+00 1.4845e-02 1.4180e-03 8.4323e-04 4.4191e-03 -6.0000e+00 8.8509e-03 -5.1134e-03 3.7264e-04 1.2423e-03 -6.0000e+00 3.7557e-03 1.5613e-03 -8.7827e-05 2.8403e-05 1.5941e-05 -6.0000e+00 2.5808e-04 -1.8367e-02 0.0000e+00 11 8 0 10 0 0 99.97 27.81 0.27 -0.01837 -0.01903 64 64 1 5 0 470.940 36.25 20.00 27.81 29.67 0.0 1044.33 603 257 -414 -2331 -2866 -2121 -1398 376 868 -349 -1857 -1225 -727 122 774 416 294 633 1198 1623 698 62 971 1220 714 954 420 -575 -382 -128 683 1558 1688 -517 -2548 -2839 -2584 -1432 -328 -141 -526 -289 -461 -743 -410 -237 -539 -562 -983 -570 561 696 931 912 870 950 994 284 31 60 833 1224 1844 1936 653 -252 -597 -1009 94 860 529 571 451 598 293 -360 -1134 -1809 -1185 -1112 -1425 -1554 -2019 -1402 -801 -466 225 592 723 704 493 269 -570 -475 -322 -141 542 994 481 19 -157 -1103 -935 -356 -765 -935 -707 -594 -85 687 684 669 501 285 -242 -121 -417 -139 131 325 74 324 429 393 554 405 66 571 357 205 97 -179 -239 -11 -20 102 -8 339 153 -69 -179 -661 -736 187 86 -130 -753 -818 -568 -389 114 289 -123 -647 -424 -250 47 328 192 139 305 590 756 333 30 462 604 370 508 223 -289 -191 -62 337 804 854 -273 -1279 -1499 -1359 -859 -215 -100 -408 -232 -380 -619 -338 -194 -432 -433 -734 -419 423 555 777 746 730 808 857 246 26 51 721 1125 1812 1885 638 -242 -525 -854 82 836 533 603 479 615 283 -335 -1019 -1527 -1013 -985 -1412 -1592 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