File name: Pandora285s1_AmesIA_20250819_L2Fit_fout2c2d20250320p1-8.txt File generation date: 20250828T142723.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 285 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora285_OF_v1d20240703.txt Instrument calibration file used: Pandora285s1_CF_v2d20250320.txt Level 1 file used: Pandora285s1_AmesIA_20250819_L1_smca1c2d20250320p1-8.txt Full location name: AmesIowa-KelleyFields Short location name: AmesIA Country of location: USA Location latitude [deg]: 42.0250 Location longitude [deg]: -93.7152 Location altitude [m]: 5 Local noon date: 20250819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0768 305.2175 305.3583 305.4990 305.6397 305.7804 305.9211 306.0618 306.2024 306.3431 306.4837 306.6244 306.7650 306.9056 307.0462 307.1868 307.3274 307.4680 307.6085 307.7491 307.8896 308.0301 308.1706 308.3111 308.4516 308.5921 308.7326 308.8730 309.0135 309.1539 309.2943 309.4347 309.5751 309.7155 309.8559 309.9963 310.1366 310.2770 310.4173 310.5576 310.6979 310.8382 310.9785 311.1188 311.2591 311.3993 311.5396 311.6798 311.8200 311.9602 312.1004 312.2406 312.3808 312.5210 312.6611 312.8013 312.9414 313.0815 313.2216 313.3617 313.5018 313.6419 313.7820 313.9220 314.0621 314.2021 314.3421 314.4821 314.6221 314.7621 314.9021 315.0420 315.1820 315.3219 315.4619 315.6018 315.7417 315.8816 316.0215 316.1613 316.3012 316.4411 316.5809 316.7207 316.8605 317.0003 317.1401 317.2799 317.4197 317.5595 317.6992 317.8389 317.9787 318.1184 318.2581 318.3978 318.5375 318.6771 318.8168 318.9564 319.0961 319.2357 319.3753 319.5149 319.6545 319.7941 319.9336 320.0732 320.2127 320.3523 320.4918 320.6313 320.7708 320.9103 321.0498 321.1892 321.3287 321.4681 321.6076 321.7470 321.8864 322.0258 322.1652 322.3045 322.4439 322.5832 322.7226 322.8619 323.0012 323.1405 323.2798 323.4191 323.5584 323.6976 323.8369 323.9761 324.1153 324.2545 324.3937 324.5329 324.6721 324.8113 324.9504 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250819T123227.7Z 9362.522543 220 1 30.69 2 79.04 82.87 35.03 101.47 0.00 1 0.00 1 0 25 3.009e-01 1.602e-02 3.456e-01 1.245e-02 5.925878e-01 6.702047e-03 6.849100e-03 -6.000000e+00 1.751442e-01 231.58 -2.00 3.53 -2.00 320.96 0.00e+00 2.655826e-03 3.006643e-03 2.516434e-03 -6.000000e+00 7.994943e-03 289.27 -2.00 20.00 -2.00 320.29 0.00e+00 5.067 0.002 302.00 328.00 3 3.9370e+00 2.2308e-02 6.0551e-02 -6.0000e+00 4.3808e-01 2.0063e-01 2.9275e-02 3.4634e-02 -6.0000e+00 4.7381e-01 -1.6640e-01 2.6650e-02 1.7440e-02 -6.0000e+00 2.8262e-01 5.7133e-02 1.2994e-02 4.9428e-03 -6.0000e+00 1.2100e-01 3.3480e-05 -6.4718e-04 3.6366e-04 6.8903e-05 -6.0000e+00 8.3102e-03 -6.8724e-03 0.0000e+00 12 8 8 10 0 0 97.91 26.87 0.44 -0.00687 -0.01174 9 9 1 5 0 3409.510 35.50 20.00 26.87 28.35 0.0 1038.44 900000 -143657 900000 -83654 -52438 -138806 23066 35404 87666 3300 -51620 -84347 -69351 -58513 -24595 14468 -47953 -77887 -61998 24901 20709 -27955 38361 5947 -65480 -30138 2006 112332 95 -24820 51731 -11976 -42080 3014 22742 10496 -35889 -24919 -18355 20353 -98 -10097 1620 6049 10380 75 10697 -9394 5779 1928 6914 10469 528 5447 3359 9985 4317 -742 -843 3724 7640 6771 9240 933 289 -1691 11051 2597 1013 -1217 4620 3297 9778 1884 1771 -2106 3265 -2576 -4226 -3681 -3476 -2201 -1245 -3965 -217 584 1126 661 -996 2685 -698 -713 -3851 -660 332 -3342 -2406 3141 1903 1085 -1734 -1254 -2064 -2399 -1269 -1954 301 -260 953 -299 1010 1241 -116 -1603 -805 -691 234 313 -188 -1491 -208 2025 2184 2341 466 -338 -578 206 683 156 -985 -784 455 -114 -530 719 1246 264 629 297 -1391 -932 -792 900000 -2536 900000 -1015 -637 -2144 280 430 1064 40 -627 -1303 -1148 -1098 -407 192 -1323 -3180 -2326 412 366 -802 593 138 -3324 -1131 55 1364 3 -994 1130 -582 -3167 154 911 471 -2832 -2087 -1760 1581 -10 -1275 191 698 1159 10 1234 -1357 744 274 1032 1677 102 1084 722 2085 980 -176 -195 814 1660 1627 2445 299 97 -562 3166 829 360 -508 2008 1517 4178 826 711 -790 1078 -904 -1667 -1698 -1861 -1322 -810 -2811 -158 452 912 554 -849 2125 -532 -506 -2692 -455 251 -3006 -2468 3473 2310 1326 -2050 -1340 -2044 -2399 -1349 -2215 352 -327 1286 -412 1508 1945 -183 -2479 -1163 -1047 353 448 -286 -2410 -332 3061 3504 3614 702 -494 -817 299 1094 255 -1776 -1500 899 -239 -1193 1685 2979 648 1540 704 -3169 -2001 -1645 SS 20250819T123800.8Z 9362.526399 223 1 29.70 2 78.02 83.77 34.05 102.68 0.00 1 0.00 1 0 17 2.937e-01 1.100e-02 2.112e-01 6.589e-03 5.477146e-01 3.480585e-03 6.265964e-03 -6.000000e+00 1.721289e-01 231.58 -2.00 3.53 -2.00 320.69 0.00e+00 2.037021e-03 1.437613e-03 3.630234e-04 -6.000000e+00 7.658912e-03 289.27 -2.00 20.00 -2.00 319.97 0.00e+00 4.668 0.002 302.00 328.00 3 3.5886e+00 1.1217e-02 5.5063e-02 -6.0000e+00 4.3067e-01 8.9542e-02 1.4397e-02 2.9500e-02 -6.0000e+00 4.6583e-01 -1.0870e-01 1.2834e-02 1.4675e-02 -6.0000e+00 2.7676e-01 4.1652e-02 6.3308e-03 4.8359e-03 -6.0000e+00 1.1678e-01 7.6549e-05 -4.8252e-04 1.9379e-04 5.3195e-05 -6.0000e+00 8.1371e-03 -6.9136e-03 0.0000e+00 12 8 8 10 0 0 99.27 26.93 0.23 -0.00691 -0.01054 15 15 1 5 0 1979.310 35.50 20.01 26.93 28.49 0.0 1038.96 -100159 -126703 -92822 -96838 -3911 -15834 900000 -157758 -16426 -97806 -36037 -44480 -76532 -13724 124648 -29825 -56938 -23406 16741 -4739 11429 -40462 47417 -4943 -23307 -12226 242 -25845 9906 -3605 -2367 15730 27498 -4268 8386 -10242 -1020 10450 5090 -435 -4629 5903 -4597 9991 8718 1556 1120 6095 2004 -7163 -990 906 4518 6344 4787 1042 -2706 7115 3714 2142 2491 2921 5659 4138 -550 -1292 -735 868 1914 1986 1050 453 752 537 -855 3681 -2941 -854 -222 -35 -3275 -3279 -2561 -528 -2273 -1122 69 2316 348 1344 1392 1363 -414 247 -2012 -978 216 1244 119 304 -127 -1469 -600 -1300 -2393 -1427 -1125 -287 346 544 1170 912 495 -421 -684 -403 -300 -71 -467 -211 -76 280 416 1024 73 264 503 122 621 422 197 -15 -71 194 422 -295 -295 957 -7 88 -275 -446 -919 -1287 -2442 -1355 -1414 -25 -102 900000 -4699 -134 -1942 -400 -657 -1918 -229 801 -843 -2341 -752 387 -143 301 -1794 914 -175 -1063 -526 9 -1245 325 -144 -108 697 1237 -280 463 -678 -68 739 464 -50 -622 762 -691 1329 1187 232 170 897 317 -1312 -188 187 978 1459 1181 277 -768 1828 964 559 671 858 1818 1497 -216 -494 -272 322 770 916 540 245 403 274 -407 1506 -1192 -338 -96 -17 -1980 -2248 -1902 -407 -1739 -909 58 1967 302 1114 1074 1076 -316 190 -1740 -870 217 1410 148 375 -148 -1582 -593 -1307 -2621 -1640 -1360 -367 475 825 1766 1446 783 -644 -1075 -602 -449 -111 -778 -338 -122 474 682 1607 110 384 705 177 989 685 349 -28 -140 401 925 -687 -650 2126 -17 207 -614 -949 -1909 SS 20250819T124323.0Z 9362.530127 226 1 30.23 2 77.03 84.65 33.11 103.89 0.00 1 0.00 1 0 17 2.715e-01 1.436e-02 1.885e-01 7.982e-03 5.101005e-01 4.221011e-03 5.931329e-03 -6.000000e+00 1.580212e-01 231.58 -2.00 3.53 -2.00 320.44 0.00e+00 1.408514e-03 1.590655e-03 1.206999e-03 -6.000000e+00 7.062590e-03 289.27 -2.00 20.00 -2.00 319.71 0.00e+00 4.337 0.001 302.00 328.00 3 4.1375e+00 1.3187e-02 5.1433e-02 -6.0000e+00 3.9528e-01 9.4844e-02 1.6446e-02 2.8046e-02 -6.0000e+00 4.2737e-01 -8.1874e-02 1.3901e-02 1.3872e-02 -6.0000e+00 2.5479e-01 2.7517e-02 6.9667e-03 3.9538e-03 -6.0000e+00 1.0794e-01 6.2412e-05 -1.5510e-04 2.3656e-04 5.3598e-05 -6.0000e+00 7.4433e-03 -7.7829e-03 0.0000e+00 12 9 9 12 1 1 99.86 27.00 0.28 -0.00778 -0.00895 9 10 1 5 0 3022.910 35.75 20.01 27.00 28.62 0.0 1039.36 -57921 -32137 -33022 -121290 51205 -70562 -159683 -113445 -118249 -60003 -21777 -39464 -11621 -13773 -58335 -8897 -9123 57403 -22186 -13598 8920 2629 -11751 9266 3521 -15658 -8913 16623 -15110 -5650 -6174 5439 -708 -7352 55415 -16329 -28084 11783 3969 7734 -4447 3327 6290 18457 6367 3771 -3203 -1858 3070 4261 -381 6003 -2970 5155 4095 5793 2713 3267 -2145 -920 2500 3027 3597 8384 27 985 182 -112 -2013 3845 964 5543 270 2558 1356 -3099 -3697 -2483 -3721 -4735 -1289 -3528 -664 -22 -94 -524 175 -566 1615 2490 -381 -939 -2154 -1863 -1241 -1823 399 1088 225 -114 -557 -819 -1556 1144 -1273 -2513 -416 66 -193 -696 1238 1361 241 -300 -1219 -143 -1155 -1027 -117 527 1164 917 672 71 -14 675 2376 -270 -173 1164 -318 536 -903 148 376 39 121 1097 -63 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