File name: Pandora285s1_AmesIA_20250822_L2Fit_fout2c2d20250320p1-8.txt File generation date: 20250828T143254.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 285 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora285_OF_v1d20240703.txt Instrument calibration file used: Pandora285s1_CF_v2d20250320.txt Level 1 file used: Pandora285s1_AmesIA_20250822_L1_smca1c2d20250320p1-8.txt Full location name: AmesIowa-KelleyFields Short location name: AmesIA Country of location: USA Location latitude [deg]: 42.0250 Location longitude [deg]: -93.7152 Location altitude [m]: 5 Local noon date: 20250822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0768 305.2175 305.3583 305.4990 305.6397 305.7804 305.9211 306.0618 306.2024 306.3431 306.4837 306.6244 306.7650 306.9056 307.0462 307.1868 307.3274 307.4680 307.6085 307.7491 307.8896 308.0301 308.1706 308.3111 308.4516 308.5921 308.7326 308.8730 309.0135 309.1539 309.2943 309.4347 309.5751 309.7155 309.8559 309.9963 310.1366 310.2770 310.4173 310.5576 310.6979 310.8382 310.9785 311.1188 311.2591 311.3993 311.5396 311.6798 311.8200 311.9602 312.1004 312.2406 312.3808 312.5210 312.6611 312.8013 312.9414 313.0815 313.2216 313.3617 313.5018 313.6419 313.7820 313.9220 314.0621 314.2021 314.3421 314.4821 314.6221 314.7621 314.9021 315.0420 315.1820 315.3219 315.4619 315.6018 315.7417 315.8816 316.0215 316.1613 316.3012 316.4411 316.5809 316.7207 316.8605 317.0003 317.1401 317.2799 317.4197 317.5595 317.6992 317.8389 317.9787 318.1184 318.2581 318.3978 318.5375 318.6771 318.8168 318.9564 319.0961 319.2357 319.3753 319.5149 319.6545 319.7941 319.9336 320.0732 320.2127 320.3523 320.4918 320.6313 320.7708 320.9103 321.0498 321.1892 321.3287 321.4681 321.6076 321.7470 321.8864 322.0258 322.1652 322.3045 322.4439 322.5832 322.7226 322.8619 323.0012 323.1405 323.2798 323.4191 323.5584 323.6976 323.8369 323.9761 324.1153 324.2545 324.3937 324.5329 324.6721 324.8113 324.9504 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250822T121312.3Z 9365.509170 72 1 28.80 2 83.10 80.60 74.70 81.56 0.00 1 0.00 1 0 25 5.747e-01 3.519e-02 4.365e-01 2.655e-02 7.723942e-01 1.500264e-02 1.006085e-02 -6.000000e+00 3.364030e-01 231.32 -2.00 3.53 -2.00 321.90 0.00e+00 1.175494e-02 7.833325e-03 8.239403e-03 -6.000000e+00 1.625222e-02 289.03 -2.00 20.00 -2.00 321.31 0.00e+00 7.609 0.008 302.00 328.00 3 2.0521e+00 5.6312e-02 9.2967e-02 -6.0000e+00 8.4213e-01 1.0955e+00 7.2134e-02 5.7417e-02 -6.0000e+00 9.1226e-01 -1.3000e+00 5.3588e-02 3.1857e-02 -6.0000e+00 5.4067e-01 5.1516e-01 2.5595e-02 1.1297e-02 -6.0000e+00 2.2917e-01 1.4136e-05 -9.7255e-04 7.5154e-04 2.6019e-04 -6.0000e+00 1.6515e-02 2.3620e-03 0.0000e+00 12 9 9 12 1 1 87.94 25.63 0.21 0.00236 -0.00495 8 9 1 5 0 3198.880 34.50 20.00 25.63 23.84 0.0 1019.39 11129 180136 -40596 900000 900000 67420 -75636 900000 200436 -59114 900000 94720 -55702 -91741 202636 -23004 45394 79504 44751 51231 -52206 30076 103946 -43557 -63127 -31122 204613 -46063 -117557 -54757 10117 53220 26856 -23237 -29013 -24020 119917 118551 32287 54559 222816 21684 188418 18390 58537 63972 -17592 72551 9424 26072 182919 26227 17748 8588 57433 35923 6664 4898 -6758 28674 64287 -8932 31411 23018 16173 -1139 -7600 8634 -3217 28511 27409 23413 47624 5359 18383 -11410 -13280 10313 20052 3513 -14038 3310 -3565 12110 5366 -1754 -11416 1526 3429 7806 -363 2618 4794 -3913 -3188 -5339 520 -1878 -2940 -3712 -2398 -4732 -6462 608 -4031 -3681 -419 8395 520 548 -1100 -927 -2183 -1968 -177 -1039 911 -839 3033 3102 -232 1615 1230 1652 959 3151 -611 3008 -3297 -101 2288 -1470 -1028 -171 884 1552 441 -918 1595 745 -559 -47 -3775 288 4661 -1576 900000 900000 1744 -2847 900000 5186 -1808 900000 2451 -2227 -6690 5243 -1190 1281 2057 1368 1446 -3930 920 2690 -2664 -4603 -1611 5294 -2492 -12720 -3478 405 1627 1200 -1749 -2116 -1582 3103 3068 1671 2567 5765 1581 4875 1428 3029 3160 -1986 3755 951 2361 4733 2850 2250 1267 5350 4183 1035 748 -1102 3190 5157 -1641 4389 3931 3097 -253 -1790 1787 -824 6049 6383 5816 8996 1428 3853 -2864 -3196 2028 4099 1018 -5703 1293 -1633 5014 2527 -939 -7030 845 1854 3878 -182 1199 2096 -1964 -1815 -3661 395 -1696 -2936 -3746 -2240 -4065 -5133 450 -3348 -3229 -378 7538 562 676 -1548 -1396 -3377 -2969 -251 -1441 1259 -1242 4583 4848 -369 2419 1783 2304 1298 4044 -797 4009 -5357 -181 4463 -3213 -2376 -417 2292 3818 1120 -2398 4438 1993 -1415 -110 -8888 SS 20250822T122402.6Z 9365.516697 75 1 29.90 2 81.11 82.38 72.79 83.26 0.00 1 0.00 1 0 33 4.866e-01 1.056e-02 1.644e-01 4.039e-03 6.821889e-01 2.198148e-03 7.887646e-03 -6.000000e+00 2.826093e-01 231.32 -2.00 3.53 -2.00 321.30 0.00e+00 1.941917e-03 1.126597e-03 3.212743e-03 -6.000000e+00 1.271126e-02 289.03 -2.00 20.00 -2.00 320.67 0.00e+00 6.119 0.004 302.00 328.00 3 1.3522e+00 7.8722e-03 7.2868e-02 -6.0000e+00 7.0649e-01 1.6738e-01 1.0911e-02 4.2168e-02 -6.0000e+00 7.6460e-01 -2.2434e-01 1.0504e-02 2.0729e-02 -6.0000e+00 4.5582e-01 8.1953e-02 4.9284e-03 5.5268e-03 -6.0000e+00 1.9407e-01 1.6099e-04 -3.0514e-04 1.1420e-04 9.4051e-05 -6.0000e+00 1.3423e-02 1.6534e-03 0.0000e+00 12 8 8 10 0 0 51.52 25.81 0.47 0.00165 -0.00064 76 76 1 5 0 393.360 34.75 20.00 25.81 24.07 0.0 1020.37 900000 -158475 -196351 -138498 -189012 -81948 -190973 -192923 -106331 -107851 -145666 -121659 -109254 -94800 -66567 -5369 -58191 -63748 -17908 -32073 -51772 -54745 -56963 -37378 -12229 -27209 -73370 -59459 -9163 -63366 -27845 -18589 -20186 -18032 -5183 -16510 -3163 -389 -2359 -524 9495 6036 3890 50 4333 4426 11760 2443 6912 5496 8265 7867 5069 3674 4074 9817 6158 3067 1543 6873 630 7559 4912 7392 1849 2560 2207 2185 580 2620 2893 4372 2603 1176 1538 -3557 -4213 -6218 -2398 -2705 -204 -1122 -1535 -861 -90 -594 87 1307 1694 1320 152 158 -1749 -737 -955 -1524 -103 793 -239 -1030 -822 -1256 -1275 -846 -1789 -1661 -1113 -542 -82 677 469 551 785 209 -345 -794 -558 413 -17 154 77 724 1033 689 319 456 156 767 366 -49 -57 -225 -505 288 -123 57 189 468 285 -283 -163 -418 -667 900000 -1418 -2741 -1041 -2165 -323 -2461 -2901 -761 -849 -1773 -1350 -1369 -1324 -970 -51 -1054 -1356 -261 -568 -1142 -1250 -1413 -839 -231 -632 -2745 -1873 -173 -2271 -844 -615 -787 -731 -178 -637 -120 -17 -131 -34 632 447 309 4 357 373 945 224 640 558 918 985 719 577 679 1616 1084 554 275 1148 116 1444 1101 1819 505 680 587 607 183 934 1134 1759 1052 454 540 -1181 -1327 -2052 -863 -1164 -100 -639 -876 -520 -58 -410 63 957 1233 928 101 98 -1080 -469 -688 -1286 -100 871 -264 -1144 -933 -1295 -1210 -808 -1857 -1823 -1288 -617 -102 941 726 902 1289 335 -526 -1174 -833 640 -28 264 131 1179 1621 1048 468 646 216 1110 602 -84 -108 -457 -1085 607 -279 136 461 1159 705 -677 -366 -890 -1489 SS 20250822T125904.1Z 9365.541020 92 1 30.18 2 74.64 88.14 66.55 88.88 0.00 1 0.00 1 0 17 7.229e-02 6.447e-03 3.300e-02 2.493e-03 4.392798e-01 1.286172e-03 5.118042e-03 -6.000000e+00 4.200945e-02 231.31 -2.00 3.53 -2.00 319.43 0.00e+00 8.459068e-04 3.549944e-04 6.325654e-04 -6.000000e+00 1.878052e-03 289.03 -2.00 20.00 -2.00 318.62 0.00e+00 3.703 0.001 302.00 328.00 3 3.2392e+00 3.6650e-03 4.3785e-02 -6.0000e+00 1.0503e-01 2.3282e-02 4.3264e-03 2.3496e-02 -6.0000e+00 1.1360e-01 -1.6402e-02 3.3007e-03 1.1429e-02 -6.0000e+00 6.7731e-02 1.5505e-03 1.7225e-03 3.1712e-03 -6.0000e+00 2.8685e-02 3.1158e-04 -9.7422e-05 7.2719e-05 3.5839e-05 -6.0000e+00 1.9820e-03 -3.8514e-03 0.0000e+00 11 8 0 10 0 0 96.87 26.18 0.34 -0.00385 -0.00458 30 30 1 5 0 1005.690 35.00 20.00 26.18 24.17 0.0 1020.85 -23550 -4164 -32168 -18425 -13985 -23560 -27925 -30579 -21869 -20772 -16899 -23256 -19668 -9043 -6907 -6492 562 -2913 600 -3623 -4655 -4685 4948 2565 -1682 -5013 -3406 -2798 -4347 -4847 -3464 3978 2156 -2636 -7863 -3227 -1225 -4115 193 1651 295 2078 -217 240 1183 1405 128 -441 170 -1162 1361 1213 1367 879 1135 2199 753 364 -618 -629 -56 1165 1405 2938 652 596 -595 -421 570 1265 1151 663 1020 786 -474 -635 -1581 -2253 -1963 -1840 -714 -1741 -2164 -1093 -717 188 471 854 763 874 505 339 -972 -255 -291 -343 405 653 223 -99 -475 -1106 -822 -272 -1015 -666 -470 -536 -194 450 614 554 393 70 -509 -534 -486 431 251 174 279 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