File name: Pandora207s1_ArlingtonTX_20221112_L2Fit_fout2c6d20221007p1-8.txt File generation date: 20240911T082443.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s1_CF_v6d20221007.txt Level 1 file used: Pandora207s1_ArlingtonTX_20221112_L1_smca1c6d20221007p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20221112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "But different Reference day, final winter reference" First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0775 305.2189 305.3602 305.5015 305.6428 305.7841 305.9254 306.0666 306.2079 306.3491 306.4904 306.6316 306.7728 306.9140 307.0552 307.1964 307.3375 307.4787 307.6198 307.7609 307.9021 308.0432 308.1843 308.3254 308.4664 308.6075 308.7485 308.8896 309.0306 309.1716 309.3126 309.4536 309.5946 309.7356 309.8765 310.0175 310.1584 310.2993 310.4403 310.5812 310.7220 310.8629 311.0038 311.1446 311.2855 311.4263 311.5671 311.7080 311.8488 311.9895 312.1303 312.2711 312.4118 312.5526 312.6933 312.8340 312.9747 313.1154 313.2561 313.3968 313.5375 313.6781 313.8188 313.9594 314.1000 314.2406 314.3812 314.5218 314.6624 314.8029 314.9435 315.0840 315.2245 315.3651 315.5056 315.6461 315.7865 315.9270 316.0675 316.2079 316.3484 316.4888 316.6292 316.7696 316.9100 317.0504 317.1907 317.3311 317.4714 317.6118 317.7521 317.8924 318.0327 318.1730 318.3133 318.4535 318.5938 318.7340 318.8743 319.0145 319.1547 319.2949 319.4351 319.5753 319.7154 319.8556 319.9957 320.1358 320.2760 320.4161 320.5562 320.6962 320.8363 320.9764 321.1164 321.2565 321.3965 321.5365 321.6765 321.8165 321.9565 322.0965 322.2364 322.3764 322.5163 322.6562 322.7962 322.9361 323.0759 323.2158 323.3557 323.4956 323.6354 323.7752 323.9151 324.0549 324.1947 324.3345 324.4742 324.6140 324.7538 324.8935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221112T132527.6Z 8351.559347 201 1 48.01 2 85.11 114.79 51.01 280.36 0.00 1 0.00 1 0 25 6.479e-01 7.355e-02 5.078e-01 6.435e-02 8.579687e-01 4.295704e-02 1.038196e-02 -6.000000e+00 4.591005e-01 224.94 -2.00 3.32 -2.00 321.85 0.00e+00 -1.581634e-02 1.525634e-02 8.849396e-03 -6.000000e+00 2.360088e-02 286.89 -2.00 20.00 -2.00 321.18 0.00e+00 9.976 0.014 302.00 328.00 3 2.4439e-01 1.4139e-01 1.1455e-01 -6.0000e+00 1.1258e+00 1.8087e+00 1.6825e-01 6.1399e-02 -6.0000e+00 1.2232e+00 -1.9074e+00 9.3170e-02 2.9669e-02 -6.0000e+00 7.2806e-01 6.8132e-01 4.7564e-02 8.6108e-03 -6.0000e+00 2.9898e-01 7.7384e-06 -1.8316e-04 2.3672e-03 3.9130e-04 -6.0000e+00 2.9167e-02 1.9122e-02 0.0000e+00 12 8 8 10 0 0 60.78 20.23 1.07 0.01912 0.01775 12 3 4 8 0 4000.000 15.00 20.23 8.51 21.06 20.96 8.9 863.16 900000 -22928 900000 -28549 900000 -8179 76070 900000 169160 -17240 -22821 900000 -67650 900000 308861 116241 26983 99668 83450 3474 63100 35240 900000 2474 900000 -48638 900000 -9705 113359 205380 139910 900000 -62802 900000 -13880 900000 27754 900000 177411 85397 260471 -13448 132052 -25360 26400 900000 44486 147803 23021 13507 -30331 900000 99084 113907 70443 65676 -10902 -12214 74391 115584 58985 -2512 900000 25662 64877 -20290 82443 -22876 18934 59689 24188 13236 33061 41868 -9091 51071 -11684 39269 -18387 15026 2190 -5930 81609 7431 20595 -10691 4759 -27992 44504 19484 28246 9758 -5165 -5773 -16449 15843 -8638 13137 -13788 12437 -3838 1489 2106 -327 12598 3673 8822 -15133 -5122 -5996 -491 -5878 6953 2765 -2051 10813 -12211 -4585 1950 1456 -2783 3313 2966 3623 12917 1484 8829 -3407 1299 655 769 928 -1085 1545 2963 2109 -512 2029 -4429 -1277 -3165 789 900000 -3346 900000 -3422 900000 -682 4757 900000 10579 -1797 -2616 900000 -13750 900000 19315 7269 2391 6233 5219 344 3946 2387 900000 267 900000 -8572 900000 -993 7089 12844 8750 900000 -11425 900000 -1499 900000 2209 900000 11095 5341 16289 -2370 8258 -4614 2702 900000 3541 9243 2356 1613 -6035 900000 6197 7123 6408 6348 -2231 -2430 5921 7228 5365 -443 900000 3793 6639 -4960 7499 -6373 3768 9332 5597 3394 6616 7069 -2331 6707 -2850 6139 -5749 3853 726 -2373 14801 3021 7728 -5683 2202 -17856 13359 7189 9186 3783 -2423 -2996 -10801 8620 -6752 8955 -12675 8633 -2976 1034 1409 -227 8036 2734 6786 -16373 -5606 -7349 -617 -8161 8609 3545 -2732 12713 -18481 -6624 2695 2021 -3951 4288 3728 4396 14056 1828 10656 -5113 2087 1183 1528 2002 -2573 3806 7580 5619 -1419 5431 -12244 -3257 -7859 1841 SS 20221112T134517.8Z 8351.573123 204 1 48.70 2 81.37 117.69 55.00 282.33 0.00 1 0.00 1 0 25 4.433e-01 9.462e-03 1.283e-01 3.835e-03 6.403470e-01 2.371948e-03 6.944805e-03 -6.000000e+00 3.012115e-01 224.94 -2.00 3.32 -2.00 321.38 0.00e+00 2.600712e-03 1.330397e-03 2.069605e-03 -6.000000e+00 1.381358e-02 286.89 -2.00 20.00 -2.00 320.81 0.00e+00 6.287 0.003 302.00 328.00 3 2.0090e-01 8.8544e-03 7.0869e-02 -6.0000e+00 7.4012e-01 2.5278e-01 1.1770e-02 3.5111e-02 -6.0000e+00 7.9970e-01 -2.5932e-01 1.0181e-02 1.7988e-02 -6.0000e+00 4.7920e-01 9.0451e-02 4.6712e-03 5.2537e-03 -6.0000e+00 1.9650e-01 4.4149e-04 -9.3439e-04 1.4874e-04 1.2930e-04 -6.0000e+00 1.8730e-02 1.9563e-02 0.0000e+00 12 8 8 10 0 0 -13.42 20.22 0.35 0.01956 0.01254 150 36 4 8 0 322.480 15.00 20.22 9.61 21.06 20.96 9.0 874.17 -168483 -146809 -126466 -168341 -116730 -160158 -91983 -165718 -74480 -152679 -107323 -129438 -98309 -65256 -87685 -36647 -54932 148 -41521 -16062 -34006 -16826 -49300 -24503 -29829 -22571 -22412 -40088 -14414 -14083 1200 -15606 -8635 -22975 -15781 780 -11161 3055 -5162 12100 -3056 10861 -1095 3866 -993 520 5601 3337 10681 2607 7421 3232 10410 5081 5398 3628 3859 7880 4650 7891 1689 8344 2711 5126 2559 3434 3254 3311 5753 1882 3644 -230 2717 -747 155 -1752 -1620 300 -1198 -208 -2141 -372 -1450 -1099 -1010 81 -802 -1000 777 -1017 69 14 288 -36 334 -111 -326 115 -563 -572 -657 -334 -1927 -856 -998 -1015 -1121 -530 -228 -337 0 -312 310 98 787 279 421 214 143 634 -551 391 100 828 818 1205 308 662 616 148 158 -218 59 -269 450 -338 -512 41 -312 -165 26 -101 -1995 -1556 -1143 -2308 -946 -2232 -688 -2817 -557 -2751 -1386 -2464 -1671 -976 -1967 -573 -1158 2 -889 -278 -728 -315 -1341 -550 -740 -537 -541 -1172 -343 -369 31 -531 -299 -969 -644 29 -524 144 -309 765 -248 820 -97 337 -93 49 517 329 1042 299 891 444 1444 796 886 625 672 1320 807 1360 328 1651 618 1217 646 878 864 936 1730 640 1288 -86 963 -260 50 -543 -498 96 -435 -86 -1020 -194 -833 -675 -660 55 -566 -713 535 -686 44 9 182 -25 252 -95 -315 120 -609 -609 -667 -321 -1840 -823 -1006 -1088 -1294 -663 -311 -500 0 -503 493 153 1190 421 647 342 235 1046 -911 624 155 1230 1184 1726 459 1056 1077 285 328 -485 127 -613 1066 -835 -1288 101 -764 -389 59 -226 SS 20221112T140031.5Z 8351.583698 210 1 49.42 2 78.57 120.03 58.03 283.85 0.00 1 0.00 1 0 25 2.064e-01 5.791e-03 4.729e-02 1.858e-03 5.151196e-01 1.124772e-03 5.624718e-03 -6.000000e+00 1.402363e-01 224.94 -2.00 3.32 -2.00 320.63 0.00e+00 2.696743e-03 4.829025e-04 4.513619e-04 -6.000000e+00 6.431020e-03 286.89 -2.00 20.00 -2.00 319.95 0.00e+00 4.877 0.002 302.00 328.00 3 6.7453e-01 3.5954e-03 5.4657e-02 -6.0000e+00 3.4458e-01 1.0662e-01 4.5007e-03 2.5821e-02 -6.0000e+00 3.7231e-01 -7.9469e-02 3.6889e-03 1.3242e-02 -6.0000e+00 2.2310e-01 1.9657e-02 1.7879e-03 4.9730e-03 -6.0000e+00 9.1487e-02 1.2059e-03 -8.1117e-04 7.6230e-05 8.8494e-05 -6.0000e+00 8.7198e-03 1.9302e-02 0.0000e+00 10 0 0 10 0 0 97.23 20.22 0.34 0.01930 0.01321 211 50 2 8 0 229.840 14.99 20.22 10.66 21.06 20.96 9.0 879.78 -53194 -81205 -58124 -86294 -80389 -75947 -67615 -40093 -67700 -51201 -65762 -35017 -46232 -27933 -33094 -14261 -13110 -8486 -4081 -13984 -1299 -15128 -9460 -15519 -5470 -15198 -1728 -10138 -8235 -5481 -8141 -5033 -8002 -3941 -8638 -1455 -3394 -1312 38 135 -432 -1707 2020 -1899 1987 -441 1940 1175 2498 1845 3021 3870 1117 3364 935 1947 463 2509 998 1925 2544 1875 2295 1200 1223 149 1483 310 1439 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