File name: Pandora207s1_ArlingtonTX_20230203_L2Fit_fout2c6d20221007p1-8.txt File generation date: 20240911T084740.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s1_CF_v6d20221007.txt Level 1 file used: Pandora207s1_ArlingtonTX_20230203_L1_smca1c6d20221007p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20230203 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 5 "But different Reference day, final winter reference" First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0775 305.2189 305.3602 305.5015 305.6428 305.7841 305.9254 306.0666 306.2079 306.3491 306.4904 306.6316 306.7728 306.9140 307.0552 307.1964 307.3375 307.4787 307.6198 307.7609 307.9021 308.0432 308.1843 308.3254 308.4664 308.6075 308.7485 308.8896 309.0306 309.1716 309.3126 309.4536 309.5946 309.7356 309.8765 310.0175 310.1584 310.2993 310.4403 310.5812 310.7220 310.8629 311.0038 311.1446 311.2855 311.4263 311.5671 311.7080 311.8488 311.9895 312.1303 312.2711 312.4118 312.5526 312.6933 312.8340 312.9747 313.1154 313.2561 313.3968 313.5375 313.6781 313.8188 313.9594 314.1000 314.2406 314.3812 314.5218 314.6624 314.8029 314.9435 315.0840 315.2245 315.3651 315.5056 315.6461 315.7865 315.9270 316.0675 316.2079 316.3484 316.4888 316.6292 316.7696 316.9100 317.0504 317.1907 317.3311 317.4714 317.6118 317.7521 317.8924 318.0327 318.1730 318.3133 318.4535 318.5938 318.7340 318.8743 319.0145 319.1547 319.2949 319.4351 319.5753 319.7154 319.8556 319.9957 320.1358 320.2760 320.4161 320.5562 320.6962 320.8363 320.9764 321.1164 321.2565 321.3965 321.5365 321.6765 321.8165 321.9565 322.0965 322.2364 322.3764 322.5163 322.6562 322.7962 322.9361 323.0759 323.2158 323.3557 323.4956 323.6354 323.7752 323.9151 324.0549 324.1947 324.3345 324.4742 324.6140 324.7538 324.8935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230203T135745.2Z 8434.581773 174 1 48.57 2 83.83 114.13 106.43 316.93 0.00 1 0.00 1 0 17 5.811e-01 3.234e-02 4.269e-01 2.933e-02 8.826867e-01 1.933358e-02 9.345536e-03 -6.000000e+00 3.991445e-01 224.88 -2.00 3.32 -2.00 322.08 0.00e+00 -7.607451e-04 1.044253e-02 4.169611e-03 -6.000000e+00 1.921417e-02 282.31 -2.00 20.00 -2.00 321.58 0.00e+00 8.354 0.008 302.00 328.00 3 7.6846e-01 7.2909e-02 9.7814e-02 -6.0000e+00 9.7960e-01 1.4873e+00 8.6390e-02 5.6176e-02 -6.0000e+00 1.0600e+00 -1.6733e+00 5.5383e-02 2.3599e-02 -6.0000e+00 6.3297e-01 6.1617e-01 2.6758e-02 7.3843e-03 -6.0000e+00 2.5813e-01 2.1677e-05 -2.3785e-03 1.0444e-03 1.4441e-04 -6.0000e+00 2.4925e-02 2.4087e-04 0.0000e+00 12 8 8 10 0 0 32.65 19.78 0.86 0.00024 -0.01763 21 5 4 8 0 2312.410 14.99 19.78 7.18 20.77 20.77 11.3 901.99 280651 10656 206503 -93000 900000 84823 -94487 33898 -51539 -18632 -38472 -28208 26024 900000 -57651 69556 5216 316006 15228 900000 -2351 25805 -56694 24271 900000 78165 900000 -44277 -20522 30390 39813 35216 -15408 -10745 -193 99043 -873 -20316 24820 177268 33146 39697 71063 14052 72348 1436 95915 25379 172071 43777 202056 36371 59024 51368 43207 34055 17083 67790 8056 21801 -2811 7094 9569 23802 5805 20046 9491 521 25240 7499 23304 9016 13331 35872 -27092 -17242 -5170 18107 -15385 -893 -9169 16011 10622 -1156 -3874 -4584 -2 -5552 1651 -6433 -637 -7920 4721 -1947 7160 3924 -6305 -2566 -3539 2214 977 1640 -9977 -888 -823 -5295 -1129 1041 -3069 -4222 3635 -384 2825 -1576 -537 -1346 -276 626 253 2282 574 2777 669 3722 4983 -876 -36 954 -197 208 625 -546 -379 1168 254 -179 -612 455 -801 -688 -472 118 8018 381 5900 -7971 900000 2423 -6524 968 -2331 -621 -1649 -1209 744 900000 -4941 1987 273 9028 725 900000 -134 1072 -5301 1009 900000 2233 900000 -3220 -1173 1105 1448 1463 -1121 -754 -12 2830 -59 -1847 1612 5065 2324 2681 3507 1204 3382 134 3488 1912 4916 3070 5773 3212 4446 4403 4152 3627 2130 4930 1025 2378 -402 977 1392 3215 1078 3322 1817 116 4759 1821 5060 2267 3085 6149 -7973 -4286 -1123 3311 -4439 -258 -3301 5032 3854 -505 -1837 -2279 -1 -2855 774 -3143 -282 -3711 2010 -968 3703 2422 -4918 -2126 -3104 1822 776 1213 -7924 -642 -616 -4403 -978 975 -3359 -5223 4549 -528 3849 -2238 -747 -1889 -390 903 376 3326 835 3824 908 4742 6136 -1147 -48 1399 -328 387 1283 -1237 -925 2993 694 -509 -1772 1295 -2246 -1837 -1193 286 SS 20230203T141516.4Z 8434.593940 177 1 49.05 2 80.50 116.72 108.80 320.01 0.00 1 0.00 1 0 25 4.708e-01 1.060e-02 1.505e-01 3.968e-03 6.804052e-01 2.458670e-03 7.356388e-03 -6.000000e+00 3.208604e-01 224.88 -2.00 3.32 -2.00 321.38 0.00e+00 1.462372e-03 1.336245e-03 3.315831e-03 -6.000000e+00 1.440780e-02 282.31 -2.00 20.00 -2.00 320.87 0.00e+00 5.773 0.003 302.00 328.00 3 8.1451e-01 8.9230e-03 6.8885e-02 -6.0000e+00 7.8962e-01 2.6137e-01 1.1929e-02 4.1179e-02 -6.0000e+00 8.5312e-01 -2.9142e-01 1.0922e-02 2.0240e-02 -6.0000e+00 5.0979e-01 1.0535e-01 5.0299e-03 5.4734e-03 -6.0000e+00 2.0870e-01 3.6756e-04 -7.5959e-04 1.5068e-04 1.4698e-04 -6.0000e+00 1.9894e-02 -7.9735e-04 0.0000e+00 12 9 8 11 8 0 54.94 19.78 0.28 -0.00080 -0.00651 109 26 4 8 0 445.770 14.99 19.78 8.66 20.77 20.77 11.2 911.83 -178256 -187464 -186853 -152519 -124803 -126989 -69999 -137118 -94517 -188248 -72115 -153100 -102805 -90669 -61236 -10698 -35894 -4454 -55396 15363 -57964 -37488 -71724 -35845 -14114 -37149 -1412 -26827 12597 -37329 -9654 -30789 -4669 -16398 -16178 -6016 -1217 11889 -2884 18918 3721 7139 -3623 986 -3932 3917 8744 4909 16803 1538 11409 4227 9132 4834 4072 4718 5564 8657 4300 7353 5289 6771 605 3633 1609 3755 4180 3341 6246 4018 6218 120 2881 -245 -570 -1968 -1598 976 -195 1917 -1500 1148 -2460 -1209 -1336 -637 -1502 -246 380 -197 474 481 441 -1128 442 -1330 -1237 -647 -427 -525 -909 -82 -1749 6 -1067 -1170 -924 -953 -298 -527 412 24 121 -243 542 201 478 1382 215 275 -55 389 -7 859 525 1051 -164 454 505 124 605 40 186 -144 437 -504 -556 -391 -134 -380 109 185 -2011 -2599 -2711 -1574 -966 -1117 -369 -1543 -765 -4304 -583 -3285 -1627 -1563 -948 -117 -568 -56 -1247 178 -1447 -791 -2245 -832 -278 -954 -26 -642 213 -1142 -255 -1137 -146 -611 -626 -224 -48 481 -174 1054 268 533 -315 84 -360 339 744 454 1469 170 1258 551 1237 735 658 785 932 1407 729 1232 954 1305 136 848 400 937 1077 924 1829 1312 2110 44 1012 -84 -183 -604 -483 303 -68 754 -696 581 -1410 -736 -867 -431 -1058 -173 261 -132 301 297 276 -767 330 -1149 -1200 -680 -465 -567 -941 -80 -1673 6 -1066 -1240 -1052 -1183 -403 -780 645 39 196 -387 837 309 744 2196 356 460 -92 624 -11 1281 764 1507 -245 722 881 238 1141 82 401 -331 1047 -1261 -1417 -993 -332 -908 249 412 SS 20230203T142544.9Z 8434.601214 182 1 48.85 2 78.55 118.32 110.14 321.93 0.00 1 0.00 1 0 25 2.970e-01 6.286e-03 6.767e-02 2.071e-03 5.862632e-01 1.274059e-03 6.324526e-03 -6.000000e+00 2.024388e-01 224.88 -2.00 3.32 -2.00 320.90 0.00e+00 3.514453e-03 5.829867e-04 5.095318e-04 -6.000000e+00 9.089092e-03 282.31 -2.00 20.00 -2.00 320.32 0.00e+00 4.869 0.002 302.00 328.00 3 7.8066e-01 4.1375e-03 5.6528e-02 -6.0000e+00 4.9819e-01 1.3853e-01 5.3127e-03 2.9928e-02 -6.0000e+00 5.3823e-01 -1.1469e-01 4.7500e-03 1.5800e-02 -6.0000e+00 3.2162e-01 3.1920e-02 2.2720e-03 6.4544e-03 -6.0000e+00 1.3170e-01 9.8655e-04 -8.9587e-04 8.2323e-05 1.1266e-04 -6.0000e+00 1.2550e-02 -2.1014e-03 0.0000e+00 10 0 0 10 0 0 19.33 19.78 0.34 -0.00210 -0.00883 188 45 4 8 0 257.050 15.01 19.78 9.41 20.77 20.77 11.2 916.37 -87063 -104285 -107009 -100983 -117941 -64692 -115241 -62943 -103637 -84202 -88089 -52755 -65427 -54874 -34260 -38737 -18518 -24729 -9421 -24141 -15437 -22571 -16490 -11109 -22020 -12604 -25634 -14666 -19483 -1743 -14167 -4554 -7541 -5026 -7194 -5932 -1146 -6717 2436 -1631 1229 -1865 1838 -812 1913 1582 812 3944 901 3490 2981 4473 2648 3367 2464 1262 2610 403 2505 543 3139 1626 1879 1446 1668 642 1418 1879 1025 2320 1261 1170 57 -260 -888 -531 -1175 -715 -788 -494 -762 -858 -709 -1289 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