File name: Pandora207s1_ArlingtonTX_20231112_L2Fit_fout2c7d20230612p1-8.txt File generation date: 20240823T135002.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s1_CF_v7d20230612.txt Level 1 file used: Pandora207s1_ArlingtonTX_20231112_L1_smca1c7d20230612p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20231112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6, but with summer RefDay for AC on period. First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.1272 305.2686 305.4099 305.5513 305.6926 305.8339 305.9752 306.1165 306.2578 306.3990 306.5403 306.6815 306.8228 306.9640 307.1052 307.2464 307.3876 307.5287 307.6699 307.8111 307.9522 308.0933 308.2344 308.3755 308.5166 308.6577 308.7988 308.9398 309.0809 309.2219 309.3629 309.5040 309.6450 309.7859 309.9269 310.0679 310.2088 310.3498 310.4907 310.6316 310.7725 310.9134 311.0543 311.1952 311.3361 311.4769 311.6178 311.7586 311.8994 312.0402 312.1810 312.3218 312.4625 312.6033 312.7440 312.8848 313.0255 313.1662 313.3069 313.4476 313.5883 313.7289 313.8696 314.0102 314.1509 314.2915 314.4321 314.5727 314.7133 314.8539 314.9944 315.1350 315.2755 315.4160 315.5566 315.6971 315.8376 315.9780 316.1185 316.2590 316.3994 316.5398 316.6803 316.8207 316.9611 317.1015 317.2419 317.3822 317.5226 317.6629 317.8032 317.9436 318.0839 318.2242 318.3645 318.5047 318.6450 318.7852 318.9255 319.0657 319.2059 319.3461 319.4863 319.6265 319.7667 319.9068 320.0470 320.1871 320.3273 320.4674 320.6075 320.7476 320.8876 321.0277 321.1678 321.3078 321.4478 321.5879 321.7279 321.8679 322.0079 322.1478 322.2878 322.4277 322.5677 322.7076 322.8475 322.9874 323.1273 323.2672 323.4071 323.5470 323.6868 323.8266 323.9665 324.1063 324.2461 324.3859 324.5257 324.6654 324.8052 324.9449 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231112T133656.3Z 8716.567318 56 1 48.12 2 82.89 116.40 75.22 121.56 0.00 1 0.00 1 0 25 5.088e-01 1.831e-02 4.193e-01 1.440e-02 8.005986e-01 9.238446e-03 8.555786e-03 -6.000000e+00 3.440483e-01 224.94 -2.00 3.32 -2.00 322.10 0.00e+00 -2.218046e-03 6.236488e-03 8.846322e-03 -6.000000e+00 1.615570e-02 286.89 -2.00 20.00 -2.00 321.58 0.00e+00 7.429 0.006 302.00 328.00 3 6.9048e-01 3.9941e-02 1.0014e-01 -6.0000e+00 8.4470e-01 6.6100e-01 5.3219e-02 8.2367e-02 -6.0000e+00 9.1485e-01 -8.3108e-01 4.3370e-02 2.9149e-02 -6.0000e+00 5.4799e-01 3.2311e-01 1.9174e-02 7.4690e-03 -6.0000e+00 2.2396e-01 7.5777e-05 -1.5492e-03 5.3239e-04 1.6499e-04 -6.0000e+00 2.1537e-02 8.7133e-03 0.0000e+00 12 9 8 11 8 0 97.16 20.60 0.52 0.00871 -0.00293 45 11 4 8 0 1069.270 15.00 20.60 19.50 21.06 20.25 17.5 895.78 900000 -84836 -1148 -172973 -176145 -154046 -155999 -214152 -116259 -138145 -85220 51625 -14759 -32777 73846 224117 -97199 -56633 -95931 -83673 -5337 -18034 20302 900000 79748 -61957 29005 -66222 -6032 -8355 -49595 20370 -9171 36731 33391 8711 -31215 55710 19137 27445 -14494 19424 24095 76651 33588 37901 53818 17150 9701 5964 22957 9262 26689 60949 44426 46738 22470 10790 8576 24726 -8168 8230 15889 19360 37044 15937 17997 6147 13366 6041 7341 11836 5906 89 5284 3117 -6407 272 -5116 -1266 -5479 941 -2957 -75 526 904 -274 1426 2003 -229 -2899 -2353 -3722 -3457 -296 1104 -1253 -1869 -1120 19 -3811 -2360 -2292 -3257 -1809 -1220 -922 -999 -679 -1193 -144 -876 -1616 61 1116 978 1205 3220 912 1290 721 852 -1149 1064 1857 1002 612 954 962 -46 8 -281 241 165 -379 -53 -499 -548 96 403 -446 -231 900000 -1190 -16 -3236 -3295 -2342 -2554 -6761 -1631 -2423 -1196 724 -207 -460 1036 3145 -3348 -1373 -3549 -2775 -82 -322 285 900000 1119 -1976 407 -2196 -115 -181 -1835 416 -269 703 681 244 -1473 1279 732 1085 -943 942 1137 2151 1457 1595 1991 963 631 441 1581 803 2111 3654 3287 3804 2333 1241 999 2498 -1215 1132 2207 2771 4626 2549 2980 1242 2757 1449 1813 2790 1417 21 1105 639 -1474 64 -1457 -401 -2068 371 -1319 -35 257 458 -143 732 998 -112 -1411 -1139 -1922 -1974 -187 790 -1030 -1665 -1012 16 -3267 -1891 -1798 -2637 -1518 -1090 -897 -1076 -811 -1577 -201 -1275 -2374 87 1555 1374 1732 4671 1379 1936 1064 1215 -1617 1421 2423 1336 867 1483 1668 -88 16 -644 587 425 -1031 -148 -1408 -1526 256 1025 -1098 -560 SS 20231112T134343.5Z 8716.572031 59 1 48.76 2 81.62 117.41 74.06 122.68 0.00 1 0.00 1 0 25 4.820e-01 1.421e-02 2.987e-01 7.110e-03 7.318746e-01 4.480944e-03 7.618243e-03 -6.000000e+00 3.254815e-01 224.94 -2.00 3.32 -2.00 321.84 0.00e+00 -3.006447e-04 2.838401e-03 1.661431e-03 -6.000000e+00 1.499891e-02 286.89 -2.00 20.00 -2.00 321.29 0.00e+00 6.449 0.004 302.00 328.00 3 6.9897e-01 1.8324e-02 7.4664e-02 -6.0000e+00 7.9966e-01 3.9496e-01 2.4683e-02 4.0161e-02 -6.0000e+00 8.6565e-01 -4.9176e-01 2.1134e-02 1.9606e-02 -6.0000e+00 5.1866e-01 1.8772e-01 9.4553e-03 5.4998e-03 -6.0000e+00 2.1121e-01 2.0862e-04 -1.5180e-03 2.6978e-04 1.1185e-04 -6.0000e+00 2.0363e-02 8.6783e-03 0.0000e+00 12 9 8 11 8 0 98.60 20.60 0.49 0.00868 -0.00273 83 20 4 8 0 585.750 15.00 20.60 19.99 21.17 20.25 17.5 899.02 -118506 -231504 -131831 -152103 -72200 -144668 -163622 44461 -191838 -65813 -178957 -78308 -144104 49448 -38869 -39528 -52739 -58470 56177 -99867 -7562 -73033 -2637 -63955 57169 -26333 -12734 7727 -39751 -10166 -217 -14035 -36756 22945 -33365 14362 11999 21631 22703 -6082 15350 -11541 5985 8738 24762 4272 32677 22964 8390 23663 7310 18177 3197 16293 1003 19571 8821 14516 15478 8201 8184 4567 7542 4445 11058 532 10489 5878 6786 6064 5411 6156 -1047 2397 -4213 2923 -4534 4424 364 1902 -719 -2085 -1083 -3340 1001 -1785 262 -471 1855 -358 -855 844 -715 63 -1803 -687 -2686 -212 -1266 -231 -639 -1893 -1276 -2549 -293 -3091 -31 -1801 238 -359 -423 511 -26 451 197 714 -116 1184 -343 860 -256 1191 978 40 1650 48 809 610 1218 -303 927 -166 -141 499 156 -274 -1061 290 -757 206 147 -349 -821 -5349 -1142 -1582 -501 -1421 -2079 308 -3879 -456 -4398 -839 -3633 343 -490 -573 -964 -1216 389 -3399 -105 -2025 -38 -1814 504 -548 -233 117 -1027 -218 -5 -398 -1413 506 -1346 389 378 722 873 -353 784 -815 366 529 1425 308 1835 1496 680 1804 725 1777 394 1886 142 2361 1192 1841 1942 1137 1208 763 1333 863 2085 115 2160 1369 1717 1673 1572 1779 -313 650 -1136 703 -1194 1159 113 670 -296 -965 -540 -1824 554 -1061 156 -282 1061 -201 -465 448 -402 38 -1278 -548 -2445 -202 -1244 -219 -576 -1643 -1081 -2238 -265 -3067 -33 -2106 301 -498 -623 765 -38 659 284 1028 -172 1793 -539 1332 -393 1747 1389 56 2212 65 1159 956 2098 -584 1911 -371 -337 1251 409 -743 -2929 781 -1998 514 355 -835 SS 20231112T140208.3Z 8716.584818 64 1 40.51 2 78.23 120.23 70.99 125.85 0.00 1 0.00 1 0 25 2.785e-01 7.479e-03 1.342e-01 4.193e-03 5.653322e-01 2.507938e-03 6.045531e-03 -6.000000e+00 1.881250e-01 224.94 -2.00 3.32 -2.00 320.91 0.00e+00 3.292736e-03 1.210569e-03 3.964861e-04 -6.000000e+00 8.668148e-03 286.89 -2.00 20.00 -2.00 320.27 0.00e+00 4.747 0.001 302.00 328.00 3 1.7964e+00 8.5272e-03 5.4805e-02 -6.0000e+00 4.6219e-01 1.1849e-01 1.0947e-02 2.8495e-02 -6.0000e+00 5.0032e-01 -1.0845e-01 9.2417e-03 1.4382e-02 -6.0000e+00 2.9977e-01 3.1583e-02 4.3756e-03 5.7152e-03 -6.0000e+00 1.2209e-01 4.1788e-04 -9.9731e-04 1.6655e-04 9.8465e-05 -6.0000e+00 1.1769e-02 7.8185e-03 0.0000e+00 11 8 0 10 0 0 98.85 20.61 0.45 0.00782 0.00032 79 27 4 8 0 512.640 15.00 20.61 20.76 21.06 20.25 17.6 903.29 -49892 -135797 -79801 -110061 -76709 -107234 -54093 -76493 -101107 -64339 -100467 -52371 -52129 -11133 -40914 2103 -29412 -18323 -2738 -41883 -12363 -31312 -6184 -22106 7597 -30801 -3315 -1491 -16163 -7314 -20386 -4861 -23376 2075 -10331 6033 -2861 670 2788 869 981 365 4736 -2704 7142 -562 5653 979 6003 2896 1572 5915 825 3484 -1080 2940 -629 2585 -419 1311 4743 1806 3795 1219 3133 308 3054 237 2351 508 1911 1075 -272 -721 -1426 509 -1473 571 -1568 30 -1778 -1416 -794 -1615 -448 -1049 -31 -599 174 -170 872 345 262 1622 1198 621 -486 -76 -1144 295 -157 -116 -1123 -366 -11 -1414 -25 -594 -129 -477 -175 -187 133 764 129 896 -230 313 -524 291 -439 326 102 466 1103 131 441 188 545 225 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