File name: Pandora207s1_ArlingtonTX_20240227_L2Fit_fout2c9d20231201p1-8.txt File generation date: 20240823T141239.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s1_CF_v9d20231201.txt Level 1 file used: Pandora207s1_ArlingtonTX_20240227_L1_smca1c9d20231201p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20240227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 with winter reference, but for new validity period for winter 2023-2024. First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0775 305.2189 305.3602 305.5015 305.6428 305.7841 305.9254 306.0666 306.2079 306.3491 306.4904 306.6316 306.7728 306.9140 307.0552 307.1964 307.3375 307.4787 307.6198 307.7609 307.9021 308.0432 308.1843 308.3254 308.4664 308.6075 308.7485 308.8896 309.0306 309.1716 309.3126 309.4536 309.5946 309.7356 309.8765 310.0175 310.1584 310.2993 310.4403 310.5812 310.7220 310.8629 311.0038 311.1446 311.2855 311.4263 311.5671 311.7080 311.8488 311.9895 312.1303 312.2711 312.4118 312.5526 312.6933 312.8340 312.9747 313.1154 313.2561 313.3968 313.5375 313.6781 313.8188 313.9594 314.1000 314.2406 314.3812 314.5218 314.6624 314.8029 314.9435 315.0840 315.2245 315.3651 315.5056 315.6461 315.7865 315.9270 316.0675 316.2079 316.3484 316.4888 316.6292 316.7696 316.9100 317.0504 317.1907 317.3311 317.4714 317.6118 317.7521 317.8924 318.0327 318.1730 318.3133 318.4535 318.5938 318.7340 318.8743 319.0145 319.1547 319.2949 319.4351 319.5753 319.7154 319.8556 319.9957 320.1358 320.2760 320.4161 320.5562 320.6962 320.8363 320.9764 321.1164 321.2565 321.3965 321.5365 321.6765 321.8165 321.9565 322.0965 322.2364 322.3764 322.5163 322.6562 322.7962 322.9361 323.0759 323.2158 323.3557 323.4956 323.6354 323.7752 323.9151 324.0549 324.1947 324.3345 324.4742 324.6140 324.7538 324.8935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240227T155508.2Z 8823.663290 280 1 25.84 2 57.01 128.56 107.66 275.36 0.00 1 0.00 1 0 17 1.015e-02 5.852e-03 4.845e-03 1.848e-03 2.318795e-01 1.088723e-03 2.657643e-03 -6.000000e+00 6.932374e-03 225.99 -2.00 3.32 -2.00 316.93 0.00e+00 6.422913e-04 1.481117e-04 6.465540e-05 -6.000000e+00 3.112453e-04 282.79 -2.00 20.00 -2.00 316.22 0.00e+00 1.830 0.000 302.00 328.00 3 4.1095e+00 2.8388e-03 2.1418e-02 -6.0000e+00 1.7100e-02 2.8690e-02 3.1658e-03 1.1278e-02 -6.0000e+00 1.8474e-02 -4.5697e-03 1.8330e-03 5.5417e-03 -6.0000e+00 1.1032e-02 -2.4992e-03 8.2798e-04 1.6111e-03 -6.0000e+00 4.4973e-03 1.0669e-03 -1.9409e-04 7.7420e-05 2.9815e-05 -6.0000e+00 4.2917e-04 1.5331e-02 0.0000e+00 12 1 1 12 1 1 99.98 21.48 0.28 0.01533 0.01387 20 9 1 8 0 1230.360 15.00 21.48 29.30 21.98 21.79 20.5 1029.95 -716 -2377 -846 -3624 -4544 -1510 -3288 1257 -1127 -1794 -3683 -685 -375 -468 424 -950 1329 -364 943 892 1288 294 1206 1260 -313 346 -416 -914 -911 755 465 786 140 1497 -2541 -1557 252 -470 461 -207 -920 -1151 -814 -505 -646 -647 -239 -47 -367 51 968 1050 674 1012 597 163 1197 539 1358 1101 1327 958 649 436 198 -510 227 -68 520 1272 102 102 151 -262 -450 -183 -433 -427 -551 -467 -957 -1137 -1150 -1527 -604 -506 -383 -554 -63 -147 -252 824 511 838 1464 1080 -165 140 -80 -764 -200 -492 -535 12 47 -889 -165 -338 -205 -113 -121 -176 -91 127 268 767 571 529 223 92 -382 -183 344 114 1017 1044 617 637 745 283 180 -126 -498 -114 435 -227 -511 -210 -375 -601 122 -152 -97 -342 -120 -511 -621 -199 -457 177 -173 -291 -634 -122 -73 -101 99 -243 350 -101 267 259 378 89 370 399 -103 114 -136 -292 -284 232 148 259 48 513 -917 -582 102 -217 240 -110 -530 -696 -504 -314 -401 -397 -144 -28 -217 31 601 683 461 717 436 121 888 403 1010 838 1050 799 566 387 173 -432 186 -57 455 1181 93 94 138 -251 -404 -152 -343 -337 -458 -421 -947 -1119 -1212 -1719 -716 -629 -492 -665 -80 -178 -286 868 519 856 1566 1253 -210 171 -99 -940 -255 -607 -658 16 62 -1155 -225 -483 -306 -175 -190 -271 -134 177 355 985 745 717 317 135 -568 -268 485 155 1422 1414 834 880 990 394 261 -190 -779 -185 681 -369 -851 -351 -623 -980 193 -238 SS 20240227T170344.4Z 8823.710930 309 1 49.99 2 47.18 146.18 121.53 285.31 0.00 1 0.00 1 0 17 7.104e-03 5.557e-03 7.899e-04 3.935e-04 1.865678e-01 2.326560e-04 2.149740e-03 -6.000000e+00 4.849624e-03 226.00 -2.00 3.32 -2.00 316.21 0.00e+00 4.475117e-04 2.665325e-05 4.426705e-05 -6.000000e+00 2.177400e-04 282.79 -2.00 20.00 -2.00 315.53 0.00e+00 1.469 0.000 302.00 328.00 3 2.1271e+00 6.0068e-04 1.7188e-02 -6.0000e+00 1.1963e-02 1.1629e-02 6.6909e-04 9.0465e-03 -6.0000e+00 1.2924e-02 -5.7760e-05 3.8111e-04 4.4443e-03 -6.0000e+00 7.7178e-03 -3.9021e-03 1.6468e-04 1.2698e-03 -6.0000e+00 3.1460e-03 1.2072e-02 -2.4581e-04 1.6599e-05 2.4631e-05 -6.0000e+00 3.0023e-04 1.5552e-02 0.0000e+00 11 1 0 11 8 0 99.47 21.49 0.33 0.01555 0.01370 353 84 1 8 0 137.320 15.00 21.49 31.25 21.98 21.79 20.8 1046.19 -1140 -1538 -1249 -1998 -2257 -1170 -264 -60 -29 384 -1365 -1137 -447 209 319 668 164 47 488 951 1236 396 717 534 187 97 422 -75 -354 598 871 143 210 405 -1850 -1245 -285 -406 0 66 -803 -1397 -783 -987 -790 -682 -555 -518 -75 -10 892 914 572 1023 357 462 730 965 856 1183 1316 936 590 656 256 -477 260 207 715 1065 480 -167 -363 -214 -320 -149 -150 -231 -177 -211 -925 -935 -1269 -1510 -584 -511 -502 -484 -32 -419 60 552 535 938 1255 829 -186 226 -327 -590 -262 -341 -662 165 170 -622 -314 -329 -293 -257 -58 -156 -220 75 198 743 708 395 190 163 -408 -151 238 243 922 1135 539 715 753 185 282 3 -176 -126 177 -268 -596 -183 -354 -415 -93 -98 -229 -322 -260 -401 -434 -220 -51 -12 -6 85 -320 -280 -118 60 99 220 57 17 178 352 463 152 280 215 77 40 171 -29 -135 224 331 56 85 165 -775 -541 -134 -217 0 40 -530 -969 -552 -701 -557 -473 -376 -344 -49 -6 605 647 423 780 281 368 583 769 686 964 1112 832 546 612 234 -421 221 177 640 1012 484 -173 -373 -210 -294 -127 -121 -184 -147 -190 -911 -994 -1325 -1682 -684 -629 -640 -623 -41 -504 68 574 581 1015 1301 927 -226 287 -424 -750 -319 -404 -784 201 217 -841 -410 -449 -417 -378 -86 -226 -305 105 265 962 928 541 272 223 -569 -207 343 336 1211 1438 680 917 1001 257 405 4 -249 -186 272 -427 -975 -301 -579 -666 -145 -152 SS 20240227T171156.6Z 8823.716627 313 1 4.22 2 46.25 148.66 123.15 286.64 0.00 1 0.00 1 0 25 7.144e-03 5.944e-03 1.803e-03 1.170e-03 1.829029e-01 7.001149e-04 2.122652e-03 -6.000000e+00 4.877105e-03 226.00 -2.00 3.32 -2.00 315.21 0.00e+00 4.511945e-04 6.486411e-05 2.502512e-05 -6.000000e+00 2.189653e-04 282.79 -2.00 20.00 -2.00 314.60 0.00e+00 1.444 0.000 302.00 328.00 3 2.2841e+00 1.7876e-03 1.6885e-02 -6.0000e+00 1.2031e-02 1.1303e-02 1.9791e-03 8.8767e-03 -6.0000e+00 1.2997e-02 -1.5032e-04 1.1282e-03 4.3595e-03 -6.0000e+00 7.7614e-03 -3.3536e-03 4.7124e-04 1.2594e-03 -6.0000e+00 3.1640e-03 1.0650e-02 -2.3329e-04 4.8705e-05 2.5750e-05 -6.0000e+00 3.0192e-04 1.5189e-02 0.0000e+00 12 1 1 12 1 1 87.08 21.50 0.33 0.01519 0.01344 20 58 1 8 0 200.500 15.00 21.50 31.90 21.98 21.79 20.9 1051.24 -291 -1672 -488 -1660 -2108 -1468 -538 158 60 897 -1343 2 -389 858 284 827 167 423 858 888 1607 171 763 557 416 -210 239 -443 -537 508 1099 -163 222 268 -1736 -1399 -359 -389 -27 250 -774 -1388 -756 -1091 -690 -768 -237 -597 -254 -87 711 872 673 1089 386 584 749 749 600 1211 1469 774 530 707 211 -497 144 57 403 1113 444 -233 -407 -35 -524 -141 -264 -52 -462 -265 -940 -915 -1252 -1460 -628 -680 -571 -622 -190 -387 155 732 717 898 1294 861 0 244 -277 -528 -211 -321 -718 387 312 -789 -282 -346 -229 -243 -210 -228 -157 187 53 805 502 430 100 241 -332 -243 167 342 884 1231 596 735 837 92 361 33 -220 -308 246 -243 -629 -278 -322 -402 -119 -127 -87 -524 -150 -496 -604 -413 -155 48 19 295 -467 1 -139 331 119 369 78 188 390 411 748 82 372 279 213 -109 121 -217 -255 256 561 -80 111 135 -900 -754 -210 -239 -19 179 -602 -1063 -588 -856 -537 -628 -188 -466 -196 -68 567 725 547 913 333 510 657 657 529 1084 1362 712 507 681 199 -452 134 53 372 1089 460 -235 -406 -35 -496 -132 -232 -45 -421 -245 -951 -943 -1383 -1630 -738 -799 -693 -764 -228 -467 174 804 754 942 1416 963 0 295 -341 -638 -257 -380 -851 469 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