File name: Pandora207s1_ArlingtonTX_20240308_L2Fit_fwvt1c9d20231201p1-8.txt File generation date: 20240823T141736.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s1_CF_v9d20231201.txt Level 1 file used: Pandora207s1_ArlingtonTX_20240308_L1_smca1c9d20231201p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20240308 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 with winter reference, but for new validity period for winter 2023-2024. First and last pixel inside fitting window: 1614 1762 Nominal wavelengths inside fitting window [nm]: 492.0579 492.1796 492.3013 492.4230 492.5447 492.6663 492.7880 492.9096 493.0312 493.1528 493.2744 493.3959 493.5175 493.6390 493.7605 493.8820 494.0035 494.1249 494.2463 494.3678 494.4892 494.6106 494.7319 494.8533 494.9746 495.0959 495.2172 495.3385 495.4598 495.5810 495.7023 495.8235 495.9447 496.0659 496.1871 496.3082 496.4293 496.5504 496.6715 496.7926 496.9137 497.0347 497.1558 497.2768 497.3978 497.5188 497.6397 497.7607 497.8816 498.0025 498.1234 498.2443 498.3651 498.4860 498.6068 498.7276 498.8484 498.9692 499.0900 499.2107 499.3314 499.4521 499.5728 499.6935 499.8141 499.9348 500.0554 500.1760 500.2966 500.4172 500.5377 500.6583 500.7788 500.8993 501.0198 501.1402 501.2607 501.3811 501.5015 501.6219 501.7423 501.8627 501.9830 502.1034 502.2237 502.3440 502.4642 502.5845 502.7048 502.8250 502.9452 503.0654 503.1856 503.3057 503.4259 503.5460 503.6661 503.7862 503.9063 504.0263 504.1464 504.2664 504.3864 504.5064 504.6263 504.7463 504.8662 504.9862 505.1061 505.2259 505.3458 505.4657 505.5855 505.7053 505.8251 505.9449 506.0647 506.1844 506.3041 506.4238 506.5435 506.6632 506.7829 506.9025 507.0221 507.1418 507.2613 507.3809 507.5005 507.6200 507.7395 507.8590 507.9785 508.0980 508.2175 508.3369 508.4563 508.5757 508.6951 508.8145 508.9338 509.0532 509.1725 509.2918 509.4111 509.5303 509.6496 509.7688 509.8880 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240308T151229.6Z 8833.633676 106 1 7.85 2 61.47 117.15 58.53 145.95 0.00 1 0.00 1 0 15 2.694e-03 2.702e-03 2.959e-04 2.954e-04 2.738576e+03 1.806290e+01 1.852867e+02 -6.000000e+00 1.514136e+02 283.23 -2.00 20.00 -2.00 505.24 0.00e+00 6.031454e-04 8.147357e-06 3.271767e-05 -6.000000e+00 7.599429e-05 283.23 -2.00 20.00 -2.00 500.40 0.00e+00 1.930408e-02 5.871067e-03 2.204973e-02 -6.000000e+00 5.371672e-02 226.60 -2.00 3.32 -2.00 501.99 0.00e+00 2.084 0.000 489.00 513.00 1 3.2932e+00 4.5000e-04 3.5936e-03 -6.0000e+00 4.1190e-03 8.2970e-03 1.1630e-04 5.2189e-04 -6.0000e+00 1.0697e-03 5.3348e-02 2.1123e-03 2.9656e-05 2.3059e-05 -6.0000e+00 2.7970e-04 2.4421e-02 -2.4227e-05 12 1 1 12 1 1 99.94 21.08 0.35 0.02442 0.03907 107 191 4 2 0 72.560 15.00 21.08 21.09 21.69 21.48 20.0 970.61 -390 -526 -496 -457 -55 227 225 182 138 135 74 -298 -476 -356 -343 -115 61 45 -51 249 439 347 458 529 535 591 379 -202 -354 -111 -59 -61 166 -41 -230 23 59 -157 -149 -95 -55 83 173 245 273 293 362 216 -148 -372 -473 -411 -264 -110 -263 -184 -61 43 223 321 382 314 301 200 199 233 140 -195 -359 -120 -53 -12 42 -124 -329 -164 4 -173 -286 -261 -386 -381 -84 -59 -155 -237 -126 -128 -23 77 341 183 28 196 353 77 -125 -469 -428 -371 -133 -43 -96 -502 -275 -109 -67 43 130 -56 -18 149 161 396 561 505 245 192 151 166 172 386 157 -28 232 204 263 398 181 -128 57 -5 -147 43 40 -218 -186 45 -37 66 263 215 135 -39 -357 -508 -402 -482 -438 -382 -526 -500 -463 -57 239 235 191 144 142 77 -306 -481 -365 -352 -116 63 47 -54 261 461 365 481 557 566 623 396 -208 -364 -111 -59 -61 171 -42 -244 24 61 -163 -153 -97 -57 85 181 257 282 308 377 222 -149 -373 -462 -407 -260 -108 -266 -186 -62 44 229 328 391 323 310 205 201 232 138 -194 -354 -117 -51 -12 42 -122 -323 -163 4 -166 -274 -251 -374 -373 -82 -58 -152 -233 -124 -125 -23 77 342 182 28 193 350 75 -122 -447 -401 -347 -126 -41 -95 -495 -272 -106 -66 42 128 -55 -18 149 162 401 557 504 245 190 151 164 167 373 152 -28 227 199 256 386 176 -123 55 -5 -139 41 38 -209 -181 44 -36 64 259 212 134 -38 -350 -501 -388 -459 -416 SQ 20240308T152910.3Z 8833.645258 114 1 5.62 2 58.39 120.38 56.66 149.96 0.00 1 0.00 1 0 15 2.709e-03 2.711e-03 7.991e-05 7.978e-05 2.176009e+03 4.796659e+00 1.445983e+02 -6.000000e+00 1.522515e+02 283.23 -2.00 20.00 -2.00 505.26 0.00e+00 5.986182e-04 2.204515e-06 3.220682e-05 -6.000000e+00 7.640257e-05 283.23 -2.00 20.00 -2.00 500.45 0.00e+00 -1.818583e-02 1.581696e-03 1.890290e-02 -6.000000e+00 5.396461e-02 226.60 -2.00 3.32 -2.00 502.05 0.00e+00 1.901 0.000 489.00 513.00 1 2.0311e-01 1.2129e-04 3.2352e-03 -6.0000e+00 4.1388e-03 2.7852e-03 3.1308e-05 4.3826e-04 -6.0000e+00 1.0736e-03 1.2084e+00 7.8676e-04 8.0518e-06 1.8753e-05 -6.0000e+00 2.8105e-04 1.5740e-02 9.9972e-05 10 0 0 10 0 0 10.60 21.07 0.37 0.01574 0.02120 1548 527 2 2 0 3.370 15.00 21.07 21.95 21.69 21.58 20.2 977.22 -407 -547 -477 -448 -17 269 251 230 143 174 102 -261 -452 -394 -340 -112 70 65 -20 246 428 357 453 551 519 571 407 -183 -285 -74 -87 -104 135 -93 -261 19 42 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244 227 213 391 199 -145 43 17 -156 62 75 -218 -158 38 5 108 272 242 161 -53 -328 -537 -438 -427 -446 SQ 20240308T152916.5Z 8833.645330 114 2 5.79 2 58.37 120.40 56.65 149.98 0.00 1 0.00 1 0 15 2.720e-03 2.723e-03 7.986e-05 7.973e-05 2.169586e+03 4.792665e+00 1.445398e+02 -6.000000e+00 1.529157e+02 283.23 -2.00 20.00 -2.00 505.26 0.00e+00 5.935034e-04 2.203243e-06 3.192344e-05 -6.000000e+00 7.673565e-05 283.23 -2.00 20.00 -2.00 500.45 0.00e+00 -1.596177e-02 1.580624e-03 1.877222e-02 -6.000000e+00 5.419881e-02 226.60 -2.00 3.32 -2.00 502.05 0.00e+00 1.900 0.000 489.00 513.00 1 2.0227e-01 1.2121e-04 3.2277e-03 -6.0000e+00 4.1568e-03 2.6512e-03 3.1286e-05 4.3633e-04 -6.0000e+00 1.0782e-03 1.2095e+00 7.9504e-04 8.0475e-06 1.8719e-05 -6.0000e+00 2.8227e-04 1.5252e-02 1.0478e-04 10 0 0 10 0 0 0.03 21.07 0.37 0.01525 0.02077 1548 527 2 2 0 3.370 15.00 21.07 21.95 21.69 21.58 20.2 977.22 -419 -527 -497 -467 -23 269 252 241 160 181 89 -253 -429 -387 -347 -122 67 76 -13 226 428 349 463 553 534 575 417 -180 -304 -85 -86 -118 141 -98 -235 26 32 -156 -206 -62 -91 70 161 219 254 338 328 230 -152 -380 -425 -470 -256 -138 -224 -194 -17 80 252 340 353 281 270 170 162 197 120 -151 -353 -174 -25 -38 28 -153 -295 -133 -15 -220 -336 -251 -344 -409 -132 -79 -155 -215 -155 -146 -66 67 305 200 37 250 342 79 -173 -443 -485 -434 -167 -24 -85 -448 -245 -107 -140 22 92 -14 33 117 178 420 547 518 287 199 199 169 172 345 157 29 281 247 203 403 180 -157 32 21 -172 56 83 -218 -146 43 0 115 274 242 145 -49 -337 -529 -476 -456 -455 -414 -513 -500 -486 -24 281 267 256 169 189 92 -258 -430 -398 -357 -122 68 79 -14 242 457 362 478 573 556 596 429 -188 -310 -85 -85 -118 145 -101 -246 27 33 -159 -215 -64 -95 72 165 227 265 350 337 232 -156 -379 -414 -451 -246 -134 -226 -193 -17 81 254 343 357 286 274 172 162 194 120 -150 -346 -170 -24 -37 28 -153 -296 -131 -15 -212 -322 -241 -333 -400 -130 -78 -150 -209 -151 -143 -64 66 304 202 37 251 338 76 -169 -424 -457 -409 -159 -22 -83 -450 -247 -107 -138 22 90 -14 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