File name: Pandora207s1_ArlingtonTX_20240322_L2Fit_fout2c9d20231201p1-8.txt File generation date: 20240823T141706.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s1_CF_v9d20231201.txt Level 1 file used: Pandora207s1_ArlingtonTX_20240322_L1_smca1c9d20231201p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20240322 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6 with winter reference, but for new validity period for winter 2023-2024. First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.0775 305.2189 305.3602 305.5015 305.6428 305.7841 305.9254 306.0666 306.2079 306.3491 306.4904 306.6316 306.7728 306.9140 307.0552 307.1964 307.3375 307.4787 307.6198 307.7609 307.9021 308.0432 308.1843 308.3254 308.4664 308.6075 308.7485 308.8896 309.0306 309.1716 309.3126 309.4536 309.5946 309.7356 309.8765 310.0175 310.1584 310.2993 310.4403 310.5812 310.7220 310.8629 311.0038 311.1446 311.2855 311.4263 311.5671 311.7080 311.8488 311.9895 312.1303 312.2711 312.4118 312.5526 312.6933 312.8340 312.9747 313.1154 313.2561 313.3968 313.5375 313.6781 313.8188 313.9594 314.1000 314.2406 314.3812 314.5218 314.6624 314.8029 314.9435 315.0840 315.2245 315.3651 315.5056 315.6461 315.7865 315.9270 316.0675 316.2079 316.3484 316.4888 316.6292 316.7696 316.9100 317.0504 317.1907 317.3311 317.4714 317.6118 317.7521 317.8924 318.0327 318.1730 318.3133 318.4535 318.5938 318.7340 318.8743 319.0145 319.1547 319.2949 319.4351 319.5753 319.7154 319.8556 319.9957 320.1358 320.2760 320.4161 320.5562 320.6962 320.8363 320.9764 321.1164 321.2565 321.3965 321.5365 321.6765 321.8165 321.9565 322.0965 322.2364 322.3764 322.5163 322.6562 322.7962 322.9361 323.0759 323.2158 323.3557 323.4956 323.6354 323.7752 323.9151 324.0549 324.1947 324.3345 324.4742 324.6140 324.7538 324.8935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240322T192329.9Z 8847.807985 367 1 3.36 2 33.66 202.22 124.09 42.99 0.00 1 0.00 1 0 17 6.892e-03 5.986e-03 1.391e-03 9.410e-04 1.784531e-01 5.682970e-04 2.061666e-03 -6.000000e+00 4.728696e-03 227.58 -2.00 3.32 -2.00 314.98 0.00e+00 2.630930e-04 5.025880e-05 2.031671e-05 -6.000000e+00 2.123346e-04 284.12 -2.00 20.00 -2.00 314.36 0.00e+00 1.201 0.000 302.00 328.00 3 1.8772e+00 1.4527e-03 1.4823e-02 -6.0000e+00 1.1703e-02 1.9518e-02 1.6056e-03 8.6505e-03 -6.0000e+00 1.2630e-02 1.1332e-03 9.1466e-04 4.2488e-03 -6.0000e+00 7.5383e-03 -3.3369e-03 3.7947e-04 1.1901e-03 -6.0000e+00 3.0652e-03 2.0273e-02 -2.0700e-04 3.9130e-05 2.5146e-05 -6.0000e+00 2.9144e-04 2.0877e-02 0.0000e+00 12 1 1 12 1 1 99.89 20.90 0.32 0.02088 0.01932 31 110 1 8 0 104.620 15.00 20.90 24.96 21.48 21.48 20.2 996.42 -611 -1425 -922 -1391 -1938 -460 -323 326 120 420 -954 -879 -237 249 698 270 304 -44 371 1212 1280 570 840 803 356 336 320 -129 -234 832 991 -124 533 22 -1648 -1206 -29 -682 -231 -101 -910 -1497 -804 -1069 -1052 -740 -694 -347 -113 264 871 986 507 896 492 277 892 903 968 1063 1425 807 399 736 120 -543 87 232 619 1125 244 -278 -492 -162 -428 -7 87 -64 -151 -200 -890 -1071 -1279 -1549 -539 -543 -573 -475 -192 -407 -53 724 732 1004 1259 690 -131 121 -321 -697 -99 -435 -609 122 140 -690 -201 -215 -278 -210 -182 -124 -309 160 286 821 690 326 236 88 -356 -202 207 347 894 1104 619 843 682 219 333 65 -166 -162 87 -259 -647 -186 -500 -445 -62 -133 -186 -453 -289 -420 -612 -142 -103 109 39 141 -335 -324 -93 106 320 122 143 -21 184 605 647 294 442 435 197 187 174 -68 -119 414 501 -65 285 12 -909 -691 -17 -448 -160 -78 -706 -1216 -663 -887 -866 -597 -547 -266 -91 215 683 804 432 786 443 238 814 824 887 934 1295 772 397 734 117 -510 78 212 589 1135 247 -288 -505 -158 -414 -7 78 -57 -140 -189 -921 -1130 -1367 -1766 -645 -649 -708 -592 -233 -472 -61 805 777 1065 1394 782 -153 148 -397 -845 -121 -517 -725 149 170 -890 -258 -288 -371 -289 -251 -167 -416 212 358 999 852 420 304 118 -481 -269 266 448 1100 1378 768 1063 848 284 446 86 -226 -229 122 -377 -967 -279 -745 -650 -89 -188 SS 20240322T192900.9Z 8847.811816 369 1 52.98 2 34.11 204.55 123.33 44.26 0.00 1 0.00 1 0 17 6.880e-03 5.566e-03 3.491e-04 1.845e-04 1.797310e-01 1.092719e-04 2.071855e-03 -6.000000e+00 4.721274e-03 227.58 -2.00 3.32 -2.00 316.03 0.00e+00 3.154145e-04 1.203791e-05 3.962175e-05 -6.000000e+00 2.119933e-04 284.12 -2.00 20.00 -2.00 315.33 0.00e+00 1.207 0.000 302.00 328.00 3 7.7789e-01 2.8250e-04 1.4931e-02 -6.0000e+00 1.1684e-02 1.3436e-02 3.1415e-04 8.7482e-03 -6.0000e+00 1.2610e-02 1.4712e-03 1.7851e-04 4.2910e-03 -6.0000e+00 7.5264e-03 -4.2527e-03 7.6326e-05 1.2013e-03 -6.0000e+00 3.0605e-03 6.0449e-02 -1.4805e-04 7.7055e-06 2.3660e-05 -6.0000e+00 2.9097e-04 2.0584e-02 0.0000e+00 10 0 0 10 0 0 99.99 20.91 0.33 0.02058 0.01947 2120 504 2 8 0 22.870 15.00 20.91 25.33 21.48 21.48 20.7 1002.16 -1018 -1385 -1202 -1662 -2180 -1074 -237 -96 326 405 -1018 -1081 -77 119 375 537 29 135 422 921 1200 436 697 683 122 50 285 -278 -342 630 959 -72 427 294 -1759 -1168 -172 -423 -93 -5 -943 -1294 -758 -920 -793 -614 -623 -475 -78 89 891 891 624 979 480 444 813 962 886 1237 1327 904 511 666 150 -443 289 173 656 1037 342 -264 -385 -257 -338 -148 -62 -199 -134 -252 -989 -881 -1358 -1423 -667 -502 -548 -463 -97 -402 75 621 603 945 1314 728 -177 153 -326 -631 -229 -310 -631 199 160 -655 -245 -221 -199 -194 -85 -170 -216 143 226 789 739 342 184 157 -394 -177 223 226 953 1173 502 766 699 133 238 5 -208 -116 207 -313 -546 -154 -356 -423 -80 -98 -223 -316 -272 -361 -455 -219 -50 -21 76 98 -257 -287 -22 37 124 189 11 51 163 362 476 177 288 290 53 22 122 -115 -137 247 382 -30 180 124 -764 -527 -84 -235 -59 -3 -645 -927 -551 -673 -575 -437 -433 -322 -52 60 617 643 470 760 383 359 658 777 720 1022 1137 814 478 626 138 -391 246 149 589 990 346 -275 -395 -252 -309 -125 -50 -158 -111 -226 -969 -930 -1537 -1571 -776 -613 -691 -589 -120 -476 83 693 643 1007 1461 874 -211 191 -412 -784 -273 -358 -731 236 199 -866 -338 -319 -299 -277 -122 -259 -313 194 291 987 937 453 256 226 -574 -255 310 300 1204 1430 609 945 894 177 328 7 -306 -178 329 -477 -853 -242 -554 -647 -129 -158 SS 20240322T194008.3Z 8847.819541 375 1 48.88 2 35.17 209.08 121.75 46.74 0.00 1 0.00 1 0 17 6.924e-03 5.360e-03 1.591e-03 7.273e-04 1.814460e-01 4.317038e-04 2.065135e-03 -6.000000e+00 4.751655e-03 227.59 -2.00 3.32 -2.00 316.38 0.00e+00 3.022428e-04 5.130912e-05 6.424198e-05 -6.000000e+00 2.133508e-04 284.12 -2.00 20.00 -2.00 315.66 0.00e+00 1.222 0.000 302.00 328.00 3 2.9721e+00 1.1220e-03 1.5079e-02 -6.0000e+00 1.1760e-02 2.8248e-02 1.2495e-03 8.7844e-03 -6.0000e+00 1.2691e-02 1.3956e-03 7.1435e-04 4.3057e-03 -6.0000e+00 7.5747e-03 -4.4494e-03 3.1142e-04 1.2005e-03 -6.0000e+00 3.0803e-03 6.5778e-03 -6.7209e-05 3.0599e-05 2.2977e-05 -6.0000e+00 2.9283e-04 2.0339e-02 0.0000e+00 10 0 0 10 0 0 100.00 20.91 0.34 0.02034 0.01983 561 133 1 8 0 86.490 15.00 20.91 26.43 21.48 21.48 20.7 1007.30 -1273 -1007 -1534 -1558 -2750 -748 -68 184 -23 4 -1507 -1047 -43 7 584 572 -80 27 412 898 1062 362 434 536 -52 13 351 -243 -401 609 813 93 315 91 -1617 -1286 103 -664 -82 -54 -840 -1189 -764 -967 -817 -745 -577 -377 -30 245 899 877 742 907 520 375 1020 973 958 1274 1421 871 546 608 5 -362 163 196 653 1119 336 -201 -293 -292 -338 -257 8 -264 -123 -345 -1038 -902 -1382 -1395 -642 -475 -471 -399 -53 -319 12 484 512 816 1282 707 -209 170 -257 -630 -256 -378 -692 248 133 -629 -255 -188 -164 -99 -57 -69 -177 102 211 665 733 230 194 213 -336 -209 200 89 854 1058 361 588 565 129 108 42 -260 -116 258 -288 -493 -106 -322 -403 -26 -111 -229 -187 -284 -276 -471 -124 -12 33 -4 1 -312 -227 -10 2 158 165 -24 9 144 317 379 132 162 205 -20 5 135 -90 -144 215 291 35 119 35 -631 -522 45 -333 -46 -34 -567 -840 -549 -699 -585 -524 -396 -253 -20 163 615 626 552 696 409 300 813 775 766 1037 1199 773 504 563 4 -315 137 166 578 1051 335 -205 -295 -281 -304 -214 6 -207 -100 -304 -1000 -936 -1538 -1650 -727 -564 -578 -494 -64 -367 15 530 536 853 1398 833 -267 206 -315 -760 -325 -466 -855 314 177 -806 -341 -263 -239 -148 -86 -101 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