File name: Pandora207s2_ArlingtonTX_20230407_L2Fit_fwvt1c1d20220105p1-8.txt File generation date: 20240213T021729.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 2 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s2_CF_v1d20220105.txt Level 1 file used: Pandora207s2_ArlingtonTX_20230407_L1_smca1c1d20220105p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20230407 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 362 424 Nominal wavelengths inside fitting window [nm]: 492.2324 492.5181 492.8037 493.0893 493.3749 493.6605 493.9460 494.2316 494.5171 494.8025 495.0880 495.3735 495.6589 495.9443 496.2297 496.5150 496.8004 497.0857 497.3710 497.6562 497.9415 498.2267 498.5119 498.7971 499.0823 499.3674 499.6526 499.9377 500.2228 500.5078 500.7929 501.0779 501.3629 501.6479 501.9328 502.2177 502.5027 502.7876 503.0724 503.3573 503.6421 503.9269 504.2117 504.4965 504.7812 505.0659 505.3506 505.6353 505.9200 506.2046 506.4892 506.7738 507.0584 507.3429 507.6275 507.9120 508.1965 508.4809 508.7654 509.0498 509.3342 509.6186 509.9030 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L1 based wavelength change coefficient, order 2, -9=no L1 wavelength change determination Column 79: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 81: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 84: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 85: Atmospheric variability [%], 999=no atmospheric variability was determined Column 86: Wavelength effective temperature [°C], 999=no effective temperature given Column 87: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 88: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 89: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 90: Number of bright count cycles Column 91: Number of dark count cycles Column 92: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 93: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 94: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 95: Integration time [ms] Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Temperature at electronics board 1 [°C], 999=no temperature signal Column 100: Temperature at electronics board 2 [°C], 999=no temperature signal Column 101: Humidity in head sensor [%], -9=no humidity signal Column 102: Pressure in head sensor [hPa], -9=no pressure signal Columns 103-165: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 166-228: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230407T141320.6Z 8497.592600 231 1 14.20 2 64.75 98.38 106.11 264.17 0.00 1 0.00 1 0 36 5.810e-03 5.806e-03 4.484e-04 4.482e-04 2.320562e+03 9.884209e+01 5.512787e+02 -6.000000e+00 1.256446e+03 285.27 -2.00 20.00 -2.00 505.23 0.00e+00 2.592730e-03 3.391723e-05 2.454033e-04 -6.000000e+00 4.653672e-04 285.27 -2.00 20.00 -2.00 500.74 0.00e+00 -7.094682e-01 2.439316e-02 1.668754e-01 -6.000000e+00 3.332513e-01 228.73 -2.00 3.32 -2.00 502.26 0.00e+00 2.330 0.000 489.00 513.00 1 6.4360e+00 1.9846e-03 1.4687e-02 -6.0000e+00 2.7381e-02 2.5476e-02 3.6634e-04 2.0959e-03 -6.0000e+00 5.0052e-03 2.2817e-03 -1.9735e-02 5.1516e-04 1.0930e-03 -6.0000e+00 6.8029e-03 2.3249e-02 1.8482e-03 -4.2714e-06 12 9 9 12 1 1 97.89 20.87 0.00 0.02325 -0.11364 47 52 4 5 0 292.060 15.00 20.66 20.10 21.38 20.87 13.5 973.87 -245 -229 -309 -390 -337 -68 102 184 42 -15 177 109 -1 144 341 159 133 373 272 317 259 234 495 578 514 431 396 181 -168 -458 -579 -776 -967 -972 -821 -678 -699 -637 -552 -433 -489 -445 -390 -63 69 548 902 1318 1322 1299 1067 789 565 197 35 -190 -278 -216 -497 -556 -636 -897 900000 -242 -227 -309 -392 -338 -68 102 186 42 -15 180 110 -1 146 345 161 135 379 276 319 260 233 493 578 516 434 397 181 -166 -452 -569 -761 -947 -951 -806 -667 -691 -632 -548 -428 -481 -436 -384 -62 69 548 907 1329 1338 1312 1074 792 566 196 34 -189 -277 -216 -500 -561 -641 -901 900000 SQ 20230407T142339.3Z 8497.599761 235 1 44.64 2 62.61 99.95 108.21 265.43 0.00 1 0.00 1 0 36 5.738e-03 5.792e-03 7.400e-04 7.384e-04 2.253881e+03 1.603514e+02 5.433568e+02 -6.000000e+00 1.240744e+03 285.27 -2.00 20.00 -2.00 505.31 0.00e+00 2.586963e-03 5.626521e-05 2.428753e-04 -6.000000e+00 4.595632e-04 285.27 -2.00 20.00 -2.00 501.01 0.00e+00 -6.854335e-01 3.999132e-02 1.642292e-01 -6.000000e+00 3.290521e-01 228.73 -2.00 3.32 -2.00 502.52 0.00e+00 2.162 0.000 489.00 513.00 1 8.0891e+00 3.2575e-03 1.4417e-02 -6.0000e+00 2.7036e-02 3.0424e-02 5.9964e-04 2.0702e-03 -6.0000e+00 4.9451e-03 4.4675e-04 -2.0879e-02 8.4606e-04 1.0943e-03 -6.0000e+00 6.7150e-03 1.2859e-01 9.3255e-04 -2.9778e-06 12 8 8 10 0 0 99.94 20.87 0.00 0.12859 -0.01623 74 25 4 5 0 602.960 15.00 20.65 20.23 21.38 20.87 13.6 976.11 -277 -225 -355 -381 -303 -160 -52 141 96 85 52 85 16 235 321 183 322 406 409 297 159 389 483 715 435 426 426 142 -208 -494 -616 -817 -1046 -937 -876 -741 -663 -618 -545 -332 -446 -516 -345 -57 33 375 814 1188 1279 1339 935 772 564 193 30 -182 -216 -317 -406 -561 -661 -812 900000 -268 -219 -348 -374 -298 -157 -51 140 96 85 52 84 16 231 317 181 319 402 404 292 156 376 468 695 425 417 415 137 -200 -473 -588 -778 -994 -889 -834 -707 -635 -594 -564 -342 -457 -527 -354 -58 34 391 852 1248 1347 1406 980 806 587 200 31 -187 -223 -329 -424 -587 -691 -846 900000 SQ 20230407T145015.8Z 8497.618238 254 1 15.99 2 57.14 104.22 113.64 268.72 0.00 1 0.00 1 0 36 5.840e-03 5.824e-03 2.536e-04 2.535e-04 2.166002e+03 5.574795e+01 5.353761e+02 -6.000000e+00 1.263198e+03 285.27 -2.00 20.00 -2.00 505.20 0.00e+00 2.572675e-03 1.914012e-05 2.394137e-04 -6.000000e+00 4.679873e-04 285.27 -2.00 20.00 -2.00 500.63 0.00e+00 -8.052794e-01 1.383551e-02 1.596795e-01 -6.000000e+00 3.349002e-01 228.73 -2.00 3.32 -2.00 502.17 0.00e+00 1.837 0.000 489.00 513.00 1 5.2368e+00 1.1257e-03 1.3979e-02 -6.0000e+00 2.7505e-02 2.8359e-02 2.0858e-04 1.9869e-03 -6.0000e+00 5.0592e-03 8.1880e-03 -1.0559e-02 2.9239e-04 1.0437e-03 -6.0000e+00 6.8294e-03 1.7958e-01 -1.3592e-04 -9.8458e-07 12 8 8 10 0 0 99.95 20.87 0.00 0.17958 0.10634 515 367 4 5 0 30.500 15.00 20.67 20.87 21.38 20.87 13.7 980.37 -226 -185 -268 -374 -296 -126 68 178 39 31 92 110 -72 148 303 204 173 361 361 278 213 312 456 648 508 400 349 163 -138 -444 -635 -821 -1053 -931 -796 -665 -627 -612 -509 -465 -509 -536 -358 -51 105 441 904 1301 1310 1334 1097 852 628 213 55 -243 -273 -324 -417 -617 -705 -797 900000 -224 -185 -270 -378 -298 -127 69 180 39 32 94 112 -73 150 308 207 176 367 367 281 214 311 455 649 510 403 351 163 -137 -438 -624 -805 -1031 -910 -780 -654 -619 -607 -505 -460 -501 -525 -351 -51 104 441 906 1309 1322 1344 1101 852 626 212 54 -241 -270 -323 -417 -619 -707 -795 900000 SQ 20230407T145032.3Z 8497.618429 254 2 15.93 2 57.08 104.27 113.70 268.76 0.00 1 0.00 1 0 29 5.856e-03 5.894e-03 1.748e-03 1.744e-03 2.140123e+03 3.769896e+02 5.094261e+02 -6.000000e+00 1.260563e+03 285.27 -2.00 20.00 -2.00 505.36 0.00e+00 2.559566e-03 1.315130e-04 2.379150e-04 -6.000000e+00 4.662772e-04 285.27 -2.00 20.00 -2.00 501.01 0.00e+00 -6.379998e-01 9.426196e-02 1.551720e-01 -6.000000e+00 3.353100e-01 228.73 -2.00 3.32 -2.00 502.54 0.00e+00 1.834 0.000 489.00 513.00 1 7.5736e+00 7.6836e-03 1.3643e-02 -6.0000e+00 2.7555e-02 2.7765e-02 1.3849e-03 1.9684e-03 -6.0000e+00 4.9850e-03 7.8209e-04 1.4600e-03 2.0007e-03 1.0375e-03 -6.0000e+00 6.8185e-03 6.3767e-02 1.4522e-04 -6.6527e-07 12 8 8 10 0 0 85.79 20.87 0.00 0.06377 0.07389 515 367 4 5 0 30.500 15.00 20.67 20.87 21.38 20.87 13.7 980.37 -204 -428 -338 -387 -159 -143 37 312 138 76 197 15 -81 122 326 217 278 461 358 206 164 415 480 683 445 338 419 -4 -100 -365 -545 -965 -1078 -1064 -903 -651 -611 -865 -650 -677 -378 -614 -265 -137 151 438 892 1343 1148 1250 900 869 603 124 128 -3 -299 -116 -295 -233 -575 -596 -853 -198 -419 -333 -381 -156 -140 36 309 138 76 195 15 -80 121 323 215 276 457 355 203 160 402 466 666 436 332 409 -4 -96 -349 -520 -922 -1026 -1013 -861 -622 -586 -834 -627 -651 -387 -629 -272 -141 157 456 935 1411 1212 1316 944 907 628 129 132 -4 -310 -120 -308 -243 -601 -619 -886 SQ 20230407T145048.8Z 8497.618621 254 3 16.24 2 57.02 104.31 113.76 268.79 0.00 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