File name: Pandora207s2_ArlingtonTX_20230628_L2Fit_fwvt1c1d20220105p1-8.txt File generation date: 20240213T070412.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 2 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s2_CF_v1d20220105.txt Level 1 file used: Pandora207s2_ArlingtonTX_20230628_L1_smca1c1d20220105p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20230628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 362 424 Nominal wavelengths inside fitting window [nm]: 492.2324 492.5181 492.8037 493.0893 493.3749 493.6605 493.9460 494.2316 494.5171 494.8025 495.0880 495.3735 495.6589 495.9443 496.2297 496.5150 496.8004 497.0857 497.3710 497.6562 497.9415 498.2267 498.5119 498.7971 499.0823 499.3674 499.6526 499.9377 500.2228 500.5078 500.7929 501.0779 501.3629 501.6479 501.9328 502.2177 502.5027 502.7876 503.0724 503.3573 503.6421 503.9269 504.2117 504.4965 504.7812 505.0659 505.3506 505.6353 505.9200 506.2046 506.4892 506.7738 507.0584 507.3429 507.6275 507.9120 508.1965 508.4809 508.7654 509.0498 509.3342 509.6186 509.9030 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L1 based wavelength change coefficient, order 2, -9=no L1 wavelength change determination Column 79: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 81: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 84: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 85: Atmospheric variability [%], 999=no atmospheric variability was determined Column 86: Wavelength effective temperature [°C], 999=no effective temperature given Column 87: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 88: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 89: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 90: Number of bright count cycles Column 91: Number of dark count cycles Column 92: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 93: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 94: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 95: Integration time [ms] Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Temperature at electronics board 1 [°C], 999=no temperature signal Column 100: Temperature at electronics board 2 [°C], 999=no temperature signal Column 101: Humidity in head sensor [%], -9=no humidity signal Column 102: Pressure in head sensor [hPa], -9=no pressure signal Columns 103-165: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 166-228: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230628T114218.6Z 8579.487716 46 1 4.88 2 87.23 63.95 142.70 295.19 0.00 1 0.00 1 0 36 6.997e-03 7.217e-03 7.896e-04 7.766e-04 1.027173e+04 1.903704e+02 6.660821e+01 -6.000000e+00 1.554539e+03 292.08 -2.00 20.00 -2.00 505.45 0.00e+00 3.194296e-03 6.099072e-05 2.577187e-04 -6.000000e+00 5.673890e-04 292.08 -2.00 20.00 -2.00 501.57 0.00e+00 2.065046e-02 3.984548e-02 1.540331e-01 -6.000000e+00 4.002607e-01 231.72 -2.00 3.32 -2.00 502.97 0.00e+00 14.003 0.038 489.00 513.00 1 3.8569e+00 3.2281e-03 2.5072e-02 -6.0000e+00 3.2934e-02 -3.7098e-02 5.5617e-04 2.6579e-03 -6.0000e+00 6.0579e-03 5.3259e-03 3.7288e-02 7.3420e-04 1.3195e-03 -6.0000e+00 8.1346e-03 -1.1985e+00 7.9666e-03 -1.1266e-05 12 9 9 12 772 768 -14.27 19.75 0.00 -1.19850 -0.93986 555 1317 4 5 0 8.500 14.99 19.78 33.20 19.85 19.75 16.1 996.92 900000 -682 -549 -480 -310 -149 -180 263 40 207 453 361 128 -1 294 280 299 540 496 431 353 177 296 556 564 477 655 339 -112 -519 -689 -996 -1230 -1137 -1176 -997 -924 -799 -428 -325 -269 -598 -764 -434 -302 104 808 1450 1585 1626 1379 984 874 342 126 -255 -290 -105 -350 -291 -376 -538 -833 900000 -568 -464 -410 -265 -128 -157 231 36 185 407 326 116 -1 271 260 280 508 470 409 334 168 282 535 548 467 641 332 -110 -508 -675 -977 -1208 -1117 -1161 -989 -921 -798 -426 -323 -265 -592 -766 -442 -313 109 858 1552 1712 1767 1503 1077 959 377 140 -285 -327 -119 -406 -340 -443 -637 -992 SQ 20230628T114224.0Z 8579.487778 46 2 5.00 2 87.22 63.96 142.72 295.21 0.00 1 0.00 1 0 36 6.957e-03 7.185e-03 7.759e-04 7.631e-04 1.033492e+04 1.871218e+02 7.374802e+01 -6.000000e+00 1.545387e+03 292.08 -2.00 20.00 -2.00 505.46 0.00e+00 3.168587e-03 5.986842e-05 2.581837e-04 -6.000000e+00 5.641195e-04 292.08 -2.00 20.00 -2.00 501.57 0.00e+00 2.209788e-02 3.913266e-02 1.565800e-01 -6.000000e+00 3.979501e-01 231.72 -2.00 3.32 -2.00 502.97 0.00e+00 13.963 0.038 489.00 513.00 1 3.8417e+00 3.1697e-03 2.5123e-02 -6.0000e+00 3.2745e-02 -3.7437e-02 5.4651e-04 2.6979e-03 -6.0000e+00 6.0226e-03 5.4384e-03 3.6080e-02 7.1827e-04 1.3449e-03 -6.0000e+00 8.0893e-03 -1.1684e+00 7.7319e-03 -1.0896e-05 12 9 9 12 772 768 -12.97 19.75 0.00 -1.16836 -0.91809 555 1317 4 5 0 8.500 14.99 19.78 33.20 19.85 19.75 16.1 996.92 900000 -696 -484 -441 -266 -174 -161 182 144 221 262 374 57 96 272 228 335 429 644 541 362 164 153 487 492 690 558 309 -54 -470 -758 -961 -1250 -1119 -1163 -933 -953 -826 -421 -253 -405 -588 -575 -514 -349 106 686 1459 1676 1678 1302 1023 806 341 124 -249 -277 -221 -274 -183 -369 -548 -869 900000 -580 -409 -376 -228 -150 -140 160 128 198 237 338 52 87 250 212 314 404 609 513 343 156 146 468 478 674 547 303 -53 -460 -743 -943 -1228 -1099 -1149 -925 -950 -825 -419 -251 -400 -582 -575 -524 -362 111 729 1560 1809 1822 1420 1119 884 376 138 -278 -313 -252 -317 -214 -434 -648 -1036 SQ 20230628T114229.2Z 8579.487838 46 3 4.97 2 87.20 63.97 142.73 295.23 0.00 1 0.00 1 0 36 6.919e-03 7.140e-03 7.633e-04 7.509e-04 1.007703e+04 1.837785e+02 6.632384e+01 -6.000000e+00 1.536435e+03 292.08 -2.00 20.00 -2.00 505.46 0.00e+00 3.227532e-03 5.898925e-05 2.587841e-04 -6.000000e+00 5.609972e-04 292.08 -2.00 20.00 -2.00 501.58 0.00e+00 5.367801e-02 3.852661e-02 1.555363e-01 -6.000000e+00 3.957706e-01 231.72 -2.00 3.32 -2.00 502.98 0.00e+00 13.924 0.038 489.00 513.00 1 3.8250e+00 3.1217e-03 2.5028e-02 -6.0000e+00 3.2568e-02 -3.7162e-02 5.3796e-04 2.6753e-03 -6.0000e+00 5.9883e-03 5.5461e-03 3.6100e-02 7.1168e-04 1.3310e-03 -6.0000e+00 8.0494e-03 -1.1254e+00 7.4619e-03 -1.0632e-05 12 9 9 12 772 256 -10.44 19.75 0.00 -1.12544 -0.87504 555 1317 4 5 0 8.500 14.99 19.78 33.20 19.85 19.75 16.1 996.92 900000 -712 -440 -347 -345 -194 -99 95 175 208 360 305 83 -22 341 332 205 544 514 567 330 158 129 491 616 479 712 379 -116 -499 -809 -912 -1315 -1104 -1110 -1005 -796 -869 -457 -335 -385 -443 -725 -443 -303 170 680 1439 1595 1623 1411 980 774 377 76 -253 -298 -158 -300 -201 -349 -534 -865 900000 -594 -372 -296 -296 -167 -86 83 155 187 325 276 75 -20 314 309 192 512 487 538 313 150 123 472 598 468 697 371 -114 -488 -793 -894 -1292 -1084 -1096 -997 -792 -869 -455 -333 -381 -438 -727 -451 -314 178 722 1539 1722 1762 1536 1072 849 416 84 -282 -336 -180 -347 -234 -411 -632 -1030 SQ 20230628T114234.3Z 8579.487897 46 4 4.94 2 87.18 63.98 142.75 295.25 0.00 1 0.00 1 0 36 7.020e-03 7.245e-03 7.520e-04 7.398e-04 1.015876e+04 1.811982e+02 5.902990e+01 -6.000000e+00 1.558590e+03 292.08 -2.00 20.00 -2.00 505.46 0.00e+00 3.190722e-03 5.806637e-05 2.615788e-04 -6.000000e+00 5.690918e-04 292.08 -2.00 20.00 -2.00 501.58 0.00e+00 1.629003e-02 3.795817e-02 1.578510e-01 -6.000000e+00 4.015243e-01 231.72 -2.00 3.32 -2.00 502.98 0.00e+00 13.886 0.038 489.00 513.00 1 3.8150e+00 3.0752e-03 2.5082e-02 -6.0000e+00 3.3043e-02 -3.6718e-02 5.3005e-04 2.7000e-03 -6.0000e+00 6.0739e-03 5.6495e-03 3.5338e-02 6.9990e-04 1.3447e-03 -6.0000e+00 8.1703e-03 -1.0932e+00 7.2372e-03 -1.0266e-05 12 9 9 12 772 256 -15.71 19.75 0.00 -1.09323 -0.84811 555 1317 4 5 0 8.500 14.99 19.78 33.20 19.85 19.75 16.1 996.92 900000 -531 -463 -475 -359 -346 -81 34 143 179 349 380 -47 81 290 397 384 545 534 517 366 131 299 496 465 584 586 405 -80 -510 -647 -1078 -1223 -1238 -1146 -939 -924 -838 -469 -226 -320 -577 -689 -458 -296 76 828 1486 1662 1647 1310 1009 789 408 46 -318 -299 -241 -271 -300 -272 -494 -874 900000 -443 -391 -406 -308 -299 -70 30 127 161 315 344 -42 74 268 368 359 513 506 490 347 124 285 478 452 571 574 396 -78 -499 -634 -1059 -1201 -1217 -1132 -932 -921 -838 -468 -224 -315 -571 -690 -467 -307 80 878 1589 1793 1788 1427 1104 866 449 51 -355 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