File name: Pandora207s2_ArlingtonTX_20230818_L2Fit_fwvt1c1d20220105p1-8.txt File generation date: 20240213T103228.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 2 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s2_CF_v1d20220105.txt Level 1 file used: Pandora207s2_ArlingtonTX_20230818_L1_smca1c1d20220105p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20230818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 362 424 Nominal wavelengths inside fitting window [nm]: 492.2324 492.5181 492.8037 493.0893 493.3749 493.6605 493.9460 494.2316 494.5171 494.8025 495.0880 495.3735 495.6589 495.9443 496.2297 496.5150 496.8004 497.0857 497.3710 497.6562 497.9415 498.2267 498.5119 498.7971 499.0823 499.3674 499.6526 499.9377 500.2228 500.5078 500.7929 501.0779 501.3629 501.6479 501.9328 502.2177 502.5027 502.7876 503.0724 503.3573 503.6421 503.9269 504.2117 504.4965 504.7812 505.0659 505.3506 505.6353 505.9200 506.2046 506.4892 506.7738 507.0584 507.3429 507.6275 507.9120 508.1965 508.4809 508.7654 509.0498 509.3342 509.6186 509.9030 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L1 based wavelength change coefficient, order 2, -9=no L1 wavelength change determination Column 79: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 81: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 84: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 85: Atmospheric variability [%], 999=no atmospheric variability was determined Column 86: Wavelength effective temperature [°C], 999=no effective temperature given Column 87: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 88: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 89: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 90: Number of bright count cycles Column 91: Number of dark count cycles Column 92: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 93: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 94: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 95: Integration time [ms] Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Temperature at electronics board 1 [°C], 999=no temperature signal Column 100: Temperature at electronics board 2 [°C], 999=no temperature signal Column 101: Humidity in head sensor [%], -9=no humidity signal Column 102: Pressure in head sensor [hPa], -9=no pressure signal Columns 103-165: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 166-228: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230818T130503.8Z 8630.545183 53 1 5.37 2 76.19 83.18 99.38 75.56 0.00 1 0.00 1 0 50 6.994e-03 7.081e-03 1.381e-04 1.379e-04 4.207149e+03 3.200032e+01 4.725828e+02 -6.000000e+00 1.551129e+03 293.72 -2.00 20.00 -2.00 505.34 0.00e+00 2.951069e-03 1.064112e-05 2.815004e-04 -6.000000e+00 5.650906e-04 293.72 -2.00 20.00 -2.00 501.08 0.00e+00 -5.467325e-01 7.307673e-03 1.821019e-01 -6.000000e+00 3.973937e-01 230.45 -2.00 3.32 -2.00 502.57 0.00e+00 4.092 0.001 489.00 513.00 1 2.6404e+00 5.9602e-04 1.6899e-02 -6.0000e+00 3.2777e-02 -8.3806e-03 1.0550e-04 2.4177e-03 -6.0000e+00 5.8904e-03 7.7551e-02 -3.0725e-03 1.5228e-04 1.2904e-03 -6.0000e+00 8.1345e-03 -1.1846e-01 1.6770e-03 -3.2475e-06 12 9 8 11 4 0 -14.30 19.75 0.00 -0.11846 -0.13977 1653 1963 4 5 0 3.000 15.00 20.02 37.71 20.14 19.75 16.8 980.25 -600 -452 -363 -360 -354 -201 -15 214 201 189 225 129 -74 85 365 318 319 558 540 406 254 180 393 692 701 645 599 293 -128 -554 -779 -989 -1303 -1212 -1077 -867 -792 -684 -467 -418 -533 -614 -553 -192 -33 360 959 1534 1622 1589 1263 997 753 315 57 -279 -285 -198 -290 -387 -488 -748 -989 -561 -426 -345 -344 -339 -192 -15 208 196 185 220 126 -73 83 359 314 316 553 536 403 251 177 387 685 697 643 596 291 -127 -547 -769 -974 -1283 -1193 -1063 -859 -788 -682 -467 -416 -528 -608 -551 -193 -33 367 984 1580 1680 1647 1309 1032 779 326 59 -289 -296 -207 -305 -410 -518 -794 -1050 SQ 20230818T130509.5Z 8630.545249 53 2 5.35 2 76.17 83.19 99.36 75.57 0.00 1 0.00 1 0 50 6.999e-03 7.086e-03 1.377e-04 1.375e-04 4.238781e+03 3.192810e+01 4.693951e+02 -6.000000e+00 1.552066e+03 293.72 -2.00 20.00 -2.00 505.34 0.00e+00 2.950733e-03 1.061380e-05 2.818622e-04 -6.000000e+00 5.654357e-04 293.72 -2.00 20.00 -2.00 501.08 0.00e+00 -5.480608e-01 7.286763e-03 1.822050e-01 -6.000000e+00 3.976298e-01 230.45 -2.00 3.32 -2.00 502.57 0.00e+00 4.086 0.001 489.00 513.00 1 2.6374e+00 5.9433e-04 1.6910e-02 -6.0000e+00 3.2796e-02 -8.4380e-03 1.0519e-04 2.4216e-03 -6.0000e+00 5.8944e-03 7.7848e-02 -2.9441e-03 1.5179e-04 1.2941e-03 -6.0000e+00 8.1395e-03 -1.0208e-01 1.5223e-03 -2.9653e-06 12 9 8 11 4 0 -17.65 19.75 0.00 -0.10208 -0.12250 1653 1963 4 5 0 3.000 15.00 20.02 37.71 20.14 19.75 16.8 980.64 -585 -410 -355 -362 -354 -223 -46 239 208 191 223 129 -71 105 341 292 343 556 535 411 256 162 363 682 714 669 588 300 -136 -566 -767 -1010 -1290 -1227 -1091 -883 -765 -667 -476 -426 -538 -624 -549 -207 -16 359 952 1501 1610 1612 1312 983 752 306 67 -262 -289 -197 -272 -375 -493 -755 -997 -547 -387 -337 -346 -339 -214 -44 231 203 187 219 126 -69 102 335 289 340 551 531 407 253 159 357 674 710 667 586 298 -135 -558 -756 -995 -1271 -1208 -1077 -875 -761 -666 -475 -424 -534 -618 -546 -207 -16 365 976 1547 1667 1670 1359 1018 778 317 69 -271 -300 -206 -287 -397 -523 -800 -1059 SQ 20230818T130515.0Z 8630.545313 53 3 5.28 2 76.15 83.20 99.35 75.59 0.00 1 0.00 1 0 43 7.002e-03 7.090e-03 1.374e-04 1.372e-04 4.255865e+03 3.185611e+01 4.709889e+02 -6.000000e+00 1.552843e+03 293.72 -2.00 20.00 -2.00 505.34 0.00e+00 2.937733e-03 1.057789e-05 2.821327e-04 -6.000000e+00 5.657264e-04 293.72 -2.00 20.00 -2.00 501.08 0.00e+00 -5.612568e-01 7.268537e-03 1.829390e-01 -6.000000e+00 3.978322e-01 230.45 -2.00 3.32 -2.00 502.58 0.00e+00 4.081 0.001 489.00 513.00 1 2.6350e+00 5.9273e-04 1.6959e-02 -6.0000e+00 3.2814e-02 -8.1996e-03 1.0493e-04 2.4319e-03 -6.0000e+00 5.8963e-03 7.8185e-02 -3.5254e-03 1.5133e-04 1.2999e-03 -6.0000e+00 8.1448e-03 -7.3993e-02 1.3159e-03 -2.6571e-06 12 9 8 11 4 0 -3.83 19.75 0.00 -0.07399 -0.09845 1653 1963 4 5 0 3.000 15.00 20.02 37.71 20.14 19.75 16.8 980.64 -581 -406 -346 -360 -349 -221 -13 244 202 191 228 126 -78 93 336 303 325 543 553 397 230 156 372 686 720 646 595 284 -117 -545 -773 -1002 -1296 -1243 -1081 -904 -768 -674 -492 -422 -515 -628 -540 -222 -32 364 964 1504 1619 1605 1314 1011 726 326 63 -273 -296 -203 -260 -388 -489 -752 -980 -544 -383 -329 -344 -334 -212 -13 236 197 186 223 123 -77 91 330 299 322 539 549 394 227 154 366 678 716 644 593 282 -115 -538 -763 -987 -1276 -1224 -1067 -896 -765 -672 -492 -421 -511 -622 -537 -223 -32 371 989 1550 1677 1664 1361 1046 751 337 66 -283 -308 -212 -274 -411 -518 -797 -1040 SQ 20230818T130520.6Z 8630.545377 53 4 5.22 2 76.14 83.21 99.33 75.60 0.00 1 0.00 1 0 50 6.990e-03 7.077e-03 1.368e-04 1.366e-04 4.285972e+03 3.174582e+01 4.650287e+02 -6.000000e+00 1.550151e+03 293.72 -2.00 20.00 -2.00 505.34 0.00e+00 2.951294e-03 1.054288e-05 2.815624e-04 -6.000000e+00 5.647270e-04 293.72 -2.00 20.00 -2.00 501.08 0.00e+00 -5.645140e-01 7.240961e-03 1.822021e-01 -6.000000e+00 3.971374e-01 230.45 -2.00 3.32 -2.00 502.57 0.00e+00 4.076 0.001 489.00 513.00 1 2.6305e+00 5.9058e-04 1.6903e-02 -6.0000e+00 3.2755e-02 -8.1319e-03 1.0452e-04 2.4251e-03 -6.0000e+00 5.8876e-03 7.8599e-02 -2.7204e-03 1.5079e-04 1.2957e-03 -6.0000e+00 8.1284e-03 -1.2794e-01 1.7260e-03 -3.2704e-06 12 9 8 11 4 0 -10.92 19.75 0.00 -0.12794 -0.14681 1653 1963 4 5 0 3.000 15.00 20.02 37.71 20.14 19.75 16.8 980.64 -591 -416 -375 -361 -347 -213 -38 238 183 202 249 127 -91 115 339 302 312 562 536 414 260 179 385 678 710 651 583 294 -149 -540 -784 -999 -1294 -1231 -1064 -875 -764 -677 -467 -424 -533 -631 -530 -208 -46 356 955 1496 1642 1614 1282 991 735 321 55 -263 -276 -208 -276 -381 -508 -718 -1010 -553 -392 -356 -345 -332 -204 -37 231 178 198 244 124 -89 112 334 298 309 557 532 410 257 176 379 671 706 649 581 292 -148 -533 -773 -984 -1274 -1213 -1050 -867 -760 -676 -466 -423 -529 -625 -527 -208 -47 363 979 1542 1700 1673 1328 1026 761 332 57 -272 -286 -218 -291 -404 -539 -762 -1072 SQ 20230818T130526.4Z 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