File name: Pandora207s2_ArlingtonTX_20230911_L2Fit_fwvt1c1d20220105p1-8.txt File generation date: 20240213T120653.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 2 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s2_CF_v1d20220105.txt Level 1 file used: Pandora207s2_ArlingtonTX_20230911_L1_smca1c1d20220105p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20230911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 362 424 Nominal wavelengths inside fitting window [nm]: 492.2324 492.5181 492.8037 493.0893 493.3749 493.6605 493.9460 494.2316 494.5171 494.8025 495.0880 495.3735 495.6589 495.9443 496.2297 496.5150 496.8004 497.0857 497.3710 497.6562 497.9415 498.2267 498.5119 498.7971 499.0823 499.3674 499.6526 499.9377 500.2228 500.5078 500.7929 501.0779 501.3629 501.6479 501.9328 502.2177 502.5027 502.7876 503.0724 503.3573 503.6421 503.9269 504.2117 504.4965 504.7812 505.0659 505.3506 505.6353 505.9200 506.2046 506.4892 506.7738 507.0584 507.3429 507.6275 507.9120 508.1965 508.4809 508.7654 509.0498 509.3342 509.6186 509.9030 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L1 based wavelength change coefficient, order 2, -9=no L1 wavelength change determination Column 79: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 81: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 84: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 85: Atmospheric variability [%], 999=no atmospheric variability was determined Column 86: Wavelength effective temperature [°C], 999=no effective temperature given Column 87: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 88: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 89: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 90: Number of bright count cycles Column 91: Number of dark count cycles Column 92: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 93: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 94: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 95: Integration time [ms] Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Temperature at electronics board 1 [°C], 999=no temperature signal Column 100: Temperature at electronics board 2 [°C], 999=no temperature signal Column 101: Humidity in head sensor [%], -9=no humidity signal Column 102: Pressure in head sensor [hPa], -9=no pressure signal Columns 103-165: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 166-228: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230911T135409.4Z 8654.579276 159 1 44.87 2 68.90 98.50 31.10 101.34 0.00 1 0.00 1 0 43 6.939e-03 6.975e-03 3.350e-04 3.348e-04 3.330117e+03 7.708881e+01 5.874946e+02 -6.000000e+00 1.537049e+03 292.59 -2.00 20.00 -2.00 505.27 0.00e+00 3.081263e-03 2.576941e-05 2.937936e-04 -6.000000e+00 5.624897e-04 292.59 -2.00 20.00 -2.00 500.90 0.00e+00 -7.447759e-01 1.793611e-02 1.883649e-01 -6.000000e+00 3.944445e-01 229.25 -2.00 3.32 -2.00 502.40 0.00e+00 2.751 0.000 489.00 513.00 1 6.6064e+00 1.4623e-03 1.6844e-02 -6.0000e+00 3.2524e-02 1.2980e-02 2.6676e-04 2.3856e-03 -6.0000e+00 5.8926e-03 1.8018e-03 -2.8199e-02 3.7776e-04 1.2715e-03 -6.0000e+00 8.1040e-03 -2.6031e-03 2.5082e-03 -6.0474e-06 12 9 8 11 4 0 99.53 19.64 0.00 -0.00260 -0.19821 223 76 4 5 0 200.260 15.00 19.65 32.18 19.85 19.64 16.5 935.95 -423 -292 -245 -362 -302 -190 -37 218 176 167 184 109 -180 45 274 243 307 477 482 383 231 156 346 694 689 619 636 287 -109 -515 -772 -959 -1305 -1199 -1067 -855 -780 -648 -439 -343 -440 -585 -512 -226 3 385 984 1519 1664 1592 1275 983 720 292 -11 -371 -357 -357 -441 -591 -716 -986 900000 -409 -285 -241 -357 -298 -187 -37 217 176 168 184 109 -179 45 275 244 309 480 485 384 230 155 344 693 690 621 637 286 -108 -509 -762 -945 -1285 -1179 -1052 -845 -775 -645 -437 -340 -434 -575 -506 -225 3 388 996 1543 1696 1623 1297 998 730 295 -11 -375 -362 -364 -452 -608 -736 -1012 900000 SQ 20230911T143806.0Z 8654.609792 181 1 45.18 2 59.87 105.38 22.46 112.61 0.00 1 0.00 1 0 43 6.899e-03 6.916e-03 1.412e-04 1.411e-04 2.655075e+03 3.206578e+01 5.914319e+02 -6.000000e+00 1.530129e+03 292.59 -2.00 20.00 -2.00 505.24 0.00e+00 3.071662e-03 1.083128e-05 2.805641e-04 -6.000000e+00 5.596852e-04 292.59 -2.00 20.00 -2.00 500.79 0.00e+00 -8.071491e-01 7.594375e-03 1.751120e-01 -6.000000e+00 3.925118e-01 229.24 -2.00 3.32 -2.00 502.31 0.00e+00 1.983 0.000 489.00 513.00 1 5.0720e+00 6.1953e-04 1.5539e-02 -6.0000e+00 3.2356e-02 1.6479e-02 1.1357e-04 2.1690e-03 -6.0000e+00 5.8863e-03 9.3824e-03 -2.0358e-02 1.6154e-04 1.1594e-03 -6.0000e+00 8.0675e-03 2.7714e-02 1.8011e-03 -4.7382e-06 12 9 8 11 4 0 99.46 19.64 0.00 0.02771 -0.11350 868 296 4 5 0 51.500 15.00 19.64 32.82 19.85 19.64 16.4 940.48 -420 -274 -265 -280 -323 -176 -8 235 153 131 186 69 -139 45 264 243 271 479 474 355 194 158 406 671 705 648 601 281 -140 -537 -762 -1012 -1247 -1236 -1043 -843 -728 -590 -423 -348 -509 -609 -496 -167 -22 421 998 1518 1618 1595 1290 992 697 270 -23 -341 -415 -340 -438 -575 -726 -985 900000 -411 -270 -263 -278 -321 -175 -8 235 154 133 187 69 -139 45 265 245 274 484 479 357 194 157 404 671 707 650 602 280 -139 -531 -752 -998 -1226 -1215 -1028 -833 -722 -586 -420 -345 -502 -599 -490 -166 -22 423 1007 1536 1642 1617 1305 1002 703 272 -24 -342 -417 -343 -444 -586 -739 -1000 900000 SQ 20230911T145510.5Z 8654.621649 189 1 6.11 2 56.43 108.34 19.30 118.98 0.00 1 0.00 1 0 50 6.864e-03 6.871e-03 1.102e-04 1.102e-04 2.453560e+03 2.493080e+01 5.776104e+02 -6.000000e+00 1.522058e+03 292.58 -2.00 20.00 -2.00 505.22 0.00e+00 2.988523e-03 8.447898e-06 2.704566e-04 -6.000000e+00 5.569791e-04 292.58 -2.00 20.00 -2.00 500.71 0.00e+00 -8.131240e-01 5.940391e-03 1.672514e-01 -6.000000e+00 3.904520e-01 229.24 -2.00 3.32 -2.00 502.24 0.00e+00 1.803 0.000 489.00 513.00 1 2.5062e+00 4.8471e-04 1.4835e-02 -6.0000e+00 3.2176e-02 1.8692e-02 8.9051e-05 2.0543e-03 -6.0000e+00 5.8804e-03 1.2555e-01 -1.2407e-02 1.2650e-04 1.1016e-03 -6.0000e+00 8.0249e-03 7.7516e-02 8.5207e-04 -2.8093e-06 12 9 8 11 4 0 98.10 19.64 0.00 0.07752 -0.00854 1866 635 4 5 0 3.060 15.00 19.65 33.76 19.85 19.64 16.9 948.77 -410 -261 -243 -304 -330 -191 5 231 161 130 151 38 -142 45 269 248 279 514 490 340 199 160 389 692 702 649 594 262 -148 -550 -771 -1014 -1259 -1219 -1028 -824 -710 -560 -394 -380 -498 -613 -503 -154 -10 448 1004 1517 1619 1574 1266 971 676 256 -36 -351 -396 -338 -434 -592 -704 -984 900000 -402 -258 -242 -303 -329 -190 5 232 162 131 152 39 -142 46 271 251 282 519 495 343 199 159 388 692 704 652 595 261 -147 -544 -761 -999 -1238 -1198 -1011 -814 -704 -556 -392 -377 -491 -603 -496 -152 -10 449 1011 1532 1640 1594 1279 978 680 256 -36 -351 -396 -340 -439 -601 -713 -995 900000 SQ 20230911T145517.2Z 8654.621727 189 2 6.59 2 56.41 108.36 19.28 119.03 0.00 1 0.00 1 0 43 6.958e-03 6.915e-03 1.278e-04 1.275e-04 2.760981e+03 2.903391e+01 5.404154e+02 -6.000000e+00 1.536385e+03 292.58 -2.00 20.00 -2.00 505.38 0.00e+00 2.855461e-03 9.741808e-06 2.647949e-04 -6.000000e+00 5.612530e-04 292.58 -2.00 20.00 -2.00 500.96 0.00e+00 -7.526114e-01 6.875061e-03 1.671567e-01 -6.000000e+00 3.951055e-01 229.24 -2.00 3.32 -2.00 502.51 0.00e+00 1.801 0.000 489.00 513.00 1 2.7256e+00 5.6139e-04 1.4764e-02 -6.0000e+00 3.2577e-02 1.6420e-02 9.9324e-05 2.1094e-03 -6.0000e+00 5.8599e-03 1.0055e-01 9.5043e-04 1.4567e-04 1.0948e-03 -6.0000e+00 8.0904e-03 6.9719e-03 5.4872e-04 -1.5031e-06 12 9 8 11 4 0 75.23 19.64 0.00 0.00697 0.01356 1866 635 4 5 0 3.060 15.00 19.65 33.76 19.85 19.64 16.9 948.77 -520 -325 -312 -355 -354 -223 5 249 187 180 189 81 -118 126 334 298 317 560 528 336 209 161 416 694 719 636 566 228 -174 -590 -790 -1029 -1267 -1215 -1035 -839 -722 -610 -482 -469 -620 -690 -524 -147 28 487 1069 1558 1662 1591 1280 993 722 286 33 -239 -237 -134 -211 -363 -466 -701 -911 -505 -317 -307 -350 -349 -220 5 247 187 180 189 81 -117 125 333 297 317 559 527 334 207 159 409 685 712 631 560 225 -171 -576 -770 -1000 -1230 -1179 -1006 -818 -706 -598 -473 -459 -604 -670 -510 -144 27 482 1062 1553 1661 1590 1276 988 716 283 35 -255 -254 -144 -228 -394 -505 -758 -983 SQ 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