File name: Pandora119s1_Athens-NOA_20190317_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T150653.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190317_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190317 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190317T043931.0Z 7015.194109 297 1 32.01 2 89.71 92.09 113.22 322.82 0.00 1 0.00 1 0 15 6.247e-02 6.032e-02 5.276e-02 5.199e-02 7.223350e+03 3.675379e+03 4.210538e+02 -6.000000e+00 3.546223e+03 278.74 -2.00 20.00 -2.00 505.26 0.00e+00 1.792748e-03 1.443643e-03 1.128654e-04 -6.000000e+00 1.763046e-03 278.74 -2.00 20.00 -2.00 500.14 0.00e+00 1.625395e+00 1.069790e+00 7.173777e-02 -6.000000e+00 1.259239e+00 226.56 -2.00 3.45 -2.00 501.76 0.00e+00 20.177 0.140 489.00 513.00 1 9.2970e+00 8.2072e-02 3.5283e-02 -6.0000e+00 9.6699e-02 1.2320e-01 2.0605e-02 2.4054e-03 -6.0000e+00 2.4688e-02 8.9647e-06 1.0914e-03 5.5945e-03 5.1415e-05 -6.0000e+00 7.1755e-03 2.4240e-02 -3.9790e-05 12 8 8 10 0 0 59.76 19.53 7.56 0.02424 0.03181 8 2 1 4 0 4000.000 24.96 19.99 19.53 4351 672 -6751 2555 5300 -2378 9665 -5972 6845 -9921 11716 451 -5383 3450 672 7515 -6281 9041 -2562 2381 9119 -2517 3326 -5294 8257 3147 64 3246 -13555 2619 -5109 499 -3585 6959 6072 -4392 1448 -3179 3087 591 -3598 -4283 6863 3381 -5623 5232 -4129 6553 -7064 524 -526 -2730 3314 -11282 1402 -3485 160 -217 1912 4764 -2342 -398 -1058 6637 1094 2176 5138 -972 9974 -11951 -3307 -947 -1669 10381 -3249 5658 -3829 6859 323 3148 -5083 -5140 -2568 -4146 3927 -4265 20395 -3538 -1443 55 -4039 12681 -10369 6028 -3049 -6182 5197 1598 7069 -9443 7019 -6918 7102 -1656 -165 3218 -2794 9635 -11749 4795 -8538 -4796 2693 -3774 10559 -6236 12426 -1456 3482 4951 -355 19250 -5987 -17 -9424 14331 -297 13048 -687 -5166 383 -4332 7368 994 2619 4412 -8550 -802 672 4908 -3092 -2067 -2409 1828 9255 -5903 4650 -5306 6146 -366 4001 649 -7222 2569 5329 -2639 9666 -7037 7084 -12023 11278 479 -5975 3469 692 7264 -7073 8921 -2896 2592 9327 -2824 3528 -6140 8391 3362 70 3392 -16378 2627 -5466 507 -3873 6954 6250 -5054 1564 -3563 3218 628 -3995 -4823 6983 3599 -6595 5509 -4741 6668 -8074 542 -535 -2785 3164 -12285 1412 -3684 166 -228 1970 4769 -2520 -421 -1127 6525 1126 2184 4927 -977 8867 -13090 -3307 -928 -1660 9228 -3314 5232 -3833 6080 303 2858 -5024 -5113 -2509 -4151 3656 -4329 16182 -3560 -1420 54 -4025 11063 -11157 5604 -2974 -6068 4540 1376 5789 -8812 5730 -6481 5983 -1572 -157 2975 -2725 8237 -12423 4331 -8922 -4886 2569 -3869 9433 -6633 11024 -1484 3349 4626 -345 15188 -6063 -16 -9705 11948 -280 11008 -647 -5063 351 -4109 6157 883 2309 3885 -8732 -770 645 4560 -3136 -2086 -2448 1781 8318 -6093 4241 -5258 5390 -344 SO 20190317T044350.0Z 7015.197107 301 1 32.01 2 88.86 92.76 113.71 323.73 0.00 1 0.00 1 0 15 3.174e-02 3.138e-02 3.151e-02 3.124e-02 4.317504e+03 2.086114e+03 2.132976e+02 -6.000000e+00 1.801890e+03 278.74 -2.00 20.00 -2.00 505.29 0.00e+00 2.515697e-03 8.711219e-04 1.319020e-04 -6.000000e+00 8.960769e-04 278.74 -2.00 20.00 -2.00 500.20 0.00e+00 3.012284e+00 6.417793e-01 5.629786e-02 -6.000000e+00 6.403758e-01 226.56 -2.00 3.45 -2.00 501.83 0.00e+00 18.397 0.106 489.00 513.00 1 8.9121e+00 4.9351e-02 3.0490e-02 -6.0000e+00 4.9170e-02 7.5238e-02 1.2348e-02 1.9517e-03 -6.0000e+00 1.2565e-02 1.5241e-05 -7.8596e-04 3.4504e-03 5.0574e-05 -6.0000e+00 3.6459e-03 2.8684e-03 2.7724e-05 12 8 8 10 0 0 56.70 19.53 4.18 0.00287 -0.00258 8 2 1 4 0 4000.000 24.96 20.00 19.53 -3831 1215 2956 3492 2656 -3130 -778 -1790 1271 -3773 1023 -5846 3315 1259 2050 3118 -1938 1296 -3803 780 778 -3573 1170 -3907 1893 -2645 4331 -3195 96 1955 -1765 9000 -2966 1598 510 2594 1876 -632 3232 -4784 2931 -756 4 1680 -510 2163 -3265 890 -1255 2866 3265 41 -927 -3536 3755 -4018 3970 -1424 1631 3213 -419 625 511 781 -4137 2390 4834 3943 -1276 -3061 3416 -6527 1504 -2120 1676 3372 -2323 -447 -3219 1170 -2702 493 656 -181 -1153 -7268 2954 -6959 5189 -653 2599 3913 -4337 4652 -2562 1053 -2062 3253 -715 -4484 949 -5607 5627 -1511 3221 4437 2621 1853 -6242 5383 -3647 1808 349 2019 294 -2413 2981 -884 -751 -2022 5956 135 301 1131 609 4664 -4604 2548 2587 843 2734 -1333 374 -3503 -15 -786 -1422 -628 -3524 1512 -2715 5274 -549 7250 -1381 -1097 -2359 -3485 6459 -6337 -3737 1167 2791 3385 2673 -3417 -844 -1982 1365 -4229 1078 -6505 3319 1273 2045 3088 -2045 1351 -4262 846 850 -4088 1280 -4513 2072 -2957 4609 -3530 104 2010 -1807 8497 -3132 1656 547 2753 2000 -685 3336 -5318 3019 -813 4 1802 -564 2334 -3700 956 -1351 2890 3195 41 -918 -3620 3652 -4332 4031 -1542 1717 3328 -451 650 532 810 -4466 2384 4630 3753 -1262 -3046 3165 -6685 1431 -2110 1610 3161 -2271 -423 -3095 1072 -2576 458 612 -171 -1111 -7482 2747 -7138 4710 -630 2446 3675 -4458 4365 -2553 992 -1956 2854 -639 -4100 823 -5153 4873 -1413 2924 3993 2385 1685 -6140 4750 -3571 1703 338 1941 290 -2458 2891 -890 -750 -2020 5421 129 286 1071 583 4300 -4664 2403 2436 805 2538 -1243 347 -3289 -14 -734 -1362 -607 -3557 1467 -2770 4997 -554 6781 -1402 -1098 -2351 -3451 5733 -6409 SO 20190317T044800.0Z 7015.200000 305 1 32.01 2 88.04 93.40 114.17 324.61 0.00 1 0.00 1 0 15 1.944e-02 1.926e-02 1.960e-02 1.947e-02 7.565695e+03 1.370438e+03 4.609823e+02 -6.000000e+00 1.103252e+03 278.74 -2.00 20.00 -2.00 505.28 0.00e+00 2.394437e-03 5.390914e-04 1.354920e-04 -6.000000e+00 5.488264e-04 278.74 -2.00 20.00 -2.00 500.19 0.00e+00 1.112579e+00 4.015165e-01 6.719135e-02 -6.000000e+00 3.927247e-01 226.56 -2.00 3.45 -2.00 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