File name: Pandora119s1_Athens-NOA_20190530_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T155746.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190530_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190530 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190530T031124.0Z 7089.132917 289 1 32.01 2 89.74 62.23 65.20 109.33 0.00 1 0.00 1 0 15 5.498e-02 5.323e-02 5.455e-02 5.389e-02 1.293554e+04 4.203865e+03 8.145696e+02 -6.000000e+00 3.213978e+03 286.17 -2.00 20.00 -2.00 505.34 0.00e+00 4.163354e-03 1.535590e-03 1.884515e-04 -6.000000e+00 1.579597e-03 286.17 -2.00 20.00 -2.00 500.31 0.00e+00 1.841878e+00 1.113575e+00 9.181134e-02 -6.000000e+00 1.110363e+00 231.91 -2.00 3.45 -2.00 501.92 0.00e+00 20.017 0.137 489.00 513.00 1 9.2556e+00 8.5615e-02 3.5435e-02 -6.0000e+00 8.5464e-02 9.0350e-02 2.1208e-02 2.8064e-03 -6.0000e+00 2.1790e-02 8.9673e-06 -4.4179e-03 5.6818e-03 8.6170e-05 -6.0000e+00 6.3192e-03 1.3562e-02 3.8131e-05 12 8 8 10 0 0 -419.32 20.69 6.08 0.01356 -0.01708 8 2 1 4 0 4000.000 25.90 20.00 20.69 496 -700 471 -2261 28 843 -4176 -1112 -2550 3914 1467 -6353 -10389 10735 6789 -110 -2060 7461 -6266 -11842 4259 3621 386 5644 3652 -1831 447 -20 937 2335 4763 10431 1615 6253 -2298 -4878 -3329 -521 -150 -31 -1148 7007 -4705 1234 146 -3639 2624 6847 3829 -1668 1164 -10397 -2291 532 -3792 2754 -1512 6136 4315 -2501 1346 6204 1170 -3278 3914 -2187 -7141 -1726 578 14398 -1704 8463 -3627 346 1644 7077 -4029 18015 -4529 -187 -10088 -7030 -2706 -409 2329 -1811 7034 3613 2487 -291 -4017 5184 -2467 1578 4652 1320 -1365 -1612 16224 153 -8194 2790 -5409 -2547 -132 10920 -6650 3417 -5530 111 11411 5421 -10231 -1899 5354 5619 1923 -2083 6424 -6051 -8525 7131 -6083 -3359 7169 9644 7202 2826 3224 -8118 4940 -1533 -5272 200 -15088 2643 3396 696 2960 2776 292 -1638 9711 -2030 -4651 -6540 -83 98 1920 2958 460 -662 452 -2300 28 878 -4653 -1214 -2828 4035 1529 -7054 -11837 9785 6396 -111 -2150 7216 -7096 -14014 4433 3804 409 5851 3782 -2008 478 -22 965 2314 4527 9364 1609 6113 -2508 -5528 -3709 -560 -159 -33 -1226 6954 -5313 1330 160 -4179 2821 6981 3956 -1780 1178 -11557 -2327 528 -4020 2808 -1603 6256 4386 -2724 1412 6224 1237 -3617 3989 -2338 -7900 -1781 576 12335 -1703 7642 -3720 344 1619 6558 -4111 14507 -4514 -177 -10547 -7155 -2654 -395 2208 -1797 6388 3382 2344 -282 -4062 4824 -2431 1520 4262 1214 -1251 -1439 11844 130 -7366 2292 -4995 -2375 -123 9268 -6724 3107 -5492 105 9758 4985 -11108 -1911 5041 5319 1907 -2163 6106 -6437 -9146 6447 -6236 -3358 6481 8545 6558 2690 3051 -8370 4429 -1448 -5117 183 -16219 2415 3138 672 2836 2698 294 -1691 8986 -2113 -4947 -7013 -82 95 1815 2775 SO 20190530T031548.0Z 7089.135972 293 1 32.01 2 88.97 62.90 64.39 110.12 0.00 1 0.00 1 0 15 3.855e-02 3.855e-02 3.373e-02 3.349e-02 8.818945e+03 2.461307e+03 7.132980e+02 -6.000000e+00 2.252926e+03 286.17 -2.00 20.00 -2.00 505.36 0.00e+00 4.336021e-03 9.543348e-04 2.050047e-04 -6.000000e+00 1.108253e-03 286.17 -2.00 20.00 -2.00 500.39 0.00e+00 2.265615e+00 6.857721e-01 4.200115e-02 -6.000000e+00 7.811490e-01 231.91 -2.00 3.45 -2.00 502.00 0.00e+00 18.516 0.108 489.00 513.00 1 8.9458e+00 5.2767e-02 3.0957e-02 -6.0000e+00 6.0086e-02 5.9044e-02 1.3075e-02 1.9969e-03 -6.0000e+00 1.5391e-02 1.4729e-05 5.4539e-03 3.6306e-03 1.0699e-04 -6.0000e+00 4.4307e-03 6.2886e-02 -5.4854e-04 12 8 8 10 0 0 33.31 20.70 6.67 0.06289 0.10072 8 2 1 4 0 4000.000 26.00 20.00 20.70 -2029 -6432 -3783 1342 3846 4239 -5330 -879 3251 -5385 -2502 -1537 -1010 2298 -270 9998 -1373 -389 2144 6877 -4555 4594 -937 -2222 4558 -3325 2400 -2547 252 648 -3324 1109 -5467 2208 -1074 531 1578 -343 6119 2897 2205 -1950 2043 -2131 -3495 1400 -1588 3892 -1855 822 -579 -3336 -1080 -8270 4002 -1734 -617 -1074 -694 70 2924 6159 4871 4017 1385 -1528 348 594 -794 2740 5368 -5137 5834 257 3995 -260 781 1398 -2300 -729 -2706 2446 -1233 -3407 36 -1968 2351 -720 4759 -7129 6770 -604 4790 5366 -1545 1847 -2435 3854 19 -1762 2237 -2504 4640 143 -393 -1646 2540 3236 5017 4021 -10042 6355 1323 -7400 -3610 1886 4362 -7844 612 -4472 1820 -5038 1637 4690 -371 2541 -4415 7712 -7611 5236 -4292 -3460 1908 -424 5698 -5573 2303 3498 5798 3274 -4249 4858 -6941 9139 -4255 564 1998 -2832 885 -3948 -1925 -6465 -3809 1326 3715 4173 -5870 -933 3307 -5913 -2631 -1578 -1017 2216 -266 8934 -1394 -399 2188 6776 -5059 4669 -1010 -2438 4698 -3713 2518 -2771 261 652 -3434 1102 -5767 2275 -1140 559 1639 -360 5973 2911 2239 -2084 2125 -2341 -3928 1502 -1747 4004 -1984 836 -583 -3388 -1067 -8873 3891 -1832 -658 -1161 -750 75 3056 6255 5019 4162 1425 -1596 351 590 -788 2664 5056 -5255 5388 253 3795 -255 748 1312 -2216 -689 -2609 2252 -1185 -3373 34 -1942 2220 -699 4365 -7383 6150 -597 4512 4999 -1516 1708 -2288 3313 17 -1552 1900 -2277 4059 136 -372 -1587 2338 2940 4480 3663 -10686 5824 1290 -7943 -3759 1874 4260 -8671 618 -4689 1766 -5180 1570 4382 -367 2450 -4574 7080 -8134 4901 -4376 -3455 1789 -406 5173 -5623 2188 3339 5486 3213 -4533 4760 -7686 8620 -4565 569 1956 -2864 856 -4025 SO 20190530T032003.0Z 7089.138924 297 1 32.01 2 88.23 63.55 63.62 110.88 0.00 1 0.00 1 0 15 1.860e-02 1.841e-02 1.941e-02 1.931e-02 1.154239e+04 1.454439e+03 8.083069e+02 -6.000000e+00 1.087180e+03 286.17 -2.00 20.00 -2.00 505.37 0.00e+00 3.827466e-03 5.475841e-04 2.037587e-04 -6.000000e+00 5.346688e-04 286.17 -2.00 20.00 -2.00 500.50 0.00e+00 1.729114e+00 3.938895e-01 7.049349e-02 -6.000000e+00 3.766272e-01 231.91 -2.00 3.45 -2.00 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