File name: Pandora119s1_Athens-NOA_20190610_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162401.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190610_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190610T030823.0Z 7100.130822 305 1 32.01 2 89.75 60.53 129.70 332.74 0.00 1 0.00 1 0 85 1.261e-01 1.150e-01 1.255e-01 1.207e-01 5.459499e+03 8.518184e+03 4.561784e+02 -6.000000e+00 7.401978e+03 287.24 -2.00 20.00 -2.00 505.23 0.00e+00 4.673121e-03 3.404269e-03 2.833483e-04 -6.000000e+00 3.631551e-03 287.24 -2.00 20.00 -2.00 499.99 0.00e+00 1.761492e+00 2.509631e+00 3.892237e-02 -6.000000e+00 2.540846e+00 232.48 -2.00 3.45 -2.00 501.63 0.00e+00 19.987 0.136 489.00 513.00 1 1.0102e+01 1.9373e-01 3.4956e-02 -6.0000e+00 1.9573e-01 1.4850e-01 4.8348e-02 1.9293e-03 -6.0000e+00 4.9737e-02 3.8545e-06 5.9126e-03 1.3120e-02 1.3874e-04 -6.0000e+00 1.4482e-02 -7.0849e-03 3.4785e-04 12 8 8 10 0 0 68.47 21.51 8.26 -0.00708 0.03393 8 2 1 4 0 4000.000 26.62 20.00 21.51 27213 -19475 12487 -3983 -7079 304 -8594 16285 4291 13438 -6960 17720 64 -6390 9491 -698 8083 -14041 6512 -4044 -10410 2228 5753 11399 -11037 -4067 -3458 -1772 1502 283 11341 19986 -6385 -217 -1646 -10678 5039 12155 2448 8209 8514 10552 -2369 4617 -4862 -239 6823 -11398 22786 -6616 7794 -14878 10830 41651 -21828 26076 -10594 -1551 -7752 -637 30866 -4070 15530 -23744 13180 7062 9319 4652 -3416 9321 -607 21503 -881 15326 -1840 -14599 -5460 1064 26466 -3903 -15031 -4350 45118 -13581 -5382 2081 7439 10268 -11921 2496 25851 1034 5670 13585 3805 -7418 -12141 -3350 18162 1470 6153 -1862 -15104 11783 13161 -9459 -4954 975 10801 16936 15531 -2944 -7136 1341 -1954 -8011 -4539 -12876 -14669 8560 19886 4742 -13762 -5339 18342 -7519 15116 -3014 5835 18869 19029 3894 -9901 -434 7796 12684 7649 -1328 6968 3138 22205 -15946 2489 -8756 14207 -17320 14768 9059 -14595 -3336 21189 -24031 11857 -4469 -8395 341 -10659 15774 4650 13102 -8188 16030 68 -7191 9102 -748 8061 -17819 6827 -4744 -13045 2465 6161 11588 -13707 -4823 -4034 -1994 1594 297 10622 17378 -7214 -236 -1845 -13095 5239 11967 2568 8125 8454 10379 -2684 4929 -5736 -268 7072 -13942 19362 -7351 7326 -17320 9775 28892 -27803 21589 -12827 -1724 -9169 -702 24882 -4662 14598 -31972 12430 6968 8847 4561 -3491 8529 -612 17469 -879 13404 -1852 -16471 -5531 997 19606 -3811 -16456 -4301 28086 -14909 -5468 1962 6632 8875 -12871 2347 19443 1006 5279 11577 3508 -7469 -12482 -3078 13219 1257 5075 -1705 -15855 9898 10976 -9594 -4761 902 9106 13611 12859 -2898 -7407 1288 -1953 -8552 -4684 -14354 -16439 7492 15347 4234 -14812 -5305 14427 -7670 12291 -2932 5176 14562 14460 3396 -9837 -393 6570 10351 6672 -1284 6263 2950 17334 -17848 2319 -9094 11889 -19036 11834 7581 -15073 -3108 SO 20190610T031248.0Z 7100.133889 309 1 32.01 2 88.99 61.21 130.09 334.00 0.00 1 0.00 1 0 32 6.991e-02 6.963e-02 7.434e-02 7.281e-02 1.399419e+04 5.898467e+03 9.917443e+02 -6.000000e+00 4.103383e+03 287.24 -2.00 20.00 -2.00 505.28 0.00e+00 1.219384e-03 2.062106e-03 5.279989e-05 -6.000000e+00 2.015519e-03 287.24 -2.00 20.00 -2.00 499.95 0.00e+00 1.371181e+00 1.529769e+00 5.655567e-02 -6.000000e+00 1.417533e+00 232.48 -2.00 3.45 -2.00 501.61 0.00e+00 18.520 0.109 489.00 513.00 1 9.8524e+00 1.1751e-01 3.0780e-02 -6.0000e+00 1.0907e-01 1.1991e-01 2.9169e-02 2.3593e-03 -6.0000e+00 2.7944e-02 6.5591e-06 8.5748e-03 7.4815e-03 7.9476e-05 -6.0000e+00 8.0324e-03 2.5666e-02 -3.6481e-04 12 8 8 10 0 0 49.43 21.50 4.85 0.02567 0.08514 8 2 1 4 0 4000.000 26.62 20.00 21.50 276 -1608 -4379 5350 3929 1974 4792 -2527 -7540 135 -2951 3832 -9565 -208 4968 -4547 -1977 -7991 4925 8616 -2451 8031 1760 20392 -5319 -3420 -10050 -6463 14930 -8125 -3792 -1675 -2715 1221 4443 7170 -4492 2664 625 5913 -1658 6341 -1345 16581 -2677 1580 16439 -12790 5374 -4040 1135 4289 3367 10640 -7169 11033 2023 -11599 -7268 -7326 -9094 3605 -7704 10170 7459 -5919 8584 11096 -6919 10173 4724 7813 2427 1164 4801 4173 10520 5465 -5179 165 117 -12165 -9276 -1671 6919 3821 6869 10338 1124 4132 4696 4565 -3739 -3932 1650 -5303 3261 5573 6192 5514 1002 -2206 -2678 8521 -11870 -314 -291 10490 8288 -4425 -19158 6331 19766 -2506 -72 -2485 -7411 3358 -6606 -1705 5052 2259 563 -1523 692 4020 2722 -1030 -10389 -4922 1400 9265 -847 778 -13186 4106 942 9389 -1112 9847 2602 -8622 5340 -8945 1781 4754 -5540 -3692 10838 687 273 -1640 -4720 5395 4128 2105 5047 -2885 -9032 149 -3297 3942 -11098 -217 4915 -4977 -2141 -9392 5187 8848 -2825 8353 1953 18835 -6371 -4014 -12509 -7644 13931 -9320 -4115 -1790 -2992 1330 4779 7551 -5152 2891 685 6117 -1805 6414 -1484 15845 -3041 1720 15306 -15723 5397 -4346 1130 4057 3196 9499 -7829 10293 2102 -13918 -8362 -8429 -10663 3732 -8935 9823 7327 -6551 8087 10048 -7404 9082 4433 7132 2357 1154 4594 3977 9256 4979 -5062 156 108 -12779 -9546 -1610 6170 3530 6150 8906 1058 3780 4297 4209 -3742 -3885 1501 -5004 2734 4443 4815 4288 823 -1928 -2450 7249 -12703 -302 -278 8962 7228 -4412 -21802 5770 15829 -2455 -69 -2464 -7789 3179 -6862 -1662 4518 2048 516 -1429 637 3588 2463 -966 -10666 -4753 1255 7577 -760 687 -13537 3608 870 8103 -1082 8687 2490 -9066 5017 -9450 1720 4400 -5458 -3518 9090 625 SO 20190610T031705.0Z 7100.136863 313 1 32.01 2 88.25 61.86 130.45 335.24 0.00 1 0.00 1 0 15 6.366e-02 6.174e-02 5.185e-02 5.101e-02 7.419396e+03 3.715153e+03 6.580613e+02 -6.000000e+00 3.736101e+03 287.24 -2.00 20.00 -2.00 505.30 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