File name: Pandora119s1_Athens-NOA_20190924_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T171908.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190924_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190924T041942.0Z 7206.180347 261 1 32.01 2 89.71 90.66 29.40 115.90 0.00 1 0.00 1 0 22 8.290e-02 8.186e-02 7.039e-02 6.913e-02 1.368034e+04 5.465757e+03 1.040199e+03 -6.000000e+00 4.878184e+03 288.13 -2.00 20.00 -2.00 505.42 0.00e+00 -1.011373e-04 1.972001e-03 1.107093e-04 -6.000000e+00 2.394468e-03 288.13 -2.00 20.00 -2.00 500.40 0.00e+00 2.361653e+00 1.403419e+00 6.350135e-02 -6.000000e+00 1.663812e+00 228.43 -2.00 3.45 -2.00 502.02 0.00e+00 19.933 0.135 489.00 513.00 1 9.5656e+00 1.0803e-01 3.4612e-02 -6.0000e+00 1.2823e-01 5.6795e-02 2.6401e-02 2.6297e-03 -6.0000e+00 3.2622e-02 6.7779e-06 -7.0536e-04 7.0697e-03 9.4527e-05 -6.0000e+00 9.5273e-03 3.0970e-02 -2.6137e-05 12 9 8 11 8 0 -25.44 20.96 6.00 0.03097 0.02608 8 2 1 4 0 4000.000 26.21 20.00 20.96 -2864 1582 -7225 -5089 -284 -2608 6587 177 -3583 9 -149 -3632 -15261 11680 -13994 12882 2522 9226 14463 -1810 -3046 7144 -3368 1998 379 3960 -13197 -636 -9290 23779 -590 12303 -1564 -4418 9702 2481 15073 -4550 7553 -7795 -134 16730 -3863 -505 -7968 -730 5322 1944 -8152 1906 -1204 -569 9064 -5011 68 -4283 219 8173 13308 7630 747 4406 -1295 2328 -2539 208 8001 -11869 13832 1113 3045 5442 -4433 -637 -7885 9254 -16814 5013 2281 5647 4520 -7521 -2110 -12447 5097 1905 -818 9138 7421 10864 -5868 14492 13437 -4288 -5185 8478 17532 1049 -5585 -1722 7042 -7900 11779 -3344 -10050 8904 -13375 10531 -7958 10057 7666 -6767 -3181 1205 5858 -22653 1733 15672 17092 7407 -1647 10615 -1311 10190 226 2133 -15838 -1125 552 -6200 10637 -7015 5862 -2642 4279 8565 -9226 4142 985 3027 2828 17201 7061 -9897 76 -10166 8150 -6577 4360 -9718 -2732 1463 -7499 -5338 -292 -2738 6422 186 -3909 9 -154 -3839 -17898 10367 -16013 11343 2504 8765 13328 -1991 -3415 7258 -3812 2151 417 4193 -16489 -691 -10779 19370 -606 11162 -1664 -4977 9702 2689 14346 -5089 7606 -8867 -141 15387 -4294 -549 -9382 -800 5454 2033 -9245 1907 -1211 -557 8012 -5152 68 -4589 229 7949 12319 7473 785 4477 -1395 2410 -2734 215 7531 -13440 11963 1082 2893 5066 -4481 -641 -8345 8389 -18990 4597 2075 5070 4010 -7578 -2033 -13446 4669 1813 -800 8077 6660 9437 -6061 12294 11513 -4328 -5145 7106 13003 894 -4993 -1473 5581 -7491 9574 -3296 -10626 8066 -14738 9308 -8243 8975 7074 -7099 -3237 1178 5497 -28516 1726 13644 14598 6877 -1646 9259 -1283 8905 219 2037 -18132 -1111 535 -6402 9190 -7150 5219 -2567 3924 7669 -10074 4030 1006 3071 2837 15430 6877 -11428 79 -11591 7623 -7032 4156 -10720 SO 20190924T042356.0Z 7206.183287 265 1 32.01 2 88.87 91.31 28.68 117.19 0.00 1 0.00 1 0 22 4.449e-02 4.329e-02 3.873e-02 3.838e-02 1.434918e+04 3.038139e+03 8.507896e+02 -6.000000e+00 2.617931e+03 288.13 -2.00 20.00 -2.00 505.39 0.00e+00 9.820739e-04 1.092286e-03 6.281634e-05 -6.000000e+00 1.285515e-03 288.13 -2.00 20.00 -2.00 500.42 0.00e+00 1.656982e+00 7.789721e-01 1.052649e-01 -6.000000e+00 8.946956e-01 228.43 -2.00 3.45 -2.00 502.03 0.00e+00 18.252 0.104 489.00 513.00 1 9.2300e+00 5.9928e-02 3.0958e-02 -6.0000e+00 6.8930e-02 5.6037e-02 1.4713e-02 2.8742e-03 -6.0000e+00 1.7579e-02 1.2524e-05 1.9799e-03 3.9532e-03 4.6305e-05 -6.0000e+00 5.1146e-03 3.3519e-02 -1.9253e-04 12 9 8 11 8 0 -1090.17 20.97 1.33 0.03352 0.04725 8 2 1 4 0 4000.000 26.21 20.00 20.97 -9090 -4420 3006 -2857 -4648 -4866 3629 -3679 -125 1780 -1538 -517 412 1400 -708 5080 -5970 4050 761 2779 -5134 -1157 5072 1394 1422 515 5838 -3053 3794 -3155 -993 3446 -1850 6168 -1449 2168 -2853 -1367 2099 -2911 4792 -3221 8442 990 517 -4393 1298 10375 -3754 -351 -3173 3825 31 3733 2835 -984 321 -3147 -349 -1648 5608 1355 348 -990 -2305 4559 -8005 4747 522 583 3967 -4109 6301 -5201 3128 3175 -7654 7176 1723 3286 -6171 480 2973 510 -4008 7589 8663 -3651 5690 -1523 6953 -3223 -5609 3449 -5654 1676 1898 13859 -5973 -227 4685 -1528 2045 -4796 3165 2071 -3360 -2647 2469 6973 -6466 8019 -11724 14541 -7974 -500 -107 -2030 2805 294 4108 -1116 3285 4473 -4577 849 1870 2587 -3451 7299 3360 -1225 -4055 -1266 6458 -6053 1642 -1336 -3354 -556 1531 3054 -1097 -504 -5678 793 -4035 -5186 3480 890 -9165 -4308 2796 -2909 -4958 -5188 3713 -3984 -130 1810 -1597 -525 409 1362 -701 4775 -6366 3994 792 2875 -5787 -1257 5193 1486 1521 556 5944 -3352 3808 -3316 -1008 3363 -1942 6149 -1594 2320 -3199 -1497 2200 -3111 4870 -3482 8416 1048 554 -4951 1374 9899 -4047 -357 -3236 3567 29 3499 2745 -1016 333 -3416 -370 -1767 5604 1417 369 -1059 -2477 4513 -8849 4556 516 571 3737 -4210 5870 -5352 3043 3062 -7903 6448 1578 3024 -6101 447 2723 484 -4021 6821 7706 -3663 5187 -1494 6306 -3260 -5812 3223 -5642 1505 1646 10384 -5357 -191 3790 -1354 1823 -4772 2993 2002 -3423 -2663 2357 6407 -6703 7435 -13004 12762 -8602 -504 -109 -2113 2770 294 3884 -1096 3070 4140 -4659 822 1794 2464 -3485 6587 3123 -1178 -3982 -1210 5775 -6248 1601 -1366 -3472 -567 1547 3060 -1151 -526 -6206 803 -4227 -5419 3314 873 SO 20190924T042803.0Z 7206.186146 269 1 32.01 2 88.06 91.95 27.98 118.50 0.00 1 0.00 1 0 15 2.580e-02 2.550e-02 2.286e-02 2.271e-02 1.214924e+04 1.749355e+03 7.759977e+02 -6.000000e+00 1.517888e+03 288.13 -2.00 20.00 -2.00 505.36 0.00e+00 2.593278e-03 6.471057e-04 1.591622e-04 -6.000000e+00 7.453876e-04 288.13 -2.00 20.00 -2.00 500.39 0.00e+00 1.642635e+00 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