File name: Pandora119s1_Athens-NOA_20190929_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T171915.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190929_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190929 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190929T042404.0Z 7211.183380 417 1 32.01 2 89.71 93.13 95.11 86.78 0.00 1 0.00 1 0 22 5.496e-02 5.400e-02 4.553e-02 4.502e-02 5.530668e+03 3.171752e+03 3.630913e+02 -6.000000e+00 3.227414e+03 287.56 -2.00 20.00 -2.00 505.33 0.00e+00 3.312157e-03 1.284286e-03 1.110484e-04 -6.000000e+00 1.585454e-03 287.56 -2.00 20.00 -2.00 500.34 0.00e+00 2.187765e+00 9.094486e-01 6.139630e-02 -6.000000e+00 1.102427e+00 227.94 -2.00 3.45 -2.00 501.94 0.00e+00 19.952 0.136 489.00 513.00 1 9.1030e+00 7.0319e-02 3.4563e-02 -6.0000e+00 8.4957e-02 9.0482e-02 1.7248e-02 2.2434e-03 -6.0000e+00 2.1599e-02 1.0561e-05 1.2196e-02 4.9554e-03 4.3041e-05 -6.0000e+00 6.3151e-03 -3.8030e-02 4.2934e-04 12 8 8 10 0 0 25.70 20.67 3.88 -0.03803 0.04657 8 2 1 4 0 4000.000 25.90 20.00 20.67 -9615 4943 -11865 15059 -5625 6300 -58 -4130 2012 -5405 10622 -9425 7522 2442 6619 4202 1208 4319 -3730 10508 -8053 4450 4501 -10108 2560 -1916 8627 -4334 5636 1785 -1884 3346 -2426 8157 -2526 1472 -3287 -2064 528 -4727 7876 -10365 5152 -2965 2831 1204 -2081 1400 166 1036 1729 72 -1103 3862 3732 -1414 6256 -8193 3380 5895 -2577 909 -1879 -3688 -2325 12322 4218 -2568 -4387 -1580 1300 -831 2402 -2326 6715 -3161 -1234 3660 -5712 2642 -5802 715 1954 4497 946 1161 -1023 -349 2422 -4838 3339 4535 5853 -5514 -6071 7448 -7463 8888 -6452 4034 3752 -1609 5488 -664 14630 -7424 13520 -634 -5593 -9586 2831 2350 -6448 -2413 -6298 3061 986 -2905 3727 466 4306 -1569 3521 3095 -3294 1064 -3127 7617 -4254 9565 572 921 12665 -5442 4246 -279 2976 -6083 1147 8473 -7069 9184 -6740 2821 -4457 1115 -459 -6002 345 -387 -9977 4544 -13318 13302 -6262 6340 -63 -4669 2122 -6060 9999 -10688 7116 2415 6292 4141 1251 4313 -4096 10078 -9326 4560 4627 -12083 2701 -2106 8440 -4730 5430 1756 -1922 3293 -2598 8053 -2809 1570 -3647 -2241 555 -5245 7759 -12390 5337 -3364 3042 1310 -2255 1477 174 1045 1695 71 -1081 3680 3654 -1489 6175 -9377 3447 5870 -2802 956 -2029 -4022 -2469 11128 4070 -2616 -4499 -1564 1251 -822 2323 -2367 6205 -3179 -1199 3350 -5713 2433 -5841 679 1847 4175 893 1094 -984 -333 2254 -4877 3136 4245 5402 -5635 -6113 6394 -7250 7172 -5983 3368 3193 -1487 4871 -639 12150 -7643 11199 -603 -5638 -10199 2701 2283 -6745 -2502 -6673 3043 978 -2974 3527 449 3952 -1522 3258 2890 -3290 1019 -3123 6823 -4275 8298 536 850 10348 -5355 3848 -270 2831 -6427 1140 7884 -7728 8574 -7390 2800 -4705 1094 -450 -6146 332 -380 SO 20190929T042818.0Z 7211.186320 421 1 32.01 2 88.88 93.78 94.32 87.42 0.00 1 0.00 1 0 15 2.437e-02 2.432e-02 2.800e-02 2.779e-02 6.007385e+03 1.973677e+03 5.114833e+02 -6.000000e+00 1.430819e+03 287.56 -2.00 20.00 -2.00 505.31 0.00e+00 1.131688e-03 7.885749e-04 6.634612e-05 -6.000000e+00 7.032060e-04 287.56 -2.00 20.00 -2.00 500.25 0.00e+00 2.499135e+00 5.655309e-01 2.244998e-02 -6.000000e+00 4.900068e-01 227.94 -2.00 3.45 -2.00 501.88 0.00e+00 18.273 0.104 489.00 513.00 1 8.8458e+00 4.3572e-02 2.9836e-02 -6.0000e+00 3.7744e-02 7.1817e-02 1.0887e-02 1.7803e-03 -6.0000e+00 9.6284e-03 1.7476e-05 2.6524e-03 3.0207e-03 6.2876e-05 -6.0000e+00 2.8015e-03 4.2495e-02 -2.5726e-04 12 9 8 11 8 0 65.53 20.67 2.79 0.04250 0.06089 8 2 1 4 0 4000.000 25.90 20.00 20.67 -1102 213 -960 714 -1728 1322 -1517 1010 2323 -1758 2555 -91 -1024 2668 1326 2710 2153 1896 2076 -63 1381 -329 -313 754 -3405 -2607 656 -380 897 -2908 -1450 3685 -6780 3091 -6142 -859 -711 2576 2081 1787 2193 -11 675 -4322 3 2134 3886 739 -2561 -1107 -2701 1246 219 644 3488 -1715 3747 -39 77 -1229 -454 417 1276 -667 -357 1645 -4780 -282 347 -3333 1702 -4279 2971 -817 270 2275 -1018 1167 1728 2225 -3610 -1809 -3032 -1868 3841 903 -1307 2394 -3798 -314 3473 2345 4072 3265 -888 1732 -3764 -610 4290 3534 -1851 -4854 -528 -4385 6081 -2660 -2649 1768 -2029 5262 -365 -456 -4656 813 2388 557 213 1278 1663 -469 -1008 -3726 -1900 4354 3119 -1936 -2520 2315 -1396 -1605 -1026 3847 -463 -1679 1350 2672 -1093 2026 1667 401 -4616 1691 -539 156 -1660 1472 96 -688 1017 2519 -1042 201 -944 713 -1818 1380 -1657 1085 2463 -1924 2643 -95 -1069 2658 1334 2705 2195 1980 2158 -67 1473 -358 -341 817 -3857 -2928 708 -409 933 -3066 -1487 3608 -7521 3194 -7113 -951 -782 2718 2185 1871 2289 -12 728 -4946 3 2306 4099 793 -2721 -1131 -2732 1216 210 620 3339 -1774 3737 -41 80 -1301 -478 436 1323 -703 -371 1654 -5046 -281 338 -3339 1614 -4320 2813 -811 266 2173 -989 1094 1595 2038 -3514 -1740 -2976 -1787 3583 852 -1263 2227 -3758 -301 3233 2229 3823 3073 -857 1592 -3561 -546 3581 2944 -1637 -4524 -487 -4339 5521 -2643 -2615 1657 -1971 4791 -356 -451 -4744 791 2301 550 212 1259 1619 -460 -981 -3688 -1843 3981 2899 -1898 -2487 2175 -1359 -1559 -981 3459 -430 -1578 1241 2466 -1069 1953 1636 403 -4812 1665 -545 157 -1693 1437 93 -664 957 2346 SO 20190929T043224.1Z 7211.189168 425 1 32.20 2 88.07 94.42 93.55 88.05 0.00 1 0.00 1 0 15 1.827e-02 1.826e-02 1.826e-02 1.815e-02 6.717935e+03 1.289486e+03 3.686962e+02 -6.000000e+00 1.072787e+03 287.56 -2.00 20.00 -2.00 505.31 0.00e+00 1.559272e-03 5.161238e-04 1.041290e-04 -6.000000e+00 5.272862e-04 287.56 -2.00 20.00 -2.00 500.32 0.00e+00 1.740480e+00 3.695003e-01 6.361425e-02 -6.000000e+00 3.674602e-01 227.93 -2.00 3.45 -2.00 501.94 0.00e+00 16.184 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