File name: Pandora119s1_Athens-NOA_20191106_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T174351.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20191106_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20191106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191106T050123.0Z 7249.209294 431 1 32.01 2 89.73 110.55 154.36 332.50 0.00 1 0.00 1 0 15 5.608e-02 5.452e-02 6.293e-02 6.221e-02 5.663213e+03 4.303736e+03 9.344763e+01 -6.000000e+00 3.236425e+03 283.16 -2.00 20.00 -2.00 505.31 0.00e+00 -1.065726e-03 1.748398e-03 5.469755e-05 -6.000000e+00 1.601044e-03 283.16 -2.00 20.00 -2.00 500.29 0.00e+00 2.022016e+00 1.269344e+00 9.035267e-02 -6.000000e+00 1.125132e+00 224.55 -2.00 3.45 -2.00 501.93 0.00e+00 20.110 0.139 489.00 513.00 1 9.5133e+00 9.7514e-02 3.5243e-02 -6.0000e+00 8.6566e-02 9.0093e-02 2.4559e-02 2.4102e-03 -6.0000e+00 2.2072e-02 7.3887e-06 -7.3254e-03 6.7285e-03 3.7620e-05 -6.0000e+00 6.4429e-03 -1.4710e-02 1.4931e-04 12 8 8 10 0 0 76.96 20.32 6.97 -0.01471 -0.06552 8 2 1 4 0 4000.000 25.68 20.01 20.32 5296 7481 755 -4924 -4525 11636 -3902 -76 1375 6971 -6583 1369 -2537 2400 -4260 -1225 6512 1406 3604 -5148 3125 -835 -5519 -3627 -1792 32 -5263 2195 3897 -3023 -2035 -6679 6793 -837 -1401 -5980 2062 -4665 6925 7086 4962 3160 -3500 4436 -1679 4651 7362 12879 3515 -6327 -4465 -1889 1108 1507 -1790 578 2680 2819 -6277 -3145 -4195 9650 156 1261 7027 -8767 -2003 -8496 8745 4688 -6119 10111 -8614 4752 1550 15019 -3657 506 7820 -1605 13137 -9962 2868 -4771 -3703 -1085 -5332 8539 -1328 -6509 -3400 6113 -6896 290 -1929 -3080 7881 -7067 2710 2306 3257 174 7601 -668 5478 8332 281 -2125 1672 -2385 3173 1037 8403 684 -1116 -4041 23 2529 1975 2526 627 2705 -10249 -3004 -244 -12762 9422 5899 2210 -2973 -3098 4007 -1302 7451 -2967 -11588 11460 -1603 -1863 -2826 334 2132 -3356 -10304 16697 6753 470 2733 -1145 2877 4764 6594 726 -5031 -4747 10657 -4262 -81 1454 6944 -7434 1410 -2681 2387 -4496 -1255 6246 1448 3718 -5904 3333 -931 -6462 -4178 -2032 36 -6162 2362 4051 -3288 -2148 -7161 6614 -879 -1519 -6898 2197 -5278 6905 6988 4979 3235 -3856 4555 -1847 4819 7399 12117 3571 -6932 -4676 -1881 1055 1430 -1785 577 2681 2855 -6995 -3397 -4577 9185 163 1307 6831 -9619 -2024 -9023 7913 4367 -6145 8849 -8926 4352 1476 12793 -3616 472 6709 -1504 10630 -10217 2609 -4732 -3673 -1059 -5452 7612 -1308 -6765 -3446 5682 -7356 288 -1934 -3060 6845 -6946 2362 1989 2779 156 6510 -645 5109 7457 272 -2088 1571 -2337 2967 1002 7621 675 -1128 -4229 23 2501 1956 2459 613 2558 -10956 -2988 -237 -14078 8334 5403 2096 -2961 -3067 3652 -1237 6447 -2858 -12042 9881 -1568 -1857 -2883 334 2107 -3526 -11649 14393 6380 465 2602 -1118 2693 SO 20191106T050538.0Z 7249.212245 435 1 32.01 2 88.95 111.21 154.70 334.65 0.00 1 0.00 1 0 22 5.345e-02 5.197e-02 4.199e-02 4.148e-02 1.062074e+04 3.084362e+03 8.672618e+02 -6.000000e+00 3.083427e+03 283.16 -2.00 20.00 -2.00 505.33 0.00e+00 2.652051e-04 1.159102e-03 3.295184e-05 -6.000000e+00 1.526119e-03 283.16 -2.00 20.00 -2.00 500.23 0.00e+00 1.591618e+00 8.377082e-01 2.988499e-02 -6.000000e+00 1.074627e+00 224.55 -2.00 3.45 -2.00 501.87 0.00e+00 18.543 0.109 489.00 513.00 1 9.3165e+00 6.4248e-02 3.0538e-02 -6.0000e+00 8.2639e-02 8.4227e-02 1.6005e-02 2.0510e-03 -6.0000e+00 2.1145e-02 1.1260e-05 1.3027e-02 4.3721e-03 8.7587e-05 -6.0000e+00 6.1403e-03 7.2671e-02 -5.9124e-04 12 8 8 10 0 0 -51.68 20.32 5.00 0.07267 0.16303 8 2 1 4 0 4000.000 25.68 20.02 20.32 5217 -3992 -4 5866 -4818 775 -7779 2531 611 9390 -517 -3356 -633 -4511 6034 -2998 1767 1109 -3853 4463 -1348 4306 -481 3232 -2309 1800 -2668 -4828 9093 -2440 4822 -8924 3542 2189 -846 5213 -2628 7121 -6987 6051 245 -4899 -2528 -1919 7510 -2701 799 -3026 6807 -1973 -3503 6198 -4270 6866 -3208 4428 -7568 -4767 -2762 -6561 4107 -1333 3684 -65 154 959 -2737 4688 -289 6111 2517 2728 2217 -4504 11133 -5089 3593 -4880 9536 -2918 8378 -4264 -1006 8762 -3382 13005 -4933 5312 -4121 -1882 -593 -176 6514 8130 926 -4688 3546 -5780 3523 9784 -12077 6521 2364 2234 5352 -6859 2657 -11973 5977 -5024 10554 -6926 4243 1867 -7037 8740 -6062 7144 -7087 1823 3440 -9131 6196 2398 9075 -7153 571 -7704 3282 6609 -7590 6944 -2274 -2609 5167 -1855 945 -775 50 184 -1167 -3251 282 -658 -499 7171 -5545 -1403 230 12535 4676 -4005 -4 5666 -5312 824 -8909 2697 661 9200 -551 -3636 -659 -4724 5841 -3127 1792 1158 -4305 4633 -1489 4506 -529 3439 -2601 1940 -2977 -5409 8652 -2553 4669 -10035 3606 2320 -939 5454 -2952 7184 -8046 6098 262 -5431 -2764 -2104 7717 -2989 845 -3271 6690 -2011 -3538 5742 -4287 6272 -3325 4351 -8505 -5236 -2975 -7340 4140 -1423 3736 -68 159 967 -2823 4430 -284 5582 2381 2591 2137 -4677 9864 -5238 3337 -4869 8178 -2832 7296 -4246 -955 7817 -3352 11259 -4983 4834 -4121 -1849 -579 -173 5947 7188 857 -4457 3016 -5271 2885 7516 -11744 5443 2142 2095 4950 -7180 2512 -13032 5445 -5155 9364 -7205 4068 1798 -7449 8161 -6447 6651 -7530 1745 3189 -9508 5529 2230 7922 -7358 544 -7955 3027 5852 -7653 5988 -2139 -2472 4590 -1803 910 -772 50 186 -1206 -3371 290 -682 -512 6717 -5666 -1358 218 10868 SO 20191106T050943.0Z 7249.215081 439 1 32.01 2 88.20 111.85 155.01 336.75 0.00 1 0.00 1 0 22 2.581e-02 2.572e-02 2.662e-02 2.642e-02 6.480135e+03 1.873646e+03 3.653600e+02 -6.000000e+00 1.489280e+03 283.16 -2.00 20.00 -2.00 505.34 0.00e+00 1.275341e-03 7.449792e-04 6.034764e-05 -6.000000e+00 7.365295e-04 283.16 -2.00 20.00 -2.00 500.29 0.00e+00 2.448516e+00 5.362565e-01 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