File name: Pandora119s1_Athens-NOA_20210319_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110617.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20210319_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20210319 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210319T052913.0Z 7748.228623 63 1 4.06 2 79.20 99.17 110.85 42.19 0.00 1 0.00 1 0 17 6.077e-01 2.379e-02 4.225e-01 1.585e-02 8.095419e-01 8.537109e-03 8.611301e-03 -6.000000e+00 3.442601e-01 226.72 -2.00 3.45 -2.00 321.39 0.00e+00 2.217386e-03 3.360891e-03 7.881649e-04 -6.000000e+00 1.462819e-02 278.94 -2.00 20.00 -2.00 321.05 0.00e+00 5.139 0.002 302.00 328.00 3 2.2353e+00 2.5697e-02 6.5531e-02 -6.0000e+00 8.6279e-01 3.4667e-01 3.6458e-02 4.1982e-02 -6.0000e+00 9.4502e-01 -4.9435e-01 4.1985e-02 2.3254e-02 -6.0000e+00 5.5032e-01 2.0926e-01 2.0702e-02 7.6909e-03 -6.0000e+00 2.2977e-01 1.4571e-04 -7.7701e-04 4.1731e-04 8.9394e-05 -6.0000e+00 1.6237e-02 1.5647e-02 -5.3161e-06 12 9 9 12 1 1 89.23 19.63 0.35 0.01565 0.00981 3 12 1 5 0 970.351 25.07 20.00 19.63 17.09 32.9 943.00 900000 -14827 23314 -111734 -239928 900000 -171193 900000 -19698 900000 -6803 -242623 142 -204310 900000 61390 -6087 162719 -70979 900000 -16568 900000 -62521 242099 -14883 69235 30676 -51820 900000 -89194 207650 -47824 96516 28509 -28653 167759 -6830 129564 1152 59328 102945 7377 31462 -4878 167967 -3719 29226 22052 35028 41158 -4284 60917 9241 38338 8051 20586 14853 -667 7036 -1624 22692 1131 13063 10847 6097 9321 -6876 7476 556 11066 712 5674 6786 2041 7782 -6313 5356 -7134 2897 -3506 -4417 1938 -116 -1668 -4157 4403 -2697 1637 2976 -5141 3434 -4269 304 -6107 -428 -470 -3100 1214 -1496 -1564 -614 496 -573 705 -2522 -4048 2635 -2542 467 399 -231 -1127 460 1252 -1176 1888 -956 723 -487 -390 428 354 3368 -1085 1746 706 -445 2158 671 1629 -670 631 1361 -886 -361 -895 1045 -446 1154 -1421 -286 294 -1329 900000 -229 360 -1724 -5956 900000 -2642 900000 -304 900000 -105 -9441 2 -9116 900000 947 -94 2511 -1923 900000 -291 900000 -1688 3736 -304 1068 473 -1563 900000 -3915 3204 -2099 1489 808 -1326 2589 -263 1999 58 2129 2734 526 1856 -414 2777 -318 1884 1596 2366 2823 -509 4387 1209 4115 1226 2893 2287 -119 1116 -270 3052 202 2393 2301 1474 2166 -1868 1834 162 3317 258 2087 2432 716 2372 -1963 1381 -2137 896 -1375 -2039 955 -65 -986 -2680 2770 -1875 1141 2036 -3663 2131 -2688 178 -3925 -298 -380 -2911 1245 -1712 -1801 -664 478 -510 629 -2457 -4153 2667 -2871 559 539 -343 -1788 729 1949 -1784 2715 -1430 1096 -778 -640 689 541 4864 -1585 2432 959 -601 2978 1054 2821 -1276 1272 2839 -1961 -841 -2159 2504 -1097 2760 -3348 -635 610 -2753 SS 20210319T053553.6Z 7748.233259 66 1 49.22 2 77.90 100.24 109.98 43.51 0.00 1 0.00 1 0 25 5.566e-01 6.899e-03 7.724e-02 1.672e-03 7.415705e-01 8.830894e-04 7.851701e-03 -6.000000e+00 3.103238e-01 226.72 -2.00 3.45 -2.00 321.45 0.00e+00 3.477450e-03 3.543214e-04 7.618255e-04 -6.000000e+00 1.252615e-02 278.94 -2.00 20.00 -2.00 321.12 0.00e+00 4.629 0.002 302.00 328.00 3 3.8524e-01 2.6897e-03 5.9537e-02 -6.0000e+00 7.7529e-01 9.3800e-02 3.9927e-03 3.8784e-02 -6.0000e+00 8.4729e-01 -1.3107e-01 4.9072e-03 2.1805e-02 -6.0000e+00 4.9868e-01 5.1631e-02 2.4010e-03 7.3108e-03 -6.0000e+00 2.0761e-01 1.6590e-03 -3.9900e-04 4.5034e-05 8.6361e-05 -6.0000e+00 1.4258e-02 1.6570e-02 -9.9699e-05 11 8 0 10 0 0 36.96 19.66 0.22 0.01657 0.01357 508 117 1 5 0 95.929 25.17 20.01 19.66 17.80 33.3 949.54 -209220 -158105 -183934 -178335 -161616 -214931 -178417 -171322 -157323 -142846 -171077 -123489 -135073 -95914 -83586 -64916 -63186 -56548 -41649 -52945 -23649 -37983 -24197 -37908 -34082 -31641 -40359 -31588 -46448 -15502 -32238 -9562 -10386 -7167 -7056 -17279 -7510 -7887 -80 -378 -748 -444 564 3367 1545 1928 2828 4478 3443 4622 6147 2908 6837 5186 3801 4351 3460 2422 910 1638 1948 3167 3304 4475 3744 2563 2728 202 2048 2039 1902 1596 593 1179 -27 -79 -1456 -701 -844 -176 -341 -761 -1503 -2147 -1189 -889 -340 27 457 688 225 685 -464 -631 -397 -457 2 456 258 -121 -360 -525 -776 -479 -1031 -1153 -1066 -454 -238 155 257 225 440 -14 192 37 74 -209 -294 -198 -428 153 454 497 737 378 269 649 518 93 280 -37 -121 -37 -193 -11 -220 350 77 -123 114 -307 -414 -1603 -902 -1529 -1425 -1001 -2172 -1338 -1369 -1257 -1095 -1841 -926 -1475 -954 -967 -783 -876 -830 -584 -889 -308 -570 -327 -649 -617 -598 -862 -608 -1022 -270 -815 -240 -315 -235 -224 -589 -252 -316 -3 -19 -44 -29 38 230 109 140 210 343 284 407 600 334 839 712 567 676 563 398 147 255 310 551 663 1022 929 635 669 53 584 678 704 620 230 426 -9 -23 -408 -199 -273 -69 -157 -373 -819 -1248 -730 -580 -232 19 316 457 139 396 -263 -373 -267 -361 2 482 299 -140 -391 -506 -677 -419 -979 -1156 -1125 -512 -296 218 406 377 739 -22 296 55 111 -329 -492 -340 -722 243 693 732 1043 516 356 911 837 171 526 -74 -255 -83 -467 -29 -566 906 198 -302 258 -653 -857 SS 20210319T054123.4Z 7748.237076 69 1 48.72 2 76.83 101.13 109.24 44.57 0.00 1 0.00 1 0 25 4.421e-01 6.105e-03 5.936e-02 1.367e-03 6.910446e-01 7.144455e-04 7.391530e-03 -6.000000e+00 2.465215e-01 226.72 -2.00 3.45 -2.00 321.25 0.00e+00 2.625559e-03 2.744027e-04 6.424730e-04 -6.000000e+00 9.950305e-03 278.95 -2.00 20.00 -2.00 320.92 0.00e+00 4.280 0.001 302.00 328.00 3 4.3012e-01 2.1365e-03 5.5127e-02 -6.0000e+00 6.1590e-01 6.1803e-02 3.0269e-03 3.5800e-02 -6.0000e+00 6.7307e-01 -8.3191e-02 3.6391e-03 1.9791e-02 -6.0000e+00 3.9614e-01 3.1474e-02 1.8113e-03 6.5284e-03 -6.0000e+00 1.6494e-01 2.3180e-03 -2.9006e-04 3.7186e-05 7.6182e-05 -6.0000e+00 1.1325e-02 1.5884e-02 -9.7830e-05 10 0 0 10 0 0 99.80 19.70 0.22 0.01588 0.01370 631 145 1 5 0 77.183 25.17 20.00 19.70 18.83 33.6 956.45 -143719 -163441 -124413 -162321 -123601 -176840 -154094 -138665 -127371 -105524 -129753 -112738 -97566 -61678 -55132 -39888 -32280 -48482 -24364 -41725 -12730 -43576 -25147 -8531 -20051 -13074 -32254 -19041 -27470 -18254 -7279 -9127 1206 -3160 -4913 -12908 -7749 -8049 -348 1572 -82 3778 346 3149 598 1317 3838 1470 3409 1365 4540 1790 4210 3130 3328 3475 2256 1933 -331 1953 2038 2824 3230 3041 2790 337 1801 -447 1180 1446 972 1241 428 676 -575 -406 -569 -1262 -382 -604 -134 -1365 -1826 -2175 -1464 -831 -292 276 554 853 504 662 35 -143 6 -408 196 586 478 -183 -146 -382 -590 -280 -939 -1105 -884 -502 -221 96 461 162 322 -44 118 58 66 -134 -253 -184 -517 35 492 192 712 390 321 570 492 69 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