File name: Pandora119s1_Athens-NOA_20210619_L2Fit_fwvt1c3d20201216p1-8.txt File generation date: 20250409T111450.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20210619_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20210619 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1789 Nominal wavelengths inside fitting window [nm]: 492.0172 492.1387 492.2601 492.3816 492.5030 492.6245 492.7459 492.8673 492.9887 493.1100 493.2314 493.3527 493.4740 493.5953 493.7166 493.8378 493.9591 494.0803 494.2015 494.3227 494.4439 494.5650 494.6862 494.8073 494.9284 495.0495 495.1706 495.2917 495.4127 495.5337 495.6547 495.7757 495.8967 496.0177 496.1386 496.2595 496.3804 496.5013 496.6222 496.7431 496.8639 496.9847 497.1055 497.2263 497.3471 497.4679 497.5886 497.7093 497.8300 497.9507 498.0714 498.1920 498.3127 498.4333 498.5539 498.6745 498.7951 498.9156 499.0362 499.1567 499.2772 499.3977 499.5181 499.6386 499.7590 499.8794 499.9998 500.1202 500.2406 500.3610 500.4813 500.6016 500.7219 500.8422 500.9625 501.0827 501.2029 501.3232 501.4434 501.5635 501.6837 501.8039 501.9240 502.0441 502.1642 502.2843 502.4043 502.5244 502.6444 502.7644 502.8844 503.0044 503.1244 503.2443 503.3642 503.4842 503.6040 503.7239 503.8438 503.9636 504.0835 504.2033 504.3231 504.4428 504.5626 504.6823 504.8021 504.9218 505.0415 505.1611 505.2808 505.4004 505.5200 505.6397 505.7592 505.8788 505.9984 506.1179 506.2374 506.3569 506.4764 506.5959 506.7153 506.8348 506.9542 507.0736 507.1930 507.3123 507.4317 507.5510 507.6704 507.7897 507.9089 508.0282 508.1474 508.2667 508.3859 508.5051 508.6243 508.7434 508.8626 508.9817 509.1008 509.2199 509.3390 509.4581 509.5771 509.6961 509.8151 509.9341 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210619T033333.4Z 7840.148303 100 1 48.70 2 85.43 63.67 135.40 320.37 0.00 1 0.00 1 0 22 4.450e-03 4.386e-03 1.691e-04 1.686e-04 1.632545e+04 1.275877e+01 1.055951e+03 -6.000000e+00 2.620612e+02 288.09 -2.00 20.00 -2.00 505.40 0.00e+00 5.047871e-03 4.839750e-06 2.904986e-04 -6.000000e+00 1.285754e-04 288.09 -2.00 20.00 -2.00 500.87 0.00e+00 8.386873e-01 3.357942e-03 1.096389e-01 -6.000000e+00 9.018501e-02 232.74 -2.00 3.45 -2.00 502.40 0.00e+00 10.444 0.019 489.00 513.00 1 2.8807e+00 2.5819e-04 1.8925e-02 -6.0000e+00 6.9417e-03 -5.6118e-02 6.3873e-05 2.6633e-03 -6.0000e+00 1.7771e-03 2.1548e-02 1.2242e-03 1.7506e-05 1.4812e-04 -6.0000e+00 5.1136e-04 1.4614e-02 -1.6308e-04 11 8 0 10 0 0 51.85 21.61 1.90 0.01461 0.02311 461 106 1 4 0 105.625 26.73 20.00 21.61 28.43 33.1 1005.00 -444 -421 -198 211 423 612 916 956 862 672 428 340 42 -182 -237 -171 -133 37 316 290 266 344 427 425 568 504 248 244 -56 -477 -488 -372 -493 -177 67 -68 -104 -45 -95 -182 -146 -66 25 103 203 261 158 -37 -137 -434 -780 -889 -974 -894 -556 -289 -183 -29 106 223 290 460 405 391 348 211 30 -86 -148 -436 -528 -398 -395 -271 -173 -310 -510 -478 -540 -682 -609 -484 -544 -517 -367 -346 -342 -278 -157 38 69 226 395 344 264 228 26 -275 -602 -1008 -1061 -1015 -749 -461 -393 -418 -392 -379 -372 -153 -29 48 239 533 757 811 947 827 548 331 385 310 393 589 484 403 502 436 430 626 413 94 215 169 60 174 177 -48 98 295 207 174 187 156 78 -101 -298 -579 -629 -558 -393 -375 -181 198 408 577 878 927 839 651 410 322 39 -177 -230 -165 -124 36 307 285 264 342 427 428 574 512 252 246 -55 -465 -467 -356 -480 -176 66 -68 -104 -45 -94 -178 -143 -66 25 104 209 271 164 -39 -139 -434 -764 -854 -928 -858 -544 -291 -188 -31 111 234 305 465 411 397 353 212 31 -88 -150 -437 -526 -397 -397 -275 -176 -315 -513 -473 -528 -665 -593 -473 -535 -514 -368 -349 -345 -280 -157 38 70 229 401 348 262 220 24 -251 -562 -934 -987 -922 -704 -452 -381 -413 -388 -374 -368 -152 -29 49 246 550 785 850 963 850 565 339 404 320 403 603 500 419 523 438 432 625 427 97 218 171 61 174 181 -50 103 314 224 189 197 165 82 -110 -319 -613 -661 -588 SQ 20210619T034517.3Z 7840.156450 103 1 26.84 2 83.34 65.38 136.80 323.88 0.00 1 0.00 1 0 29 3.353e-03 3.326e-03 1.366e-04 1.364e-04 1.258702e+04 1.001266e+01 8.209311e+02 -6.000000e+00 1.974533e+02 288.09 -2.00 20.00 -2.00 505.36 0.00e+00 3.422079e-03 3.897827e-06 2.006529e-04 -6.000000e+00 9.687665e-05 288.09 -2.00 20.00 -2.00 500.70 0.00e+00 6.608592e-01 2.725534e-03 8.544866e-02 -6.000000e+00 6.795044e-02 232.74 -2.00 3.45 -2.00 502.26 0.00e+00 7.836 0.008 489.00 513.00 1 2.2866e+00 2.0954e-04 1.4078e-02 -6.0000e+00 5.2303e-03 -4.2735e-02 5.2198e-05 2.0692e-03 -6.0000e+00 1.3390e-03 5.8735e-02 1.0683e-03 1.4424e-05 1.1101e-04 -6.0000e+00 3.8530e-04 1.6406e-02 -1.7321e-04 10 0 0 10 0 0 -1.88 21.62 1.37 0.01641 0.02382 633 146 1 4 0 42.187 26.73 20.01 21.62 28.89 33.0 1008.37 -133 -193 -68 192 331 468 670 689 640 475 333 241 104 -64 -105 -18 -15 26 223 160 128 321 316 333 459 363 124 174 -16 -350 -288 -138 -341 -83 53 -113 -174 -63 -42 -174 -116 -90 -54 -3 125 116 13 -104 -147 -369 -621 -698 -745 -688 -414 -295 -272 -140 -15 127 173 344 265 273 245 166 30 -39 -78 -310 -357 -245 -243 -178 -123 -274 -429 -359 -315 -479 -472 -366 -426 -440 -305 -271 -262 -169 -73 58 26 113 230 163 95 91 -16 -259 -468 -703 -722 -725 -610 -389 -409 -447 -286 -289 -234 -80 2 5 142 412 524 573 681 620 355 294 363 276 364 519 375 266 385 371 375 639 444 186 345 293 119 234 165 -25 90 195 185 124 135 53 -31 -122 -292 -430 -421 -349 -123 -180 -65 180 320 463 675 702 655 483 334 240 102 -63 -101 -18 -15 26 227 159 128 322 317 336 464 369 126 175 -15 -339 -286 -137 -330 -82 53 -117 -180 -64 -43 -176 -117 -91 -55 -3 127 118 13 -105 -153 -375 -619 -681 -721 -669 -410 -300 -273 -142 -15 129 176 352 272 281 251 168 30 -38 -79 -312 -357 -246 -246 -174 -121 -269 -417 -357 -310 -470 -463 -360 -423 -441 -296 -265 -256 -165 -71 56 25 111 228 162 92 90 -15 -242 -430 -640 -658 -675 -587 -373 -405 -449 -288 -289 -234 -80 2 5 147 413 529 582 698 640 367 301 365 274 373 533 372 266 385 371 375 636 439 182 348 294 116 231 166 -26 94 206 197 128 141 56 -32 -125 -308 -448 -434 -360 SQ 20210619T034544.3Z 7840.156763 103 2 26.80 2 83.26 65.45 136.85 324.02 0.00 1 0.00 1 0 29 3.336e-03 3.311e-03 1.347e-04 1.344e-04 1.248717e+04 9.831502e+00 8.170143e+02 -6.000000e+00 1.964348e+02 288.09 -2.00 20.00 -2.00 505.35 0.00e+00 3.376106e-03 3.834061e-06 1.980350e-04 -6.000000e+00 9.637676e-05 288.09 -2.00 20.00 -2.00 500.70 0.00e+00 6.481985e-01 2.682871e-03 8.460643e-02 -6.000000e+00 6.759809e-02 232.74 -2.00 3.45 -2.00 502.26 0.00e+00 7.759 0.008 489.00 513.00 1 2.2760e+00 2.0608e-04 1.3933e-02 -6.0000e+00 5.2032e-03 -4.2189e-02 5.1463e-05 2.0540e-03 -6.0000e+00 1.3320e-03 6.0116e-02 1.0347e-03 1.4221e-05 1.0884e-04 -6.0000e+00 3.8331e-04 1.4858e-02 -1.6134e-04 10 0 0 10 0 0 11.04 21.63 1.36 0.01486 0.02204 633 146 1 4 0 42.187 26.73 20.01 21.63 28.93 33.1 1008.68 -166 -185 -64 215 324 443 661 676 658 466 323 291 52 -89 -96 -26 -28 31 216 150 164 316 343 340 451 366 136 156 -28 -343 -275 -146 -326 -117 73 -129 -191 -70 -45 -134 -90 -49 -27 -6 123 106 25 -99 -157 -379 -633 -685 -692 -685 -450 -279 -250 -149 -23 122 159 322 299 264 243 138 54 -44 -83 -325 -341 -260 -292 -202 -133 -257 -416 -370 -338 -485 -436 -337 -430 -418 -318 -266 -245 -175 -48 51 17 124 246 179 99 101 -37 -243 -451 -699 -702 -712 -602 -374 -452 -449 -317 -265 -230 -80 -2 -11 171 392 532 610 692 632 363 301 333 246 366 491 375 260 400 343 390 633 438 208 357 272 106 235 174 -36 65 202 165 122 131 46 -41 -119 -264 -421 -425 -343 -155 -174 -59 203 316 443 672 667 650 458 328 292 51 -87 -93 -25 -28 31 212 150 166 318 347 346 461 375 140 158 -28 -335 -264 -139 -318 -117 75 -134 -199 -73 -46 -136 -92 -51 -27 -6 126 109 26 -101 -157 -389 -635 -674 -674 -672 -450 -275 -252 -153 -24 126 163 332 310 273 250 141 55 -43 -82 -317 -330 -252 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2.200e-03 7.295e-05 7.285e-05 2.366352e+03 4.588886e+00 1.656397e+02 -6.000000e+00 1.304538e+02 288.12 -2.00 20.00 -2.00 505.27 0.00e+00 5.286490e-04 2.060844e-06 3.593637e-05 -6.000000e+00 6.399542e-05 288.12 -2.00 20.00 -2.00 500.50 0.00e+00 -1.545795e-01 1.461313e-03 1.757651e-02 -6.000000e+00 4.485374e-02 232.73 -2.00 3.45 -2.00 502.09 0.00e+00 1.155 0.000 489.00 513.00 1 4.9768e-01 1.1232e-04 2.3550e-03 -6.0000e+00 3.4531e-03 -1.4278e-02 2.8623e-05 4.1040e-04 -6.0000e+00 8.8302e-04 1.0140e+00 8.2958e-04 8.1445e-06 2.2328e-05 -6.0000e+00 2.5455e-04 -1.5950e-02 9.1702e-05 10 0 0 10 0 0 19.66 23.77 1.53 -0.01595 -0.01020 1969 453 1 4 0 2.687 28.62 20.00 23.77 39.63 33.9 1080.66 243 134 55 117 77 139 300 292 302 206 199 236 92 41 110 205 149 81 147 -23 -8 206 223 220 297 164 -53 54 -22 -128 151 293 -47 -29 -71 -309 -268 -39 4 -49 10 -3 -87 -111 -83 -116 -181 -240 -223 -329 -405 -319 -301 -320 -250 -346 -451 -328 -183 -17 71 161 75 56 88 82 64 38 35 -136 -84 29 -95 -115 -100 -233 -295 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0.00 1 0.00 1 0 15 2.211e-03 2.203e-03 7.253e-05 7.244e-05 2.408938e+03 4.562291e+00 1.692159e+02 -6.000000e+00 1.302255e+02 288.12 -2.00 20.00 -2.00 505.27 0.00e+00 5.244466e-04 2.048767e-06 3.570492e-05 -6.000000e+00 6.388428e-05 288.12 -2.00 20.00 -2.00 500.52 0.00e+00 -1.552017e-01 1.452511e-03 1.774243e-02 -6.000000e+00 4.477666e-02 232.73 -2.00 3.45 -2.00 502.10 0.00e+00 1.164 0.000 489.00 513.00 1 4.8208e-01 1.1162e-04 2.3713e-03 -6.0000e+00 3.4472e-03 -1.4318e-02 2.8437e-05 4.1629e-04 -6.0000e+00 8.8153e-04 1.0287e+00 8.5885e-04 8.0658e-06 2.1991e-05 -6.0000e+00 2.5411e-04 -1.5417e-02 8.5931e-05 10 0 0 10 0 0 52.72 23.78 1.52 -0.01542 -0.00946 2014 463 1 4 0 2.621 28.62 20.00 23.78 39.83 33.8 1081.57 243 120 48 122 109 148 316 282 298 240 198 243 107 61 134 224 146 79 162 -12 -18 202 223 219 297 162 -38 66 -8 -129 127 290 -60 -33 -67 -314 -282 -49 -14 -49 13 -8 -99 -137 -103 -151 -210 -247 -237 -353 -420 -312 -285 -310 -246 -318 -427 -328 -184 -4 66 162 86 51 73 81 77 45 50 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7840.523640 369 2 5.51 2 30.85 251.11 81.65 100.46 0.00 1 0.00 1 0 15 2.221e-03 2.210e-03 7.365e-05 7.355e-05 2.410295e+03 4.631156e+00 1.685546e+02 -6.000000e+00 1.308076e+02 288.12 -2.00 20.00 -2.00 505.28 0.00e+00 5.186968e-04 2.080550e-06 3.547132e-05 -6.000000e+00 6.417014e-05 288.12 -2.00 20.00 -2.00 500.51 0.00e+00 -1.517943e-01 1.476735e-03 1.795713e-02 -6.000000e+00 4.497732e-02 232.73 -2.00 3.45 -2.00 502.10 0.00e+00 1.164 0.000 489.00 513.00 1 5.0853e-01 1.1367e-04 2.3797e-03 -6.0000e+00 3.4626e-03 -1.4780e-02 2.8924e-05 4.1969e-04 -6.0000e+00 8.8549e-04 1.0017e+00 8.7644e-04 8.2017e-06 2.1871e-05 -6.0000e+00 2.5524e-04 -1.5341e-02 8.4559e-05 10 0 0 10 0 0 61.82 23.78 1.52 -0.01534 -0.00926 2014 463 1 4 0 2.621 28.62 20.00 23.78 39.83 33.8 1081.57 254 136 64 123 88 157 312 269 291 229 195 244 118 63 121 205 154 70 163 -19 -7 210 222 227 290 150 -54 62 -25 -130 143 306 -63 -48 -81 -318 -278 -54 2 -56 25 1 -76 -120 -97 -136 -188 -237 -221 -352 -431 -325 -291 -323 -256 -335 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42 -130 -278 -296 -314 -202 -61 -57 SQ 20210619T123414.5Z 7840.523779 369 4 5.57 2 30.89 251.16 81.61 100.49 0.00 1 0.00 1 0 15 2.203e-03 2.185e-03 8.589e-05 8.574e-05 2.389839e+03 5.404347e+00 1.677147e+02 -6.000000e+00 1.297225e+02 288.12 -2.00 20.00 -2.00 505.27 0.00e+00 5.247863e-04 2.427763e-06 3.535805e-05 -6.000000e+00 6.364147e-05 288.12 -2.00 20.00 -2.00 500.48 0.00e+00 -1.471663e-01 1.725101e-03 1.768673e-02 -6.000000e+00 4.461632e-02 232.73 -2.00 3.45 -2.00 502.07 0.00e+00 1.165 0.000 489.00 513.00 1 7.7055e-01 1.3282e-04 2.3657e-03 -6.0000e+00 3.4346e-03 -1.4287e-02 3.3819e-05 4.1422e-04 -6.0000e+00 8.7869e-04 7.7041e-01 1.2830e-03 9.5666e-06 2.2502e-05 -6.0000e+00 2.5310e-04 -1.2885e-02 4.2978e-05 10 0 0 10 0 0 99.19 23.78 1.52 -0.01288 -0.00399 2014 463 1 4 0 2.621 28.62 20.00 23.78 39.83 33.8 1081.57 220 106 70 134 97 135 288 298 291 235 200 243 104 57 93 187 152 56 163 -22 26 205 214 219 299 174 -57 62 -17 -122 143 281 -35 -37 -70 -318 -268 -30 -11 -47 14 14 -84 -115 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426 279 317 125 -93 -32 120 85 46 58 -134 -223 -309 -307 -238 -65 -44 SQ 20210619T123420.6Z 7840.523849 369 5 5.52 2 30.91 251.19 81.59 100.50 0.00 1 0.00 1 0 15 2.132e-03 2.129e-03 1.092e-04 1.090e-04 2.378105e+03 6.914425e+00 1.665630e+02 -6.000000e+00 1.255900e+02 288.12 -2.00 20.00 -2.00 505.28 0.00e+00 5.037681e-04 3.085797e-06 3.461954e-05 -6.000000e+00 6.161438e-05 288.12 -2.00 20.00 -2.00 500.47 0.00e+00 -1.351253e-01 2.190010e-03 1.747388e-02 -6.000000e+00 4.320037e-02 232.73 -2.00 3.45 -2.00 502.07 0.00e+00 1.165 0.000 489.00 513.00 1 1.1454e+00 1.6796e-04 2.3476e-03 -6.0000e+00 3.3255e-03 -1.3693e-02 4.2968e-05 4.0874e-04 -6.0000e+00 8.5094e-04 5.2927e-01 8.0552e-04 1.2187e-05 2.1951e-05 -6.0000e+00 2.4501e-04 -1.2335e-02 2.6536e-05 10 0 0 10 0 0 97.96 23.78 1.52 -0.01233 -0.00675 2014 463 1 4 0 2.621 28.62 20.00 23.78 39.83 33.8 1081.57 159 59 65 136 109 134 281 293 301 264 197 237 103 66 108 170 158 53 162 -12 14 193 226 226 286 190 -42 92 -8 -129 71 221 -60 -84 -69 -288 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131 319 291 381 517 401 278 466 417 288 335 169 -30 -16 122 100 73 48 -119 -215 -287 -297 -235 -106 -89 SQ 20210619T123426.6Z 7840.523919 369 6 5.59 2 30.93 251.22 81.57 100.52 0.00 1 0.00 1 0 15 2.164e-03 2.139e-03 1.038e-04 1.035e-04 2.366040e+03 6.541913e+00 1.675040e+02 -6.000000e+00 1.274648e+02 288.12 -2.00 20.00 -2.00 505.27 0.00e+00 5.057891e-04 2.931372e-06 3.424646e-05 -6.000000e+00 6.253420e-05 288.12 -2.00 20.00 -2.00 500.47 0.00e+00 -1.377745e-01 2.082906e-03 1.723699e-02 -6.000000e+00 4.384671e-02 232.73 -2.00 3.45 -2.00 502.06 0.00e+00 1.165 0.000 489.00 513.00 1 1.0726e+00 1.6037e-04 2.3347e-03 -6.0000e+00 3.3752e-03 -1.3759e-02 4.0747e-05 4.0834e-04 -6.0000e+00 8.6370e-04 5.6927e-01 9.6686e-04 1.1613e-05 2.2183e-05 -6.0000e+00 2.4866e-04 -1.2284e-02 2.3040e-05 10 0 0 10 0 0 99.52 23.78 1.53 -0.01228 -0.00558 2014 463 1 4 0 2.621 28.62 20.00 23.78 39.83 33.8 1081.57 155 102 34 161 103 142 285 286 295 244 215 245 129 51 100 189 145 75 142 12 5 197 209 214 312 179 -15 56 1 -130 84 234 -89 -45 -78 -287 -261 -50 18 -40 19 -10 -83 -117 -74 -100 -143 -227 -212 -318 -426 -340 -339 -355 -269 -314 -408 -313 -175 -13 67 166 98 64 107 88 85 23 27 -144 -114 -11 -93 -125 -85 -209 -263 -118 5 -150 -152 -75 -247 -280 -232 -150 -130 -21 44 105 13 0 58 -117 -134 -87 -116 -212 -232 -259 -203 -282 -370 -334 -472 -487 -233 -98 -34 35 -41 -80 -6 114 179 213 303 259 113 195 325 231 306 328 164 128 327 344 405 557 392 304 490 441 300 335 188 -54 11 112 102 69 56 -94 -228 -277 -311 -226 -136 -76 147 97 33 161 107 142 291 296 305 251 219 245 128 53 102 193 142 75 145 13 5 206 220 226 329 189 -16 59 1 -129 82 228 -88 -46 -81 -304 -276 -52 18 -41 20 -11 -86 -123 -79 -106 -152 -238 -218 -320 -418 -326 -322 -338 -262 -313 -416 -323 -181 -13 70 172 102 67 110 89 85 23 27 -140 -110 -11 -91 -124 -84 -206 -257 -114 5 -143 -145 -72 -239 -274 -229 -150 -130 -21 45 106 13 0 58 -116 -132 -85 -116 -206 -221 -244 -191 -270 -364 -322 -465 -483 -228 -95 -33 34 -40 -79 -6 115 182 218 312 266 115 196 323 227 298 321 161 126 321 337 395 540 377 289 459 411 280 317 181 -53 11 112 103 70 57 -97 -234 -282 -310 -221 -131 -73 SQ 20210619T123432.7Z 7840.523990 369 7 5.63 2 30.94 251.24 81.55 100.54 0.00 1 0.00 1 0 15 2.214e-03 2.184e-03 1.191e-04 1.188e-04 2.354489e+03 7.478386e+00 1.654159e+02 -6.000000e+00 1.303910e+02 288.12 -2.00 20.00 -2.00 505.25 0.00e+00 5.030193e-04 3.358033e-06 3.397977e-05 -6.000000e+00 6.396970e-05 288.12 -2.00 20.00 -2.00 500.46 0.00e+00 -1.438217e-01 2.385501e-03 1.710674e-02 -6.000000e+00 4.485027e-02 232.73 -2.00 3.45 -2.00 502.05 0.00e+00 1.165 0.000 489.00 513.00 1 1.2776e+00 1.8340e-04 2.3264e-03 -6.0000e+00 3.4525e-03 -1.3630e-02 4.6781e-05 4.0297e-04 -6.0000e+00 8.8340e-04 4.6399e-01 1.2132e-03 1.3297e-05 2.2715e-05 -6.0000e+00 2.5439e-04 -1.2271e-02 2.9697e-05 10 0 0 10 0 0 99.82 23.78 1.52 -0.01227 -0.00386 2014 463 1 4 0 2.621 28.62 20.00 23.78 39.83 33.8 1081.55 190 81 55 143 109 140 303 274 304 252 178 240 98 38 56 159 120 82 166 -16 17 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123 218 218 333 268 137 207 348 233 290 327 133 151 348 355 423 546 385 265 488 421 268 309 116 -83 -8 117 91 81 64 -110 -230 -278 -304 -242 -96 -104 SQ 20210619T123438.7Z 7840.524059 369 8 5.55 2 30.96 251.27 81.53 100.55 0.00 1 0.00 1 0 15 2.277e-03 2.246e-03 9.738e-04 9.697e-04 2.479009e+03 6.293228e+01 1.818804e+02 -6.000000e+00 1.340992e+02 288.12 -2.00 20.00 -2.00 505.26 0.00e+00 4.272975e-04 2.737987e-05 3.060323e-05 -6.000000e+00 6.577552e-05 288.12 -2.00 20.00 -2.00 500.30 0.00e+00 -1.192416e-01 1.974444e-02 1.619467e-02 -6.000000e+00 4.608904e-02 232.73 -2.00 3.45 -2.00 501.92 0.00e+00 1.166 0.000 489.00 513.00 1 3.8605e+00 1.5181e-03 2.2630e-03 -6.0000e+00 3.5485e-03 -1.4047e-03 3.8758e-04 4.0082e-04 -6.0000e+00 9.0695e-04 3.5021e-02 6.6891e-04 1.0874e-04 2.1975e-05 -6.0000e+00 2.6167e-04 -1.7937e-02 1.3493e-04 10 0 0 10 0 0 80.99 23.78 1.25 -0.01794 -0.01330 2014 463 1 4 0 2.621 28.62 20.00 23.78 39.83 33.8 1081.55 363 152 132 167 37 165 209 132 273 300 192 239 208 76 185 274 229 17 114 -91 52 157 201 198 245 12 -93 -44 -50 -190 193 417 1 -122 -139 -348 -185 -70 -50 -18 110 69 -130 -136 -55 -275 -157 -319 -253 -386 -415 -292 -231 -338 -250 -289 -414 -363 -211 -67 64 40 67 9 105 22 88 -113 128 -149 -89 66 -71 -212 -132 -232 -140 -32 216 -144 37 -39 -195 -169 -134 -155 -283 38 80 204 126 63 14 -110 -174 -178 -78 -172 -167 -168 -160 -212 -457 -477 -629 -397 -300 -58 0 109 -72 -125 -29 -149 63 125 259 283 -39 170 326 224 398 310 87 142 369 248 423 380 397 256 644 497 434 395 161 -9 -16 116 58 -13 59 -160 -168 -216 -410 -146 9 73 343 145 129 168 39 174 225 143 297 324 205 251 216 78 188 278 236 17 122 -99 57 173 213 211 261 13 -99 -46 -51 -191 197 409 1 -126 -146 -371 -197 -73 -52 -18 114 72 -136 -144 -59 -294 -166 -336 -261 -389 -408 -280 -219 -323 -244 -290 -424 -376 -219 -69 67 42 70 9 108 22 88 -112 125 -145 -85 63 -69 -209 -131 -229 -136 -31 205 -137 35 -37 -189 -159 -128 -148 -273 37 77 197 123 62 14 -110 -172 -173 -75 -160 -152 -151 -145 -195 -432 -465 -625 -395 -296 -56 0 106 -70 -125 -29 -153 64 129 267 291 -40 171 324 220 389 304 86 140 362 243 413 369 382 243 601 461 391 361 150 -9 -16 113 57 -12 58 -158 -165 -211 -393 -137 8 68 SQ 20210619T123444.7Z 7840.524129 369 9 5.61 2 30.98 251.30 81.52 100.57 0.00 1 0.00 1 0 15 2.626e-03 2.594e-03 2.519e-03 2.508e-03 2.625210e+03 1.633061e+02 1.925590e+02 -6.000000e+00 1.546707e+02 288.12 -2.00 20.00 -2.00 505.26 0.00e+00 4.263951e-04 7.072058e-05 3.315136e-05 -6.000000e+00 7.586731e-05 288.12 -2.00 20.00 -2.00 500.31 0.00e+00 -8.094286e-02 5.101439e-02 1.724133e-02 -6.000000e+00 5.316331e-02 232.73 -2.00 3.45 -2.00 501.93 0.00e+00 1.166 0.000 489.00 513.00 1 4.8728e+00 3.9234e-03 2.3354e-03 -6.0000e+00 4.0931e-03 -4.9075e-03 1.0001e-03 4.2596e-04 -6.0000e+00 1.0462e-03 1.2686e-02 4.7614e-04 2.8000e-04 2.3765e-05 -6.0000e+00 3.0181e-04 -1.9769e-02 1.3985e-04 10 0 0 10 0 0 49.12 23.78 0.87 -0.01977 -0.01647 2014 463 1 4 0 2.621 28.62 20.00 23.78 39.83 33.8 1081.55 235 268 201 204 38 -20 88 86 404 411 332 385 340 46 349 552 290 88 109 -211 18 102 365 -24 319 -9 -233 -85 -185 -355 67 335 -50 -398 -237 -276 -335 -34 9 7 319 144 -90 -109 39 -119 -289 -134 -172 -448 -297 -349 -298 -590 206 -448 -301 -308 -339 -80 74 74 -77 83 122 -252 47 -286 352 -340 -138 -58 123 -323 -155 -81 -108 -86 303 -146 32 108 13 -165 -65 -306 -464 -169 -66 34 -26 130 -165 169 -29 -253 -214 -135 -167 -203 30 -374 -354 -560 -539 -254 -268 83 80 175 -77 -85 -51 -341 93 84 372 142 1 5 356 442 323 98 -36 366 510 215 326 375 529 226 709 475 487 365 6 119 17 143 72 143 5 -3 -152 -309 -429 -250 53 115 220 253 194 202 39 -21 94 93 435 439 350 400 349 47 351 555 296 91 117 -229 20 112 398 -26 350 -10 -255 -92 -196 -368 68 338 -51 -408 -249 -294 -356 -36 10 8 327 148 -94 -114 41 -127 -306 -140 -177 -452 -291 -335 -283 -564 200 -448 -307 -318 -352 -83 77 77 -80 86 126 -258 47 -284 343 -330 -133 -56 119 -319 -154 -80 -102 -80 286 -138 30 103 12 -156 -62 -294 -450 -163 -64 33 -26 129 -165 169 -29 -247 -205 -126 -153 -183 27 -344 -335 -547 -537 -253 -265 81 77 170 -77 -85 -52 -350 96 87 385 147 1 5 354 435 317 96 -35 361 487 206 310 355 496 210 646 431 442 336 6 114 17 140 71 142 5 -3 -151 -305 -416 -238 49 108 SQ 20210619T123450.7Z 7840.524198 369 10 5.57 2 31.00 251.32 81.50 100.58 0.00 1 0.00 1 0 15 3.517e-03 3.503e-03 4.595e-03 4.576e-03 2.773011e+03 2.979366e+02 2.146613e+02 -6.000000e+00 2.071682e+02 288.12 -2.00 20.00 -2.00 505.26 0.00e+00 4.543461e-04 1.295142e-04 3.613082e-05 -6.000000e+00 1.016184e-04 288.12 -2.00 20.00 -2.00 500.33 0.00e+00 -9.254831e-02 9.283912e-02 1.583758e-02 -6.000000e+00 7.120899e-02 232.73 -2.00 3.45 -2.00 501.95 0.00e+00 1.166 0.000 489.00 513.00 1 5.5078e+00 7.1387e-03 2.3040e-03 -6.0000e+00 5.4825e-03 -5.4282e-03 1.8191e-03 4.1855e-04 -6.0000e+00 1.4014e-03 6.7237e-03 4.9865e-04 5.1042e-04 2.7223e-05 -6.0000e+00 4.0424e-04 -2.1332e-02 1.4779e-04 10 0 0 10 0 0 27.24 23.78 0.62 -0.02133 -0.01787 2014 463 1 4 0 2.621 28.62 20.00 23.78 39.83 33.8 1081.55 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3.3229e-05 12 1 1 12 1 1 100.00 23.79 1.48 -0.01221 -0.00264 654 175 1 4 0 63.899 28.62 19.99 23.79 39.46 33.6 1077.06 113 3 -40 58 66 100 264 285 251 240 143 227 56 38 69 167 122 57 178 -23 -9 222 230 244 285 189 -60 88 -31 -101 90 263 -77 25 -62 -291 -214 -31 4 -37 15 30 -76 -46 -42 -62 -100 -208 -189 -316 -454 -342 -304 -338 -305 -334 -378 -267 -165 21 80 164 102 60 117 90 106 52 -8 -172 -61 37 -68 -123 -95 -205 -333 -130 0 -176 -102 -99 -265 -280 -237 -136 -141 19 60 166 8 36 43 -73 -121 -110 -106 -231 -231 -268 -172 -319 -384 -343 -460 -464 -274 -72 -39 62 -27 -65 16 76 203 215 326 242 87 190 304 205 309 356 132 131 300 340 366 545 371 287 507 434 244 317 80 -102 6 125 88 63 55 -96 -263 -333 -364 -285 -111 -72 107 3 -39 58 68 106 284 310 273 259 153 238 58 39 70 170 126 60 191 -24 -9 231 238 254 297 198 -63 90 -33 -105 92 267 -80 25 -64 -304 -223 -32 4 -38 15 30 -77 -48 -43 -65 -104 -214 -192 -312 -463 -341 -299 -335 -308 -327 -379 -270 -168 21 82 167 104 62 118 90 104 50 -8 -164 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390 398 613 418 288 477 397 211 269 133 -56 19 162 132 75 51 -74 -177 -242 -341 -354 -251 -185 SQ 20210619T162506.7Z 7840.684106 485 10 6.04 2 75.60 288.68 46.14 150.85 0.00 1 0.00 1 0 15 2.670e-03 2.657e-03 1.327e-04 1.325e-04 7.759734e+03 9.191666e+00 5.193185e+02 -6.000000e+00 1.572687e+02 288.14 -2.00 20.00 -2.00 505.31 0.00e+00 1.237937e-03 3.774654e-06 8.047414e-05 -6.000000e+00 7.715503e-05 288.14 -2.00 20.00 -2.00 500.62 0.00e+00 2.135808e-01 2.658245e-03 5.291804e-02 -6.000000e+00 5.409460e-02 232.73 -2.00 3.45 -2.00 502.19 0.00e+00 3.934 0.001 489.00 513.00 1 1.3407e+00 2.0433e-04 7.3724e-03 -6.0000e+00 4.1641e-03 -3.4285e-02 5.1408e-05 1.2842e-03 -6.0000e+00 1.0656e-03 2.8157e-01 1.0161e-03 1.4423e-05 5.9246e-05 -6.0000e+00 3.0683e-04 -2.2800e-03 -3.4386e-05 10 0 0 10 0 0 3.10 22.83 1.35 -0.00228 0.00477 545 125 1 4 0 10.464 27.78 19.99 22.83 33.94 33.5 1040.68 24 -28 -14 156 192 260 456 503 464 351 281 266 95 -2 20 106 85 76 226 86 60 265 260 276 359 283 19 112 -13 -224 -33 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