File name: Pandora119s1_Athens-NOA_20210630_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110745.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20210630_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20210630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210630T035811.8Z 7851.165415 212 1 49.24 2 81.60 67.11 48.87 193.45 0.00 1 0.00 1 0 25 3.591e-01 2.524e-02 3.540e-01 1.864e-02 7.652294e-01 1.055298e-02 8.051661e-03 -6.000000e+00 2.093261e-01 232.66 -2.00 3.45 -2.00 321.83 0.00e+00 -4.055831e-03 4.233843e-03 7.943608e-04 -6.000000e+00 9.215885e-03 289.09 -2.00 20.00 -2.00 321.44 0.00e+00 6.429 0.004 302.00 328.00 3 2.3578e+00 3.3324e-02 7.5338e-02 -6.0000e+00 5.3138e-01 6.7232e-01 4.2977e-02 4.0755e-02 -6.0000e+00 5.8050e-01 -1.0160e+00 4.2586e-02 2.1880e-02 -6.0000e+00 3.3706e-01 4.2530e-01 2.1537e-02 7.1294e-03 -6.0000e+00 1.3784e-01 4.1456e-05 -8.9474e-04 5.4857e-04 8.9259e-05 -6.0000e+00 9.7650e-03 5.9164e-03 -3.3814e-05 12 8 8 10 0 0 19.10 22.38 0.59 0.00592 -0.00081 31 7 1 5 0 1588.142 27.35 20.00 22.38 32.91 33.2 1028.37 -55197 -103409 900000 -45811 -21512 -82106 15079 900000 -142682 9800 -127859 900000 -114235 -58453 -4989 -43863 74722 -33748 72683 -36137 900000 10593 9848 900000 -45612 900000 -41440 900000 -55634 41054 107464 -10879 102073 -33265 900000 -19015 900000 28456 -23 13990 29026 14742 25712 96655 56272 25270 39616 40594 64831 -14640 39204 28868 66637 3194 19403 45124 9659 37500 16688 24163 20293 9674 23034 1186 37424 167 7493 -727 18843 11587 12355 20231 -1386 7541 -3565 18467 2135 -6156 4693 5615 12063 -1091 232 -6110 -1797 3252 -1571 598 -5438 1108 -3783 -314 -2388 -2868 -534 -7992 -1024 -4299 -590 -716 -751 -1193 -4270 -3732 -5429 22 -1514 2099 425 -763 -3 -1026 957 -658 1503 -251 -615 -360 -1089 1008 -1161 2828 276 1675 1058 1533 2932 856 3124 725 139 1945 -595 116 -1280 862 -539 1535 -823 603 -404 -1027 -2143 -1093 -3440 900000 -907 -390 -1761 274 900000 -7061 178 -5906 900000 -5465 -1929 -115 -1737 1356 -1392 1319 -1610 900000 280 260 900000 -2483 900000 -2256 900000 -2937 813 1950 -485 1852 -2305 900000 -1004 900000 1127 -2 946 1915 1192 1909 3508 2971 1792 2418 2478 3208 -1691 2910 2667 4617 453 2497 4690 1482 4330 2257 2870 2477 1404 3306 241 5680 36 1471 -159 3730 2867 3383 5373 -453 2115 -1011 3717 465 -1462 1115 1584 3781 -452 105 -3155 -949 1743 -930 357 -3445 634 -2122 -160 -1198 -1500 -309 -5854 -817 -3770 -553 -681 -672 -1049 -3494 -3035 -4872 20 -1346 2116 442 -918 -4 -1509 1404 -959 2044 -333 -829 -509 -1653 1560 -1811 4055 391 2269 1392 1941 3855 1108 4550 1240 264 3914 -1300 269 -3246 2253 -1456 4119 -2250 1548 -973 -2319 -4716 SS 20210630T041249.5Z 7851.175573 217 1 48.75 2 78.92 69.18 49.58 198.03 0.00 1 0.00 1 0 25 4.276e-01 9.919e-03 1.473e-01 4.846e-03 6.280043e-01 2.586009e-03 6.705723e-03 -6.000000e+00 2.439786e-01 232.66 -2.00 3.45 -2.00 321.32 0.00e+00 5.754304e-03 9.821239e-04 5.545525e-04 -6.000000e+00 9.629742e-03 289.09 -2.00 20.00 -2.00 320.96 0.00e+00 5.017 0.002 302.00 328.00 3 1.9138e+00 7.7925e-03 5.9591e-02 -6.0000e+00 6.1824e-01 1.1463e-01 1.0477e-02 3.3335e-02 -6.0000e+00 6.7214e-01 -2.1789e-01 1.1783e-02 1.7865e-02 -6.0000e+00 3.9380e-01 9.2770e-02 5.8810e-03 5.7429e-03 -6.0000e+00 1.6229e-01 2.8841e-04 -5.6083e-04 1.3955e-04 6.3384e-05 -6.0000e+00 1.0961e-02 4.1485e-03 -3.8987e-05 12 8 8 10 0 0 3.47 22.43 0.30 0.00415 -0.00007 104 24 1 5 0 468.656 27.45 20.01 22.43 33.77 33.4 1034.07 -133521 -175034 -110724 -105046 -186157 -172460 -169655 -84937 -130988 -59730 -158567 -80511 -67109 -84306 -42345 -35494 -38548 -50095 6140 -19368 -4400 -5266 -25431 -11199 -32800 -3500 -21825 -10048 -8909 -27803 -467 -1976 11590 -5120 -679 -9912 8617 435 5993 10171 -3670 10487 -1585 6043 734 8635 5682 6934 11089 987 13000 8729 9584 4648 8371 13023 5047 3200 -182 3004 543 2298 4738 2748 5474 1531 3389 2840 2478 1201 2629 2521 -873 767 602 -1670 -1700 -1602 -218 -1472 -989 -1589 -1776 -2809 -1342 -485 -265 898 707 198 -482 910 -24 -329 -792 -414 -253 -187 -297 -64 -368 -44 -1132 -117 -1334 -731 -846 -279 -451 -182 -13 77 375 0 462 -188 229 -232 -367 -223 -614 386 372 481 531 784 1008 1032 712 190 463 -4 250 355 -177 45 -364 386 -308 -216 -43 -150 -623 -1388 -3083 -1256 -1142 -3759 -3097 -3047 -723 -1981 -480 -3522 -875 -793 -1554 -660 -637 -820 -1326 102 -439 -89 -107 -637 -259 -1008 -84 -650 -261 -223 -880 -13 -69 416 -242 -30 -454 350 22 357 638 -301 806 -146 535 70 779 542 673 1077 112 1441 1136 1359 753 1388 2137 926 599 -34 538 102 465 1067 718 1493 425 894 765 729 416 1005 1017 -364 299 216 -548 -514 -481 -71 -582 -458 -849 -1049 -1775 -893 -344 -198 687 545 149 -340 588 -15 -207 -559 -338 -240 -204 -327 -71 -419 -45 -1061 -109 -1365 -789 -963 -338 -546 -247 -19 123 594 0 664 -259 316 -339 -573 -364 -1003 601 559 698 739 1146 1412 1504 1080 326 869 -8 522 788 -425 113 -938 1007 -807 -542 -101 -333 -1351 SS 20210630T041851.5Z 7851.179763 220 1 48.78 2 77.81 70.02 49.94 199.88 0.00 1 0.00 1 0 25 2.862e-01 5.632e-03 1.643e-01 3.616e-03 5.876561e-01 1.901293e-03 6.269687e-03 -6.000000e+00 1.633298e-01 232.66 -2.00 3.45 -2.00 321.11 0.00e+00 2.936538e-03 6.970884e-04 4.838382e-04 -6.000000e+00 6.446397e-03 289.09 -2.00 20.00 -2.00 320.77 0.00e+00 4.594 0.002 302.00 328.00 3 1.9566e+00 5.6313e-03 5.4844e-02 -6.0000e+00 4.1388e-01 1.7421e-02 7.5644e-03 3.1051e-02 -6.0000e+00 4.4995e-01 -6.6291e-02 8.6672e-03 1.6700e-02 -6.0000e+00 2.6362e-01 2.4844e-02 4.3671e-03 5.3639e-03 -6.0000e+00 1.0865e-01 4.3411e-04 -4.4176e-04 1.0442e-04 5.4235e-05 -6.0000e+00 7.3373e-03 3.9013e-03 -3.0250e-05 10 0 0 10 0 0 99.88 22.46 0.25 0.00390 0.00058 126 29 1 5 0 387.089 27.45 20.01 22.46 34.17 33.3 1036.45 -12576 -109074 -50436 -92687 -120872 -135486 -112800 -45738 -101013 -27009 -113367 -54947 -1006 -71101 -32675 -41194 -20837 -37204 -6513 -22550 -4766 -6062 -23187 22491 -25576 13610 -25252 -4110 -168 -14269 -9588 -11976 1524 125 -278 -6070 -8563 638 -3608 8875 289 1527 92 1965 2578 4500 -619 -1706 4527 801 7131 2341 1871 2348 404 3068 415 2777 346 1377 1662 2108 2542 2582 2192 270 2802 795 -1064 1553 241 902 -659 367 194 -843 -818 -1491 -415 -1476 -604 -1357 -1259 -1674 -1288 -689 -564 321 279 1543 258 908 546 105 273 -271 550 185 530 -358 -224 -148 -572 -49 -681 -1056 -1042 -365 102 -64 395 -85 469 283 -56 170 115 -7 -218 -124 -492 68 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