File name: Pandora119s1_Athens-NOA_20220121_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110611.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20220121_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20220121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220121T062036.9Z 8056.264316 295 1 49.20 2 83.29 121.77 73.04 272.72 0.00 1 0.00 1 0 25 5.402e-01 2.655e-02 4.323e-01 2.062e-02 9.452507e-01 1.178136e-02 9.814988e-03 -6.000000e+00 3.007447e-01 224.17 -2.00 3.45 -2.00 322.39 0.00e+00 7.827412e-03 5.217398e-03 1.316042e-03 -6.000000e+00 1.313685e-02 277.12 -2.00 20.00 -2.00 322.02 0.00e+00 7.811 0.008 302.00 328.00 3 8.5014e-01 3.9099e-02 9.0837e-02 -6.0000e+00 7.4858e-01 1.2727e+00 4.9457e-02 4.8243e-02 -6.0000e+00 8.1960e-01 -1.6975e+00 4.6287e-02 2.6584e-02 -6.0000e+00 4.8112e-01 6.8119e-01 2.4225e-02 9.3004e-03 -6.0000e+00 2.0152e-01 3.8848e-05 -1.7764e-03 5.7483e-04 1.3240e-04 -6.0000e+00 1.4208e-02 3.5226e-03 -5.4985e-05 12 8 8 10 0 0 6.23 19.25 0.54 0.00352 -0.00983 54 12 1 5 0 911.000 24.75 20.00 19.25 16.68 30.2 921.40 -42238 -44846 -20514 179292 -42484 209221 -121483 900000 -115322 -103334 900000 -106486 900000 -49193 900000 -58256 52642 78532 37364 59481 74312 214506 -63801 68386 -49368 17783 13729 -31913 35915 -50234 57507 -53997 83732 17579 -18032 84294 -65289 174611 -14944 94924 64251 17648 103473 10217 100844 3901 68269 -15822 43481 57901 28382 74387 29222 113248 19252 125031 61927 35392 28521 2868 107364 23026 39161 23226 20413 40066 12897 36371 7077 48636 5538 27342 10112 7276 17745 -10474 18937 -807 16950 -5292 2621 -905 775 17115 -4863 9814 -1230 936 4400 -1622 -1399 -2178 2126 -9737 -4234 -2056 -2964 -671 -3960 466 -3769 -1019 -6767 -3788 -2415 -5464 886 -3589 -1019 -1749 93 -3314 -577 2452 -988 -432 -2279 146 -369 1016 2387 -672 2048 1062 3445 2005 4463 1790 536 1041 354 346 -352 1173 -558 661 643 -867 204 -786 649 -432 -2382 -1312 -1638 -600 3603 -1164 4204 -5548 900000 -4845 -3775 900000 -3891 900000 -1618 900000 -3193 1058 1578 956 1195 1493 4310 -3497 1374 -2345 465 359 -1218 722 -2221 1156 -3354 1683 742 -922 1694 -4771 3509 -931 2289 2324 1064 2703 678 2634 267 2469 -1367 2184 2676 1939 3587 2408 4324 1973 4522 4231 3058 2464 300 3883 2082 3463 2800 2789 4509 1892 4385 1138 6548 1153 4745 2032 1382 2960 -1837 2511 -135 2725 -1189 656 -274 259 5159 -1928 3550 -519 397 1793 -675 -542 -800 734 -4020 -1926 -1104 -1922 -503 -3458 399 -3174 -739 -4562 -2408 -1623 -4023 647 -2983 -933 -1888 115 -4656 -819 3360 -1354 -571 -3106 205 -550 1542 3471 -948 2682 1370 4217 2425 5128 2260 812 1850 719 768 -844 2982 -1556 1915 1889 -2608 602 -2214 1653 -1018 -5457 SS 20220121T063153.0Z 8056.272141 298 1 48.83 2 81.43 123.66 75.22 274.33 0.00 1 0.00 1 0 25 5.472e-01 2.005e-02 3.448e-01 1.105e-02 8.305441e-01 6.083988e-03 8.750211e-03 -6.000000e+00 3.045182e-01 224.17 -2.00 3.45 -2.00 322.05 0.00e+00 8.432552e-03 2.654154e-03 1.052424e-03 -6.000000e+00 1.270434e-02 277.12 -2.00 20.00 -2.00 321.68 0.00e+00 6.327 0.004 302.00 328.00 3 1.6396e+00 1.9543e-02 7.5380e-02 -6.0000e+00 7.5899e-01 5.8826e-01 2.7521e-02 4.3059e-02 -6.0000e+00 8.3193e-01 -8.6699e-01 3.0452e-02 2.4031e-02 -6.0000e+00 4.8895e-01 3.6907e-01 1.4898e-02 8.2734e-03 -6.0000e+00 2.0384e-01 8.6754e-05 -1.6193e-03 3.1128e-04 1.1213e-04 -6.0000e+00 1.4005e-02 3.1436e-03 -1.1666e-04 12 8 8 10 0 0 99.94 19.23 0.33 0.00314 -0.00902 66 15 1 5 0 739.706 24.75 19.99 19.23 17.42 30.0 924.91 -160976 -192662 -5272 -186272 -54502 -202066 -131726 -142108 -154586 900000 -208610 -16967 -165417 197863 -127572 52488 122706 -23309 900000 -32156 -36502 -23389 -26393 28185 -41664 33510 -6942 1269 -57799 -36400 -12417 59841 19264 29860 77008 -51086 86817 9505 30573 30236 39654 27362 10748 37099 13842 26812 18464 39937 35915 10737 37580 7140 33893 19908 39710 23776 18393 17975 13265 33206 12531 18570 16575 18185 25060 15270 17227 11487 4433 6257 11899 9263 8939 8783 -2865 2967 3960 4254 1670 5954 -866 -1605 1541 -819 875 -2355 122 -70 -937 -2165 -2513 446 -4358 -1063 545 -2319 -1610 -3014 -910 -1881 -297 -105 -1837 -2001 -2846 -1979 -1347 -2178 -2218 -1941 -225 -471 -465 -1125 551 -454 -217 -476 -729 190 976 1342 1453 2212 2228 2408 986 1238 2149 446 1470 790 -46 245 -28 -132 -512 415 -58 -71 379 -726 -2415 -2838 -5661 -57 -5473 -587 -5343 -1677 -2088 -2725 900000 -6538 -183 -4536 2132 -4248 565 1322 -434 900000 -724 -858 -458 -517 364 -1020 433 -135 22 -1585 -941 -308 903 519 804 1244 -2502 1216 298 1021 1096 1476 1233 600 1635 773 1339 1031 1877 1864 768 2282 664 2656 1950 3383 2445 2035 1972 1455 2862 1338 2037 2143 2689 3804 2557 2801 2047 929 1495 2995 2504 2390 2193 -724 625 764 837 384 1604 -299 -651 620 -358 399 -1180 63 -37 -501 -1133 -1232 217 -2160 -533 283 -1476 -1205 -2682 -888 -1888 -276 -87 -1366 -1462 -2256 -1651 -1178 -2075 -2357 -2372 -308 -705 -712 -1703 784 -628 -302 -698 -1137 303 1516 1967 2035 2986 2908 3041 1223 1620 3248 796 2904 1699 -105 601 -75 -368 -1451 1177 -163 -192 939 -1679 -5440 SS 20220121T073128.1Z 8056.313519 334 1 48.94 2 72.31 134.59 86.62 282.78 0.00 1 0.00 1 0 17 3.424e-01 2.154e-02 2.867e-01 1.561e-02 4.679612e-01 7.861263e-03 5.367904e-03 -6.000000e+00 1.895065e-01 224.18 -2.00 3.45 -2.00 320.14 0.00e+00 4.170425e-03 2.232012e-03 2.426432e-04 -6.000000e+00 7.797506e-03 277.12 -2.00 20.00 -2.00 319.81 0.00e+00 3.246 0.001 302.00 328.00 3 5.2440e+00 2.1969e-02 3.9571e-02 -6.0000e+00 4.7082e-01 1.1877e-01 2.6019e-02 2.3445e-02 -6.0000e+00 5.1499e-01 -1.0342e-01 2.3568e-02 1.2163e-02 -6.0000e+00 3.0392e-01 4.4883e-02 1.2591e-02 3.7586e-03 -6.0000e+00 1.2825e-01 6.2088e-05 -1.5136e-03 4.5137e-04 4.2570e-05 -6.0000e+00 8.7646e-03 -9.0522e-04 -3.3581e-05 12 9 8 11 8 0 99.98 19.42 0.90 -0.00091 -0.01228 44 10 1 5 0 1112.064 24.96 20.00 19.42 18.93 30.4 935.08 100423 -124078 900000 -77713 5867 42894 -100163 53109 -87707 145850 -49224 88537 24848 26580 88988 -43927 184843 17588 82058 17642 18442 35485 -32251 98458 -24866 41376 -10635 11082 -14276 -14166 24470 -13396 41746 -2949 14382 3682 2308 3573 -12059 19366 -3851 14035 -778 538 -243 4893 12815 -4628 7649 -7963 8533 -3097 5064 7564 872 11657 -1908 7631 3355 -1149 2158 -1888 8763 -1993 8268 982 2939 -395 -5395 1620 -2106 4593 -2786 2109 103 -5328 -2379 -4528 8750 -8604 2939 -2797 -2351 -2542 -2461 958 -1060 1770 -1450 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