File name: Pandora119s1_Athens-NOA_20220515_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110729.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20220515_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20220515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220515T040815.9Z 8170.172406 217 1 48.15 2 81.00 73.06 107.50 264.94 0.00 1 0.00 1 0 33 5.277e-01 2.954e-02 4.441e-01 2.223e-02 8.022596e-01 1.266702e-02 8.479276e-03 -6.000000e+00 3.050548e-01 231.12 -2.00 3.45 -2.00 322.05 0.00e+00 1.281755e-02 5.382657e-03 9.238685e-04 -6.000000e+00 1.307195e-02 284.72 -2.00 20.00 -2.00 321.68 0.00e+00 6.052 0.004 302.00 328.00 3 2.8705e+00 4.0660e-02 7.3448e-02 -6.0000e+00 7.7178e-01 8.1725e-01 5.1195e-02 4.2049e-02 -6.0000e+00 8.4413e-01 -1.2472e+00 4.7593e-02 2.2072e-02 -6.0000e+00 4.9012e-01 5.3149e-01 2.4202e-02 7.1802e-03 -6.0000e+00 2.0163e-01 3.1291e-05 -2.1292e-03 6.4954e-04 9.9927e-05 -6.0000e+00 1.3606e-02 7.9615e-03 -1.4957e-04 12 8 8 10 0 0 96.77 20.50 0.67 0.00796 -0.00804 26 6 1 5 0 1851.553 25.79 20.01 20.50 23.71 33.0 987.40 -162967 900000 39682 90351 50619 900000 -126897 -110061 -120325 900000 -2238 -40324 -62584 -26544 -49234 -51128 106990 4323 137341 298805 47799 900000 900000 31701 48148 900000 94162 -49537 16091 90715 31893 -14 -5243 900000 69853 900000 61731 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-10 2806 403 -1268 -481 -453 611 96 2461 1875 502 -1722 -2647 -3573 -6504 -2161 -1697 620 -4965 -369 -3102 -860 -2500 -4985 -2801 -2777 340 -2678 -4161 -1065 -2018 1170 -3818 135 902 1922 1787 -2989 997 3074 2417 1859 2199 1178 3591 3732 1228 3177 2411 3409 353 6398 579 -1448 2011 -1087 -3086 -966 1075 -3020 -802 437 -4086 SS 20220515T041919.8Z 8170.180090 222 1 48.82 2 78.90 74.66 109.61 266.50 0.00 1 0.00 1 0 25 5.207e-01 9.807e-03 2.128e-01 5.249e-03 7.074400e-01 2.819059e-03 7.392018e-03 -6.000000e+00 2.953427e-01 231.12 -2.00 3.45 -2.00 321.56 0.00e+00 4.862667e-03 1.141547e-03 7.237458e-04 -6.000000e+00 1.172426e-02 284.72 -2.00 20.00 -2.00 321.21 0.00e+00 5.010 0.002 302.00 328.00 3 1.9363e+00 8.6493e-03 6.1925e-02 -6.0000e+00 7.4558e-01 1.2865e-01 1.2534e-02 3.7571e-02 -6.0000e+00 8.1170e-01 -2.4154e-01 1.4913e-02 2.0893e-02 -6.0000e+00 4.7614e-01 9.9662e-02 7.2785e-03 6.9630e-03 -6.0000e+00 1.9674e-01 2.5938e-04 -4.2870e-04 1.4801e-04 7.5578e-05 -6.0000e+00 1.3346e-02 6.3848e-03 -8.5177e-05 12 8 8 10 0 0 26.79 20.55 0.34 0.00638 0.00316 111 26 1 5 0 439.765 25.79 20.02 20.55 24.61 33.1 993.38 -6380 -243996 -152840 -156701 -204843 -161424 -162935 -133478 -179920 -118701 -159220 -165247 -118087 -84792 -62615 -31371 -21080 -30130 -4211 -21092 -56607 870 -48502 -15182 -46798 -27075 -44316 -62929 -27830 -55418 -17112 -8186 15163 -12173 -22888 2305 -16321 -5294 -779 10497 15492 8447 10609 4287 3227 7463 5882 1943 15343 8929 4779 10887 2009 12572 5039 10207 6298 2507 -1476 9 6989 940 6352 7583 7397 4130 1836 2540 737 5493 2984 3164 226 1153 -131 422 -3279 -1745 1017 1571 -482 -321 -1682 -1841 -1450 -148 -415 285 -39 278 -301 191 85 -1119 45 -1082 -552 398 -158 -111 -722 -706 -445 556 -1813 -1635 -426 -958 -345 -203 220 -228 28 -18 -111 127 -173 307 44 92 188 164 1075 482 828 664 384 625 675 29 -108 354 -58 149 -396 291 -347 290 156 -456 268 -348 -606 -33 -4542 -1408 -1524 -2936 -1405 -1501 -1025 -2487 -972 -2038 -2453 -1390 -955 -737 -337 -237 -416 -50 -313 -1246 11 -993 -241 -1102 -554 -1112 -1868 -570 -1589 -403 -218 380 -449 -914 68 -627 -214 -37 543 872 503 657 293 227 517 427 153 1114 740 460 1120 250 1539 710 1425 947 392 -233 1 1011 159 1168 1581 1669 949 424 599 195 1615 1005 1119 82 390 -41 117 -876 -464 295 546 -202 -155 -913 -1062 -890 -96 -284 201 -27 189 -192 113 49 -665 30 -851 -504 417 -168 -119 -795 -695 -394 489 -1768 -1685 -457 -1108 -437 -267 321 -357 45 -28 -160 175 -241 448 68 148 301 251 1564 682 1227 950 532 908 1027 51 -208 723 -125 342 -982 753 -921 777 416 -1171 639 -780 -1321 SS 20220515T042529.3Z 8170.184366 225 1 48.72 2 77.73 75.54 110.79 267.37 0.00 1 0.00 1 0 25 4.433e-01 7.857e-03 1.794e-01 3.648e-03 6.534889e-01 1.918726e-03 6.936198e-03 -6.000000e+00 2.514377e-01 231.12 -2.00 3.45 -2.00 321.32 0.00e+00 2.844187e-03 7.431960e-04 5.972617e-04 -6.000000e+00 9.981264e-03 284.72 -2.00 20.00 -2.00 320.98 0.00e+00 4.567 0.002 302.00 328.00 3 1.9451e+00 5.7791e-03 5.6668e-02 -6.0000e+00 6.3475e-01 4.6321e-02 8.0963e-03 3.4483e-02 -6.0000e+00 6.9104e-01 -1.1496e-01 9.5553e-03 1.8816e-02 -6.0000e+00 4.0536e-01 4.4329e-02 4.7464e-03 6.1306e-03 -6.0000e+00 1.6750e-01 4.1508e-04 -4.8394e-04 1.0331e-04 6.4176e-05 -6.0000e+00 1.1362e-02 5.9437e-03 -1.0219e-04 11 8 0 10 0 0 92.98 20.60 0.23 0.00594 0.00231 125 29 1 5 0 389.707 25.90 20.02 20.60 25.13 33.0 996.62 -154331 -98906 -122174 -149149 -185162 -166654 -180276 132350 -130820 -95899 -17735 -132353 -88406 -129252 8923 -56631 -17522 -35334 -36457 2440 -54954 6922 -26187 13725 -4799 -21079 -10462 -41505 -16702 -35226 4769 -13507 21660 5703 -11209 7610 -16067 3574 -4007 4413 -1973 3411 4648 -3597 5123 -6081 7037 -2102 5706 2473 721 5696 981 5734 2498 7275 4159 3163 6280 361 5108 -304 5611 3892 3606 3230 510 1646 -1477 1774 1672 1535 934 -125 284 -2891 322 -2373 1015 -715 107 -600 -1934 -1820 -2766 337 -453 569 706 871 962 -592 294 -497 28 -102 446 551 -352 389 -615 -16 -753 -149 -1205 -1608 -1098 -896 -71 -153 282 146 129 85 -80 385 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