File name: Pandora119s1_Athens-NOA_20220709_L2Fit_fwvt1c3d20201216p1-8.txt File generation date: 20250409T111128.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20220709_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20220709 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1640 1789 Nominal wavelengths inside fitting window [nm]: 492.0172 492.1387 492.2601 492.3816 492.5030 492.6245 492.7459 492.8673 492.9887 493.1100 493.2314 493.3527 493.4740 493.5953 493.7166 493.8378 493.9591 494.0803 494.2015 494.3227 494.4439 494.5650 494.6862 494.8073 494.9284 495.0495 495.1706 495.2917 495.4127 495.5337 495.6547 495.7757 495.8967 496.0177 496.1386 496.2595 496.3804 496.5013 496.6222 496.7431 496.8639 496.9847 497.1055 497.2263 497.3471 497.4679 497.5886 497.7093 497.8300 497.9507 498.0714 498.1920 498.3127 498.4333 498.5539 498.6745 498.7951 498.9156 499.0362 499.1567 499.2772 499.3977 499.5181 499.6386 499.7590 499.8794 499.9998 500.1202 500.2406 500.3610 500.4813 500.6016 500.7219 500.8422 500.9625 501.0827 501.2029 501.3232 501.4434 501.5635 501.6837 501.8039 501.9240 502.0441 502.1642 502.2843 502.4043 502.5244 502.6444 502.7644 502.8844 503.0044 503.1244 503.2443 503.3642 503.4842 503.6040 503.7239 503.8438 503.9636 504.0835 504.2033 504.3231 504.4428 504.5626 504.6823 504.8021 504.9218 505.0415 505.1611 505.2808 505.4004 505.5200 505.6397 505.7592 505.8788 505.9984 506.1179 506.2374 506.3569 506.4764 506.5959 506.7153 506.8348 506.9542 507.0736 507.1930 507.3123 507.4317 507.5510 507.6704 507.7897 507.9089 508.0282 508.1474 508.2667 508.3859 508.5051 508.6243 508.7434 508.8626 508.9817 509.1008 509.2199 509.3390 509.4581 509.5771 509.6961 509.8151 509.9341 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220709T041530.4Z 8225.177436 99 1 26.87 2 79.19 69.99 148.01 307.40 0.00 1 0.00 1 0 15 3.351e-03 3.329e-03 1.864e-04 1.861e-04 8.702783e+03 1.322255e+01 5.633481e+02 -6.000000e+00 1.986418e+02 289.90 -2.00 20.00 -2.00 505.35 0.00e+00 2.082147e-03 5.333184e-06 1.262474e-04 -6.000000e+00 9.729707e-05 289.90 -2.00 20.00 -2.00 500.75 0.00e+00 3.423954e-01 3.730757e-03 6.231800e-02 -6.000000e+00 6.805860e-02 232.60 -2.00 3.45 -2.00 502.30 0.00e+00 5.129 0.002 489.00 513.00 1 3.2484e+00 2.8671e-04 9.4239e-03 -6.0000e+00 5.2370e-03 -5.1092e-02 7.2123e-05 1.4712e-03 -6.0000e+00 1.3494e-03 3.4542e-02 2.2981e-04 2.0231e-05 7.1793e-05 -6.0000e+00 3.8641e-04 6.5329e-03 -1.9297e-04 10 0 0 10 0 0 98.64 21.29 1.61 0.00653 0.00813 569 131 1 4 0 47.191 26.41 20.00 21.29 28.03 33.4 995.55 900000 -293 -186 47 245 364 574 623 621 448 313 266 96 -67 -150 -70 -80 -15 214 216 167 254 310 356 436 397 176 224 52 -273 -294 -119 -270 -90 90 -70 -136 -32 -38 -148 -108 -37 -47 13 150 124 75 -64 -97 -328 -619 -686 -700 -705 -491 -350 -259 -127 -14 77 166 348 319 289 282 171 95 -6 -36 -300 -318 -233 -222 -162 -77 -231 -436 -403 -357 -478 -527 -395 -464 -477 -366 -306 -292 -220 -108 18 -15 70 217 133 38 38 -42 -213 -443 -681 -697 -684 -556 -311 -292 -427 -340 -285 -256 -142 -24 27 180 368 520 556 650 630 444 362 419 303 309 475 372 240 373 465 459 679 515 219 297 226 18 135 163 -22 54 227 184 87 134 40 -30 -154 -337 -482 -481 -435 900000 -272 -176 46 233 355 570 627 628 451 312 261 93 -65 -143 -67 -77 -15 214 220 172 263 322 370 433 396 176 232 53 -273 -289 -117 -267 -92 89 -70 -138 -33 -37 -147 -106 -37 -47 13 154 128 77 -65 -98 -325 -600 -684 -689 -697 -471 -344 -260 -130 -15 79 171 359 330 299 291 175 96 -6 -36 -293 -308 -226 -216 -160 -77 -229 -429 -391 -343 -457 -504 -380 -450 -467 -362 -305 -292 -220 -108 18 -15 71 222 136 39 38 -41 -201 -410 -624 -637 -636 -532 -309 -298 -423 -336 -280 -250 -139 -24 27 183 376 535 576 678 660 465 376 429 306 310 475 374 243 378 471 464 684 515 217 290 220 18 134 164 -23 57 240 189 90 139 42 -31 -159 -344 -506 -499 -450 SQ 20220709T041557.4Z 8225.177748 99 2 26.86 2 79.10 70.05 148.08 307.55 0.00 1 0.00 1 0 15 3.291e-03 3.261e-03 7.086e-04 7.068e-04 8.714881e+03 4.988604e+01 5.644419e+02 -6.000000e+00 1.950909e+02 289.90 -2.00 20.00 -2.00 505.34 0.00e+00 2.028155e-03 2.026424e-05 1.218866e-04 -6.000000e+00 9.552374e-05 289.90 -2.00 20.00 -2.00 500.78 0.00e+00 3.663144e-01 1.409718e-02 6.154270e-02 -6.000000e+00 6.662410e-02 232.60 -2.00 3.45 -2.00 502.31 0.00e+00 5.093 0.002 489.00 513.00 1 5.0440e+00 1.0865e-03 9.3149e-03 -6.0000e+00 5.1316e-03 -4.8071e-02 2.7064e-04 1.4625e-03 -6.0000e+00 1.3135e-03 5.7510e-03 2.6120e-04 7.7098e-05 7.0937e-05 -6.0000e+00 3.7801e-04 3.7235e-03 -1.3014e-04 10 0 0 10 0 0 99.75 21.30 1.49 0.00372 0.00554 569 131 1 4 0 47.191 26.41 20.00 21.30 28.07 33.4 995.55 -175 -414 -153 -1 250 308 588 572 530 434 221 390 1 18 -168 -24 13 -48 262 68 167 286 441 400 373 376 124 203 -51 -339 -363 -116 -241 -122 104 -184 -81 16 119 22 -19 11 -98 80 14 54 109 -63 -83 -350 -459 -641 -718 -694 -477 -362 -264 -18 -27 192 81 442 319 290 282 131 224 -21 65 -362 -336 -292 -130 -82 -89 -165 -546 -344 -368 -498 -449 -426 -387 -490 -329 -326 -276 -261 -52 178 -10 204 196 89 -1 -4 73 -189 -378 -742 -566 -642 -563 -228 -340 -430 -409 -140 -165 -104 32 -96 220 257 556 435 864 637 306 294 342 336 252 559 279 184 435 423 421 570 456 224 362 209 67 150 10 18 -31 263 161 107 219 -94 -29 -291 -321 -530 -491 -291 -160 -380 -143 -1 248 293 568 560 520 424 214 372 0 17 -156 -22 12 -46 256 67 167 288 444 404 379 383 126 205 -50 -329 -346 -110 -232 -120 105 -189 -84 17 121 22 -19 12 -100 83 15 57 115 -65 -85 -353 -451 -617 -685 -664 -465 -362 -270 -19 -28 200 85 462 336 305 295 136 229 -21 65 -359 -331 -288 -129 -82 -90 -166 -546 -338 -358 -482 -435 -415 -380 -487 -331 -330 -281 -265 -53 180 -10 210 191 87 -1 -4 72 -181 -354 -689 -524 -605 -548 -216 -330 -424 -403 -137 -160 -101 32 -97 222 261 569 448 894 664 319 304 347 337 251 556 279 186 437 426 423 571 453 221 352 202 65 148 10 18 -32 277 171 115 236 -102 -31 -312 -339 -552 -505 -298 SQ 20220709T045151.8Z 8225.202682 115 1 5.91 2 72.36 75.05 153.02 321.02 0.00 1 0.00 1 0 15 2.637e-03 2.620e-03 1.444e-04 1.443e-04 5.536805e+03 9.750215e+00 3.713709e+02 -6.000000e+00 1.562998e+02 289.91 -2.00 20.00 -2.00 505.29 0.00e+00 8.638636e-04 4.114692e-06 5.743295e-05 -6.000000e+00 7.656547e-05 289.91 -2.00 20.00 -2.00 500.61 0.00e+00 1.288153e-01 2.894303e-03 3.844150e-02 -6.000000e+00 5.357905e-02 232.60 -2.00 3.45 -2.00 502.17 0.00e+00 3.253 0.001 489.00 513.00 1 1.5990e+00 2.2225e-04 5.7829e-03 -6.0000e+00 4.1224e-03 -2.7257e-02 5.6607e-05 9.2962e-04 -6.0000e+00 1.0630e-03 2.4322e-01 1.0732e-03 1.5881e-05 4.0866e-05 -6.0000e+00 3.0407e-04 6.0673e-03 -2.2989e-04 10 0 0 10 0 0 99.99 21.31 1.41 0.00607 0.01351 598 138 1 4 0 9.692 26.41 20.00 21.31 28.26 33.5 996.60 900000 -98 -70 100 157 204 411 455 450 373 271 253 134 -23 -37 42 17 32 219 128 59 217 252 273 356 305 84 132 84 -211 -151 59 -155 -62 91 -117 -186 -82 -18 -98 -51 -51 -43 -52 24 26 -39 -139 -177 -293 -489 -525 -533 -535 -376 -289 -301 -247 -153 15 93 219 226 171 200 172 82 -35 -2 -197 -225 -117 -133 -93 -58 -183 -373 -298 -158 -303 -341 -239 -343 -398 -292 -201 -188 -118 -22 67 6 5 116 15 -44 -39 -35 -209 -313 -489 -472 -480 -469 -280 -325 -388 -313 -212 -189 -87 -12 -39 72 234 325 387 479 470 292 276 361 250 276 417 264 187 375 413 436 661 557 301 407 342 145 212 173 -18 10 141 127 69 78 -45 -173 -231 -295 -369 -300 -271 900000 -93 -67 100 153 205 420 472 468 387 278 255 134 -23 -36 42 17 32 226 134 59 221 257 278 364 313 86 134 88 -215 -150 59 -156 -64 92 -121 -192 -83 -19 -99 -51 -51 -44 -53 25 27 -41 -143 -179 -292 -496 -520 -521 -525 -375 -283 -302 -251 -156 16 95 225 233 176 204 174 82 -35 -2 -190 -215 -112 -129 -91 -57 -179 -363 -286 -149 -298 -337 -228 -329 -386 -286 -198 -187 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