File name: Pandora119s1_Athens-NOA_20221017_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110809.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20221017_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20221017 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221017T051721.0Z 8325.220382 274 1 47.29 2 82.80 107.71 19.18 239.33 0.00 1 0.00 1 0 60 6.135e-01 2.052e-01 6.702e-01 2.372e-01 6.068234e-01 1.382564e-01 6.956962e-03 -6.000000e+00 3.670433e-01 226.19 -2.00 3.45 -2.00 320.04 0.00e+00 -3.241400e-02 2.372787e-02 1.297519e-04 -6.000000e+00 1.973970e-02 285.52 -2.00 20.00 -2.00 319.64 0.00e+00 7.350 0.007 302.00 328.00 3 4.8460e+00 3.7463e-01 7.8131e-02 -6.0000e+00 9.2339e-01 7.6992e-01 4.2620e-01 3.0147e-02 -6.0000e+00 1.0153e+00 -1.3030e+00 2.4256e-01 1.4688e-02 -6.0000e+00 5.8457e-01 5.9148e-01 1.2807e-01 4.2918e-03 -6.0000e+00 2.4844e-01 1.8731e-06 1.1084e-03 7.4924e-03 6.0006e-05 -6.0000e+00 1.8826e-02 8.9153e-03 -5.3354e-04 12 9 8 11 8 0 99.93 20.13 3.07 0.00892 0.01724 12 3 1 5 0 3940.518 25.47 19.99 20.13 20.29 33.3 930.74 900000 -80763 80657 103362 900000 900000 900000 -116194 900000 900000 900000 900000 900000 900000 900000 -32749 18597 39103 145339 900000 -16537 151634 900000 -66156 900000 -35452 -46045 123533 -39733 900000 192643 900000 -85794 -3594 55883 119825 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900000 5795 900000 900000 13557 -2860 1409 900000 54731 900000 -15527 2579 -8080 -24822 5256 3188 28939 900000 7367 29313 14215 -18942 -8335 -649 900000 -45818 4209 10569 900000 -25236 -13245 -13565 20738 8783 5769 -7930 17530 12380 -23603 -5156 15071 22241 9785 23721 -2406 7244 -1859 -17305 -2432 -35243 -17276 -7847 -9029 17667 4061 11467 16452 28572 -19200 -4483 24238 12507 8582 43082 2865 15961 6791 31561 -46505 32277 7791 35806 1026 -474 -22672 -4771 13349 3236 13084 -31317 -23852 -7606 3027 5766 15957 -6475 13909 -25862 14695 -3200 10480 SS 20221017T053003.9Z 8325.229211 277 1 48.52 2 80.43 109.79 21.36 244.34 0.00 1 0.00 1 0 25 4.850e-01 1.631e-02 3.426e-01 1.049e-02 6.556828e-01 5.667508e-03 7.057382e-03 -6.000000e+00 2.714350e-01 226.19 -2.00 3.45 -2.00 321.62 0.00e+00 3.417233e-03 2.283647e-03 6.670962e-04 -6.000000e+00 1.153549e-02 285.52 -2.00 20.00 -2.00 321.26 0.00e+00 5.733 0.003 302.00 328.00 3 2.4835e+00 1.7456e-02 6.5680e-02 -6.0000e+00 6.7667e-01 1.9179e-01 2.4094e-02 3.4383e-02 -6.0000e+00 7.4045e-01 -3.2938e-01 2.7564e-02 1.8930e-02 -6.0000e+00 4.3506e-01 1.3949e-01 1.3713e-02 6.3158e-03 -6.0000e+00 1.8597e-01 8.3789e-05 -9.2194e-04 3.1169e-04 7.6780e-05 -6.0000e+00 1.2666e-02 8.3438e-03 -2.8143e-05 12 8 8 10 0 0 99.90 20.12 0.35 0.00834 0.00142 41 9 1 5 0 1183.199 25.47 20.00 20.12 20.69 33.1 933.23 900000 900000 -127208 900000 -213501 900000 -166194 -117550 81627 -140244 52543 -189477 10591 -78671 32040 65586 163526 -30483 -69574 88737 -76381 228913 21847 6918 50313 -69511 82350 -65646 2046 -13969 -8209 24842 -20730 19832 -38116 11403 -41745 22863 -4426 -11672 6318 3524 40975 -2435 32070 -12878 12605 12427 29793 33205 -3261 21636 -3554 10318 9639 13590 11989 4334 11605 2975 9558 -2332 10439 9965 5959 5392 -773 9775 5211 7679 6283 2325 6149 -6175 2164 -2673 8049 -654 -3497 184 -366 2560 -3748 1060 -5514 721 -1200 736 2831 -801 -444 -3843 1940 -1975 -1022 -1006 -2785 -750 -1502 278 -1078 521 -283 -479 770 -4601 -598 -1456 -581 -800 24 590 74 939 -944 1331 416 1195 577 -892 113 -870 462 473 804 1372 1028 2293 45 1405 149 925 512 -487 74 -596 -207 -532 160 -846 218 454 -460 900000 900000 -1626 900000 -5821 900000 -2690 -1302 835 -2390 537 -5812 108 -1274 328 671 1672 -597 -2193 907 -2798 2341 325 118 655 -2902 842 -2629 40 -333 -217 571 -883 625 -2078 359 -2383 799 -249 -855 441 273 2304 -218 2049 -1317 1020 1038 2183 2490 -389 2267 -527 1451 1454 2050 1900 742 1790 487 1490 -413 1856 2030 1359 1213 -180 2091 1275 2132 1976 801 2031 -2186 645 -746 2016 -179 -1009 61 -144 1129 -1949 557 -3305 435 -779 485 1832 -520 -268 -2239 1019 -1104 -635 -729 -2387 -727 -1618 296 -1094 467 -232 -394 680 -4548 -598 -1576 -684 -1065 35 918 117 1414 -1369 1804 574 1717 890 -1458 181 -1355 685 679 1108 1816 1315 3028 69 2416 285 1869 1090 -1115 180 -1544 -546 -1428 425 -2179 521 1017 -1008 SS 20221017T053833.1Z 8325.235105 282 1 25.71 2 78.87 111.20 22.86 247.24 0.00 1 0.00 1 0 17 3.871e-01 1.471e-02 2.689e-01 1.044e-02 5.840226e-01 5.438974e-03 6.329240e-03 -6.000000e+00 2.181561e-01 226.19 -2.00 3.45 -2.00 321.15 0.00e+00 4.666502e-03 2.011012e-03 4.868788e-04 -6.000000e+00 8.889207e-03 285.51 -2.00 20.00 -2.00 320.80 0.00e+00 4.996 0.002 302.00 328.00 3 2.9800e+00 1.6096e-02 5.7335e-02 -6.0000e+00 5.4542e-01 9.3307e-02 2.1158e-02 3.0035e-02 -6.0000e+00 5.9665e-01 -1.7240e-01 2.3239e-02 1.6212e-02 -6.0000e+00 3.4882e-01 7.4520e-02 1.1806e-02 5.2797e-03 -6.0000e+00 1.4565e-01 1.0851e-04 -5.4968e-04 3.0503e-04 5.8395e-05 -6.0000e+00 1.0081e-02 7.5037e-03 -5.4057e-05 12 9 9 12 1 1 99.99 20.14 0.52 0.00750 0.00337 28 13 1 5 0 880.791 25.47 20.00 20.14 21.33 33.3 937.24 -211989 900000 -81899 -100409 -140346 1064 900000 -168890 900000 -125847 -31488 -139781 -62555 -78595 -30963 39973 -72446 -19955 13441 -8112 -17799 -35959 25948 -64596 94071 -29047 8221 -55451 19264 -3856 -31213 89452 10438 29180 -19625 4235 1147 7826 23733 639 11424 -12983 27052 10355 10648 25304 6839 23359 -7050 13435 7189 9913 13782 6948 8242 8558 4214 -1328 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