File name: Pandora119s1_Athens-NOA_20231025_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20231026T062547.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20231025_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20231025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231025T054659.8Z 8698.240970 148 1 49.27 2 78.97 114.92 146.50 319.56 0.00 1 0.00 1 0 17 2.939e-01 9.756e-03 2.070e-01 6.405e-03 5.625476e-01 3.305092e-03 6.171093e-03 -6.000000e+00 1.633892e-01 225.53 -2.00 3.45 -2.00 321.03 0.00e+00 -8.395726e-04 1.190850e-03 4.569051e-04 -6.000000e+00 6.805898e-03 284.57 -2.00 20.00 -2.00 320.68 0.00e+00 5.039 0.002 302.00 328.00 3 2.7027e+00 9.7221e-03 5.7133e-02 -6.0000e+00 4.0782e-01 5.7320e-02 1.2699e-02 2.9070e-02 -6.0000e+00 4.4613e-01 -9.6086e-02 1.4107e-02 1.5636e-02 -6.0000e+00 2.6220e-01 3.8437e-02 7.2122e-03 5.0498e-03 -6.0000e+00 1.0946e-01 1.4364e-04 -8.4479e-04 1.8730e-04 5.9335e-05 -6.0000e+00 7.5247e-03 1.2201e-02 -7.5428e-05 12 8 8 10 0 0 74.47 20.84 0.27 0.01220 0.00585 38 9 1 5 0 1296.309 26.11 20.00 20.84 26.53 34.6 964.71 -42142 -147447 -50993 -125187 -74881 -84871 -113126 -67697 -108774 900000 -115841 -8594 -40581 -15186 -18624 1963 6367 -35015 38333 -41481 50809 -21315 -20986 10862 -4689 52463 -53560 18874 -31318 7934 14254 -2936 22505 -7311 5930 -14140 790 -847 7316 2374 -1605 8570 -11295 4216 7884 9353 3609 6899 8077 -276 8080 -1860 9101 5808 1357 5143 973 5739 -3359 2960 843 3221 1716 3453 1973 13 2157 -3906 2234 941 1256 1486 -493 387 -1831 1098 -651 -1891 -1400 -3456 1090 -3167 -687 -2430 -758 -1179 -1273 710 -380 949 -101 1839 659 1284 1595 483 663 162 211 -496 -390 -464 -883 1259 -1256 -938 -2645 340 -996 52 351 186 875 -801 692 -692 665 187 -125 240 -938 6 214 1030 31 742 711 799 1008 -802 567 54 -101 -79 -186 47 -154 202 -279 40 85 -67 -389 -263 -2762 -425 -2052 -717 -848 -1601 -705 -1993 900000 -2653 -72 -558 -202 -318 33 114 -1035 590 -1409 762 -657 -664 276 -154 1048 -2989 526 -1369 238 457 -132 909 -411 301 -789 44 -53 523 218 -175 913 -1543 505 914 1084 448 843 1006 -39 1161 -331 1591 1143 298 1136 233 1319 -822 663 196 797 487 1084 665 4 676 -1317 773 383 535 665 -225 177 -789 411 -228 -661 -533 -1585 558 -1817 -422 -1609 -529 -885 -1011 571 -310 737 -74 1301 447 875 1130 398 626 176 249 -590 -434 -465 -816 1156 -1286 -1015 -3063 407 -1313 75 560 311 1448 -1290 1028 -992 946 281 -201 403 -1588 10 335 1545 46 1029 946 1104 1561 -1414 1071 108 -212 -165 -418 111 -371 493 -684 94 188 -149 -846 SS 20231025T055326.3Z 8698.245443 151 1 48.81 2 77.83 116.03 147.24 321.97 0.00 1 0.00 1 0 25 2.231e-01 7.291e-03 2.050e-01 6.266e-03 5.141857e-01 3.191177e-03 5.705613e-03 -6.000000e+00 1.239194e-01 225.53 -2.00 3.45 -2.00 320.76 0.00e+00 2.170934e-03 1.081732e-03 3.642705e-04 -6.000000e+00 5.022626e-03 284.57 -2.00 20.00 -2.00 320.42 0.00e+00 4.601 0.002 302.00 328.00 3 3.1133e+00 9.2389e-03 5.2108e-02 -6.0000e+00 3.0877e-01 2.4056e-02 1.1638e-02 2.6328e-02 -6.0000e+00 3.3765e-01 -4.0501e-02 1.2380e-02 1.3907e-02 -6.0000e+00 1.9890e-01 1.6246e-02 6.4260e-03 4.4059e-03 -6.0000e+00 8.3080e-02 1.4963e-04 -3.1901e-04 1.8252e-04 4.9830e-05 -6.0000e+00 5.7126e-03 1.1548e-02 -9.0603e-05 11 8 0 10 0 0 88.80 20.86 0.23 0.01155 0.00915 37 9 1 5 0 1318.891 26.11 20.01 20.86 26.99 34.6 967.58 -86195 -56375 -32150 -99666 -82100 144594 -20585 12355 -4724 -61626 -14233 -66431 -52964 -30637 -6180 26149 -18692 -4648 -36450 -35865 17721 -5912 -25489 3833 -3721 -4598 4022 -9360 5831 -5666 17246 -2824 1128 -2391 -5999 -11124 -1177 2090 -5858 1494 1191 -4631 -916 2896 167 1886 5829 5530 -1928 836 -1138 7430 928 1360 1594 -214 1006 -2707 2078 1271 3533 3314 1678 298 1013 2271 -772 -802 1417 4227 248 634 236 -963 217 -408 2102 -479 739 -1946 -1727 -529 -1794 -1070 -1256 -1390 255 728 702 128 105 1090 618 1440 1145 -775 63 989 548 -848 -254 -502 -193 -90 -1050 -1497 -758 -1008 -130 143 249 -50 444 -59 -37 202 470 44 -588 -698 -463 26 328 -202 458 1273 1342 916 -151 735 48 128 20 363 -225 109 -244 185 -182 -344 365 -475 -296 -1053 -630 -309 -1827 -1175 884 -163 80 -42 -1022 -156 -1264 -1063 -620 -122 447 -546 -129 -1463 -1516 469 -198 -1060 129 -147 -194 160 -415 213 -238 656 -154 67 -160 -400 -750 -78 157 -586 164 148 -657 -132 413 25 280 844 816 -315 138 -210 1404 204 322 399 -57 271 -760 542 329 917 941 532 107 380 809 -278 -291 546 1789 121 325 121 -477 98 -171 786 -181 301 -957 -959 -330 -1236 -772 -972 -1156 221 648 626 111 85 805 432 1003 882 -697 64 1109 670 -1048 -292 -535 -189 -90 -1150 -1744 -899 -1273 -177 214 396 -83 726 -95 -55 286 669 66 -948 -1186 -784 42 516 -309 667 1762 1826 1265 -236 1263 87 245 40 760 -495 251 -576 443 -436 -798 813 -1012 -616 SS 20231025T055912.8Z 8698.249453 154 1 31.72 2 76.81 117.03 147.86 324.21 0.00 1 0.00 1 0 25 1.495e-01 6.725e-03 1.041e-01 4.275e-03 4.830856e-01 2.150655e-03 5.408509e-03 -6.000000e+00 8.303008e-02 225.53 -2.00 3.45 -2.00 320.37 0.00e+00 9.662088e-04 6.617949e-04 2.929121e-04 -6.000000e+00 3.365275e-03 284.57 -2.00 20.00 -2.00 320.04 0.00e+00 4.271 0.001 302.00 328.00 3 2.7830e+00 6.0931e-03 4.8449e-02 -6.0000e+00 2.0689e-01 2.4230e-02 7.4088e-03 2.4520e-02 -6.0000e+00 2.2624e-01 -3.1900e-02 7.3496e-03 1.2782e-02 -6.0000e+00 1.3327e-01 8.8421e-03 3.8837e-03 3.9805e-03 -6.0000e+00 5.5669e-02 2.9370e-04 -3.4468e-04 1.2321e-04 4.3478e-05 -6.0000e+00 3.8274e-03 1.1177e-02 -8.9079e-05 12 9 1 12 1 1 88.67 20.90 0.17 0.01118 0.00859 32 12 1 5 0 960.927 26.11 20.01 20.90 27.49 34.6 970.47 27554 -61009 -62740 -3679 -61236 -15350 -83347 -28580 -49148 -38974 -39140 -24648 -504 -35653 2649 -34661 -15260 -5182 -13356 -13106 4897 15869 -12587 6927 -11453 -1733 -6270 -5160 -3334 4042 6417 -7992 3443 506 3444 -555 -1907 2209 -2656 -43 -4917 -1774 1114 1440 4735 971 2114 -1104 -802 -782 4481 2427 3186 2415 -884 2002 -119 3351 696 2056 3237 854 3888 798 847 -79 1405 -677 583 714 -763 1001 -799 646 -235 -44 -517 -2096 926 -1895 37 -1181 -1137 -1646 -843 -1025 -1555 -367 409 787 194 1268 919 489 794 -47 877 335 324 -184 -732 86 -164 376 -859 -1246 -754 -612 390 -93 304 -214 262 185 175 114 419 414 -766 -346 -562 -150 578 395 951 -606 406 1135 470 241 -146 143 -196 426 45 -412 -206 307 -60 -148 169 -334 -259 176 -1055 -1200 -40 -1036 -159 -1748 -408 -964 -760 -787 -464 -9 -1071 67 -1457 -587 -195 -589 -609 198 590 -618 304 -658 -96 -374 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