File name: Pandora119s1_Athens-NOA_20240420_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20240420T222810.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20240420_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20240420 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240420T053038.1Z 8876.229608 219 1 48.78 2 69.72 90.83 125.22 314.96 0.00 1 0.00 1 0 17 2.168e-01 1.044e-02 1.513e-01 5.746e-03 5.310656e-01 2.990114e-03 5.797487e-03 -6.000000e+00 1.225423e-01 229.29 -2.00 3.45 -2.00 320.44 0.00e+00 1.234070e-03 9.280836e-04 3.328742e-04 -6.000000e+00 5.401808e-03 282.23 -2.00 20.00 -2.00 320.11 0.00e+00 2.855 0.000 302.00 328.00 3 3.7784e+00 8.4902e-03 3.9295e-02 -6.0000e+00 3.0781e-01 2.1462e-02 1.0443e-02 2.6929e-02 -6.0000e+00 3.3593e-01 1.3048e-02 1.0640e-02 1.4091e-02 -6.0000e+00 1.9694e-01 -8.9643e-03 5.5820e-03 4.3658e-03 -6.0000e+00 8.1914e-02 3.5659e-04 1.1791e-03 1.6444e-04 4.5866e-05 -6.0000e+00 5.6887e-03 2.6370e-02 1.5577e-04 12 8 8 10 0 0 99.99 19.92 0.32 0.02637 0.03523 259 60 1 5 0 188.295 25.39 20.00 19.92 14.86 34.0 915.58 -80676 41173 -85760 900000 -110529 900000 -71240 10276 -2252 -72053 900000 -83494 900000 -45031 43340 -10403 8699 48471 -31016 33546 -32738 22493 -4939 -10717 2808 -21108 19591 -26026 46333 -14660 23984 17162 572 17451 -15089 20688 -7964 14491 -1411 -2548 5906 -4217 7825 -5877 9119 -5735 3041 119 -4048 7703 -5346 9193 -2564 7046 35 -454 1393 -1293 4374 -2011 6737 638 2587 1901 912 2131 -3688 4019 -552 2046 -1507 294 393 -889 1745 -2059 1519 -446 735 331 -1455 -192 -3641 -65 -1816 204 -213 -974 855 -622 1679 85 1824 104 512 900 -615 1520 -962 948 -931 -491 372 -804 -560 -1607 10 -870 122 -427 1 319 -333 746 -488 779 397 217 51 -918 67 -1149 870 75 1202 633 201 1485 108 786 -647 684 -433 92 205 -694 460 -298 284 -633 474 55 -622 -1089 231 -1576 900000 -2333 900000 -1071 83 -23 -1552 900000 -2186 900000 -1229 656 -297 235 986 -1402 886 -1659 688 -201 -492 126 -1248 809 -1596 1390 -797 1044 916 41 1158 -1290 1229 -673 1163 -160 -353 847 -700 1208 -1064 1432 -1064 522 21 -778 1379 -1198 1983 -677 1826 10 -136 422 -401 1273 -613 1936 209 935 769 387 851 -1500 1530 -242 1010 -830 169 224 -485 850 -928 623 -185 333 173 -894 -132 -2736 -49 -1508 177 -195 -925 793 -560 1396 66 1320 78 423 829 -656 1796 -1249 1188 -1101 -529 368 -831 -626 -1866 12 -1116 167 -653 2 542 -557 1169 -720 1083 560 322 80 -1526 109 -1827 1309 109 1688 854 261 2000 164 1290 -1157 1257 -835 186 443 -1545 1031 -684 641 -1406 983 108 -1212 SS 20240420T053525.1Z 8876.232929 222 1 0.53 2 68.77 91.57 125.87 316.12 0.00 1 0.00 1 0 25 9.598e-02 7.600e-03 6.727e-02 5.144e-03 5.029783e-01 2.565095e-03 5.727316e-03 -6.000000e+00 5.391441e-02 229.29 -2.00 3.45 -2.00 319.06 0.00e+00 1.566101e-03 5.619155e-04 1.991800e-04 -6.000000e+00 2.158886e-03 282.23 -2.00 20.00 -2.00 318.75 0.00e+00 2.736 0.000 302.00 328.00 3 1.1663e+00 6.9906e-03 3.7449e-02 -6.0000e+00 1.3549e-01 3.8110e-02 7.9971e-03 2.5379e-02 -6.0000e+00 1.4790e-01 -2.7186e-02 6.4316e-03 1.2737e-02 -6.0000e+00 8.6872e-02 8.7415e-03 3.4834e-03 3.6906e-03 -6.0000e+00 3.5896e-02 5.6631e-03 -4.3613e-04 1.3680e-04 3.6222e-05 -6.0000e+00 2.4619e-03 2.7954e-02 -2.2835e-04 12 9 1 12 1 1 -866.59 19.92 0.26 0.02795 0.02468 4 107 1 5 0 104.808 25.39 20.01 19.92 15.21 33.9 917.28 -32103 12039 -39521 11249 -54623 -15227 -33472 -29317 7670 -20845 35415 -29116 11435 -20721 -3072 3454 -3538 12042 -10886 10549 -12615 5606 -2430 -2208 2734 -7635 9068 -10093 11277 -9848 1341 -1511 3124 2291 -7356 5663 -3490 1328 417 -633 593 -2795 1409 -1582 -547 -1452 -563 342 469 4584 174 2738 -353 2563 919 555 2318 -117 2420 940 2561 33 2388 1160 -566 -409 -301 -1279 -313 411 -250 -704 232 378 321 -818 -299 -1442 -305 83 -1717 -477 -2557 -801 -1191 -664 2 291 667 -160 722 165 1328 -5 74 -205 591 1593 -255 278 -331 -468 195 -422 73 -1601 -151 -770 -8 143 263 790 -29 -167 156 141 473 -499 7 -238 -564 -420 351 -123 727 525 209 891 74 236 269 809 -299 30 -457 -413 316 -149 63 -149 -18 -255 -174 -761 215 -1238 213 -1748 -323 -910 -874 181 -690 721 -1145 373 -1100 -168 208 -253 798 -951 805 -1222 461 -218 -214 273 -895 915 -1183 1048 -1136 158 -208 469 362 -1212 815 -588 253 96 -173 175 -887 448 -529 -182 -496 -192 117 163 1596 68 1126 -159 1206 452 278 1172 -60 1205 467 1291 18 1396 745 -374 -261 -187 -794 -207 301 -198 -575 185 291 235 -549 -191 -921 -208 63 -1463 -431 -2462 -796 -1233 -720 2 327 754 -177 756 163 1257 -4 76 -229 714 2063 -350 372 -425 -564 223 -503 91 -2079 -199 -1057 -12 217 421 1280 -47 -257 231 202 683 -745 11 -380 -896 -651 535 -183 1052 736 286 1250 112 373 446 1372 -519 53 -855 -789 611 -290 121 -281 -34 -451 -306 SS 20240420T064104.4Z 8876.278524 267 1 10.30 2 55.94 102.54 133.24 334.21 0.00 1 0.00 1 0 17 1.249e-02 4.880e-03 2.388e-03 6.155e-04 3.202971e-01 3.060316e-04 3.728023e-03 -6.000000e+00 7.023096e-03 229.29 -2.00 3.45 -2.00 317.56 0.00e+00 3.072303e-04 4.317359e-05 7.467118e-05 -6.000000e+00 2.810275e-04 282.24 -2.00 20.00 -2.00 317.23 0.00e+00 1.780 0.000 302.00 328.00 3 1.1786e+00 8.1194e-04 2.4077e-02 -6.0000e+00 1.7651e-02 1.9604e-02 9.1079e-04 1.6072e-02 -6.0000e+00 1.9260e-02 -3.6324e-03 5.6896e-04 7.9614e-03 -6.0000e+00 1.1314e-02 -2.0026e-03 2.8821e-04 2.2569e-03 -6.0000e+00 4.6783e-03 1.8153e-02 3.4134e-04 1.6904e-05 2.2430e-05 -6.0000e+00 3.2030e-04 2.6239e-02 -7.8249e-05 12 1 1 12 1 1 99.96 20.03 0.22 0.02624 0.02880 223 244 1 5 0 45.982 25.47 19.99 20.03 15.41 34.0 917.87 -3346 -2631 -3204 -5662 -4568 -6152 -2451 -2037 131 -2197 -4473 -1626 -1445 -320 -438 626 -315 348 557 297 650 -608 1100 663 -437 -101 -322 -578 -1312 157 925 1157 1368 -286 -2212 -2011 -1003 -1085 -197 -281 -827 -534 -499 -15 -239 294 -189 -59 -492 -29 1142 749 1049 1047 969 1005 753 580 319 913 726 1345 1030 1260 86 -473 -7 -773 531 108 -121 44 -234 196 -295 -201 -286 -625 -44 -659 -685 -1127 -1636 -1501 -762 -585 -354 -137 320 345 271 610 298 587 394 36 522 706 83 -349 -195 -295 -108 164 -620 -758 -636 -418 -41 189 353 85 198 69 233 286 358 71 -84 -182 -480 -174 200 104 636 317 516 1057 562 75 6 -142 -149 98 -12 -8 -72 215 -115 -263 -113 -303 -378 -269 -237 -303 -526 -370 -474 -192 -180 13 -236 -489 -176 -177 -46 -73 116 -62 72 120 67 150 -140 253 164 -107 -26 -83 -141 -326 38 238 301 391 -87 -642 -560 -300 -381 -83 -130 -424 -286 -276 -8 -133 164 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