File name: Pandora119s1_Athens-NOA_20240515_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20240515T234419.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20240515_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20240515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240515T035915.7Z 8901.166154 102 1 15.35 2 82.61 71.66 123.90 350.87 0.00 1 0.00 1 0 25 8.145e-01 5.846e-02 5.307e-01 4.453e-02 1.015393e+00 2.727948e-02 1.081033e-02 -6.000000e+00 4.945173e-01 231.19 -2.00 3.45 -2.00 322.38 0.00e+00 -4.497364e-03 1.131708e-02 1.125326e-03 -6.000000e+00 2.199996e-02 284.82 -2.00 20.00 -2.00 322.00 0.00e+00 7.192 0.006 302.00 328.00 3 2.3004e+00 8.9383e-02 8.9190e-02 -6.0000e+00 1.2610e+00 1.2657e+00 1.1032e-01 5.3035e-02 -6.0000e+00 1.3893e+00 -1.7858e+00 9.6744e-02 2.7934e-02 -6.0000e+00 8.0113e-01 7.2923e-01 5.1908e-02 9.0149e-03 -6.0000e+00 3.2722e-01 1.4676e-05 -3.5207e-03 1.2657e-03 1.3691e-04 -6.0000e+00 2.3058e-02 2.0681e-02 -2.0756e-04 12 9 9 12 1 1 13.80 21.51 0.56 0.02068 -0.00578 4 4 1 5 0 3068.916 26.62 20.00 21.51 21.41 34.5 954.01 900000 79695 900000 287490 -157258 900000 -74260 900000 900000 6786 123318 900000 900000 -139442 900000 10750 900000 900000 -11864 900000 900000 900000 26061 900000 -63246 -39606 -38763 -115153 900000 66437 900000 900000 900000 -52152 900000 284491 -93379 97266 -48878 900000 6633 172321 165012 135275 900000 -10356 229733 -15366 900000 228170 -42580 189220 111451 302211 3159 65764 -120 900000 67393 -20014 900000 -32744 279448 7544 77324 27765 -6828 -12321 -550 63796 -21200 38156 12744 115984 98923 -2572 52630 38258 11785 -3177 63304 6594 -11395 17870 -1887 21683 7099 4130 26760 20054 -555 -6635 13793 -11841 8735 -283 5310 -10670 -10988 -5095 -2673 18031 -5740 7028 4462 -12563 -4047 -8663 -2953 -8187 5804 3776 3059 5531 -3178 6504 -6465 -4630 -3885 -353 4059 -711 287 -8172 3646 8416 7364 2448 4579 3776 -2414 497 666 3021 -2110 1805 -2553 2345 -335 -515 1481 -4095 -342 900000 3443 900000 12421 -9567 900000 -3208 900000 900000 293 5328 900000 900000 -10166 900000 464 900000 900000 -513 900000 900000 900000 1126 900000 -3326 -1711 -1675 -8786 900000 2870 900000 900000 900000 -3380 900000 12291 -7805 4202 -3581 900000 382 7445 7129 5844 900000 -666 9925 -1047 900000 9858 -4679 8175 4815 13057 322 3810 -13 900000 3573 -2287 900000 -4275 12073 891 5087 2932 -1000 -2013 -89 6431 -5300 5715 2346 7458 6659 -398 4444 3869 1754 -659 8326 1759 -4012 5119 -683 6700 2591 1587 8294 6366 -197 -2379 4094 -4789 3372 -144 3051 -8307 -9446 -4213 -2069 10243 -3570 3850 2699 -9363 -2936 -7181 -2626 -8850 6350 4667 3970 6998 -4254 7684 -8830 -6536 -5642 -517 5493 -946 360 -10880 4276 9143 7881 2905 6330 6089 -4701 1031 1455 6976 -5432 4783 -7018 6180 -894 -1318 3393 -9228 -708 SS 20240515T041042.8Z 8901.174106 105 1 49.32 2 80.46 73.32 124.22 354.00 0.00 1 0.00 1 0 25 5.654e-01 2.289e-02 4.390e-01 1.404e-02 8.768074e-01 7.796100e-03 9.090819e-03 -6.000000e+00 3.218334e-01 231.19 -2.00 3.45 -2.00 322.08 0.00e+00 1.161301e-02 3.374513e-03 1.049184e-03 -6.000000e+00 1.299068e-02 284.82 -2.00 20.00 -2.00 321.72 0.00e+00 5.749 0.003 302.00 328.00 3 2.5168e+00 2.5064e-02 7.3483e-02 -6.0000e+00 8.1338e-01 7.0040e-01 3.5375e-02 4.5999e-02 -6.0000e+00 8.8732e-01 -1.0043e+00 3.8529e-02 2.4752e-02 -6.0000e+00 5.1998e-01 4.2002e-01 1.8623e-02 8.1753e-03 -6.0000e+00 2.1367e-01 5.3720e-05 -1.9846e-03 3.7740e-04 1.0567e-04 -6.0000e+00 1.4743e-02 2.0313e-02 -1.4894e-04 12 8 8 10 0 0 98.26 21.51 0.45 0.02031 0.00540 33 8 1 5 0 1494.270 26.62 20.00 21.51 22.16 34.5 958.37 43169 -76960 -189250 -169504 900000 -234654 -160658 -192061 -144528 -121201 -112002 -85811 -77241 -27176 -127271 -75371 -36023 3704 900000 27099 95297 62815 26750 28428 47680 -59934 178874 -15681 12878 -82987 466 57845 74962 56359 179431 -9165 -30377 27955 42682 38810 69253 32300 36985 53180 50371 29439 71073 50941 -360 51087 92682 38280 33794 41728 30290 24747 -2375 21084 18651 18349 13457 12846 4458 21377 16818 13940 22811 25588 14261 10609 6147 3665 16113 7497 3119 9963 -1164 -2660 -1608 576 9606 1932 -2564 2083 1393 -3606 -3248 1939 4463 2538 1871 3749 -809 -4537 -1084 -3103 -3682 -576 -633 -239 -1060 -2245 -2506 -4256 -3313 -1339 -2695 -2532 -1675 -3212 -3297 -337 167 -750 -519 -725 153 107 -802 984 787 3022 3470 875 434 1838 1571 2547 2401 1190 505 1706 305 -1034 35 835 -358 276 -83 -88 -1261 -1041 -1325 591 -1053 -6239 -4428 900000 -8903 -2931 -4881 -2354 -1658 -1533 -1174 -1057 -372 -4478 -1964 -728 58 900000 371 1304 860 366 389 652 -1718 2448 -290 176 -3082 10 871 1128 1118 2455 -307 -1247 765 1197 1328 1943 1392 1594 2001 1964 1450 2383 2196 -26 2517 3361 2569 2598 3208 2743 2419 -308 2116 1823 1734 1359 1440 630 2967 2663 2262 3374 3835 2648 2263 1514 960 3811 1788 695 1831 -224 -539 -374 154 2802 706 -1088 893 638 -1841 -1733 1009 2257 1258 869 1607 -354 -2184 -585 -2048 -2904 -516 -632 -240 -1003 -1898 -1889 -3238 -2687 -1125 -2427 -2467 -1815 -4091 -4586 -493 247 -1102 -762 -1032 219 163 -1242 1539 1250 4434 4854 1218 586 2372 1980 3417 3785 2106 1007 3629 699 -2580 92 2295 -1009 782 -232 -234 -3112 -2363 -2904 SS 20240515T041957.4Z 8901.180526 110 1 48.84 2 78.71 74.65 124.40 356.54 0.00 1 0.00 1 0 17 5.503e-01 1.728e-02 3.581e-01 1.031e-02 7.733816e-01 5.569166e-03 8.127912e-03 -6.000000e+00 3.116341e-01 231.19 -2.00 3.45 -2.00 321.72 0.00e+00 6.044199e-03 2.261802e-03 8.155429e-04 -6.000000e+00 1.238073e-02 284.83 -2.00 20.00 -2.00 321.35 0.00e+00 4.933 0.002 302.00 328.00 3 3.0488e+00 1.7252e-02 6.3710e-02 -6.0000e+00 7.8678e-01 3.3429e-01 2.4448e-02 4.0881e-02 -6.0000e+00 8.5720e-01 -4.9383e-01 2.7813e-02 2.2189e-02 -6.0000e+00 5.0278e-01 2.0640e-01 1.3576e-02 7.2310e-03 -6.0000e+00 2.0719e-01 8.0057e-05 -1.3025e-03 2.8085e-04 9.1486e-05 -6.0000e+00 1.4116e-02 2.0399e-02 -2.0871e-04 12 8 8 10 0 0 99.82 21.52 0.43 0.02040 0.01061 31 7 1 5 0 1575.328 26.62 20.00 21.52 22.66 34.6 961.14 -226921 -152699 -241529 56794 -190053 -141683 -230580 -42383 -91474 -226489 -82596 77552 -116761 -124303 67075 -50232 -31153 -25554 -6493 -7138 81183 107182 -65442 -42983 59959 -32936 -24401 -82735 -36342 -28683 -32707 -2777 -28301 39559 -17442 -18013 -43525 -18059 3640 10488 7060 -431 24923 24977 34489 35614 20011 31896 -5901 6502 17795 19277 17653 25635 11218 10841 10760 12016 13080 14286 11897 9874 6391 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