File name: Pandora119s1_Athens-NOA_20250104_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250104T223635.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20250104_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20250104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250104T074502.0Z 9135.322940 840 1 48.21 2 71.96 140.25 102.81 93.08 0.00 1 0.00 1 0 17 9.571e-02 6.866e-03 1.250e-01 6.217e-03 4.581256e-01 3.081596e-03 5.123732e-03 -6.000000e+00 5.260216e-02 223.73 -2.00 3.45 -2.00 320.09 0.00e+00 6.494948e-04 8.853202e-04 2.457158e-04 -6.000000e+00 2.152634e-03 277.80 -2.00 20.00 -2.00 319.75 0.00e+00 3.187 0.000 302.00 328.00 3 4.6239e+00 8.5708e-03 3.8622e-02 -6.0000e+00 1.3053e-01 2.1291e-02 1.0259e-02 2.2666e-02 -6.0000e+00 1.4313e-01 7.3977e-03 9.7267e-03 1.1794e-02 -6.0000e+00 8.4414e-02 -1.2589e-02 5.1975e-03 3.6336e-03 -6.0000e+00 3.5233e-02 1.2961e-04 1.0549e-04 1.7817e-04 3.7685e-05 -6.0000e+00 2.4530e-03 4.0046e-02 -1.3570e-04 11 8 0 10 0 0 99.44 20.43 0.34 0.04005 0.04084 20 5 1 5 0 2410.022 25.79 20.01 20.43 21.83 35.4 936.32 -23636 -18916 7273 -38393 -26004 -42760 -366 16416 -21096 -33347 15808 -20094 -1665 -33184 -6534 35323 -17546 -14048 14507 1488 353 -4707 25331 5364 3509 -21093 3818 -13078 -4194 -5944 304 1872 12400 4054 5535 -7163 -10496 228 -2084 -477 988 -1686 2826 -3245 -221 -2537 2135 459 0 -252 391 5723 2875 2693 -200 238 702 3357 1318 1738 2967 -48 2886 -246 -434 -538 -459 -348 -370 -590 -1195 509 348 772 703 -331 -1072 -3303 -97 -420 -487 -819 -1175 -1597 -1603 -827 -144 436 892 1303 1013 -274 566 606 -311 684 1073 1406 24 -409 -992 83 -1040 401 -707 -601 -1200 -320 -413 130 560 -14 490 -38 -3 57 164 109 3 -104 -341 -373 136 9 1379 -196 179 484 496 458 -362 -238 -172 -146 90 -68 -53 197 -162 -92 454 -384 -149 -334 -294 95 -746 -400 -751 -5 204 -426 -824 250 -475 -39 -1288 -236 999 -896 -747 620 76 19 -263 1114 307 221 -1756 257 -993 -278 -413 22 157 1060 398 503 -725 -1184 28 -317 -85 193 -359 600 -744 -49 -588 473 104 0 -61 103 1570 876 882 -69 84 254 1206 469 609 1063 -19 1239 -120 -215 -251 -210 -160 -184 -338 -753 327 221 461 394 -167 -503 -1575 -49 -251 -325 -615 -951 -1364 -1470 -784 -143 440 889 1262 908 -229 442 482 -276 683 1182 1735 32 -531 -1195 92 -1088 432 -837 -729 -1538 -431 -600 201 929 -23 806 -58 -5 80 234 164 5 -171 -557 -604 212 14 1948 -268 241 667 760 769 -638 -434 -325 -291 187 -147 -117 442 -360 -196 932 -758 -290 SS 20250104T074648.4Z 9135.324172 842 1 48.85 2 71.74 140.61 102.47 93.33 0.00 1 0.00 1 0 25 1.499e-01 7.424e-03 1.600e-01 6.410e-03 4.557925e-01 3.179196e-03 5.135126e-03 -6.000000e+00 8.238221e-02 223.73 -2.00 3.45 -2.00 320.08 0.00e+00 3.295863e-04 9.085425e-04 2.403203e-04 -6.000000e+00 3.371074e-03 277.80 -2.00 20.00 -2.00 319.74 0.00e+00 3.150 0.000 302.00 328.00 3 4.6766e+00 8.8555e-03 3.8308e-02 -6.0000e+00 2.0442e-01 1.3658e-02 1.0588e-02 2.2613e-02 -6.0000e+00 2.2416e-01 8.4976e-03 9.9908e-03 1.1730e-02 -6.0000e+00 1.3220e-01 -8.9233e-03 5.3381e-03 3.5962e-03 -6.0000e+00 5.5182e-02 1.2781e-04 -2.2460e-04 1.8390e-04 3.8480e-05 -6.0000e+00 3.8414e-03 4.0049e-02 -1.1877e-04 11 8 0 10 0 0 99.16 20.45 0.31 0.04005 0.03836 21 5 1 5 0 2325.767 25.79 20.01 20.45 21.86 35.3 936.51 36148 -44584 -30614 -25736 35200 -65328 93846 10107 -62608 -10768 -20798 11074 -27613 59206 -11145 -9335 4531 -898 15846 -12037 7849 -7617 17578 -16920 -6913 3718 -14028 7079 -8708 2953 2591 4839 4744 -5307 13488 -12134 1952 -6410 2199 -3553 -1228 -813 693 6513 -2330 3051 -2067 -1349 -184 -679 3267 -555 -355 3643 852 2138 -1049 1322 1079 -1120 -1677 2565 519 641 2662 2023 199 -1457 2763 417 -183 963 204 1019 -1323 1156 -1705 2272 292 -657 240 -2059 -189 -2140 -841 -924 -1117 890 877 243 -136 476 -692 -596 1244 -857 625 874 487 -788 -691 -793 -98 -513 -292 -601 -1118 -718 183 767 -71 -324 1449 95 407 -341 -273 -88 134 206 -595 511 146 -40 807 221 198 793 585 -556 114 10 -134 102 -54 -366 -123 329 -114 19 -319 -183 146 299 -909 -579 -448 314 -1459 587 136 -1902 -222 -471 199 -855 990 -425 -406 187 -42 673 -710 391 -441 840 -1218 -488 250 -1142 445 -609 188 188 393 438 -561 1137 -1293 199 -828 321 -655 -247 -173 151 1360 -534 671 -479 -312 -43 -165 832 -162 -112 1182 291 746 -388 486 386 -404 -629 1011 228 309 1282 922 90 -677 1355 236 -114 615 130 609 -742 577 -807 1023 148 -391 159 -1562 -152 -1835 -764 -898 -1118 895 876 238 -123 396 -548 -479 1083 -866 705 1081 642 -1026 -832 -879 -102 -557 -344 -745 -1431 -968 264 1181 -119 -554 2363 150 596 -481 -390 -132 214 344 -996 819 227 -60 1143 308 265 1107 889 -937 198 18 -252 201 -111 -791 -271 732 -252 41 -658 -358 282 SS 20250104T085812.0Z 9135.373750 1719 1 49.48 2 64.38 156.50 88.85 103.60 0.00 1 0.00 1 0 25 5.632e-02 7.431e-03 5.495e-02 6.261e-03 3.464781e-01 3.057991e-03 4.036498e-03 -6.000000e+00 3.095966e-02 223.73 -2.00 3.45 -2.00 319.08 0.00e+00 -1.349334e-04 6.538248e-04 1.222653e-04 -6.000000e+00 1.266696e-03 277.80 -2.00 20.00 -2.00 318.74 0.00e+00 2.298 0.000 302.00 328.00 3 5.5712e+00 8.2565e-03 2.8389e-02 -6.0000e+00 7.6825e-02 7.7154e-03 9.4592e-03 1.7151e-02 -6.0000e+00 8.4234e-02 2.7756e-02 7.2141e-03 8.7147e-03 -6.0000e+00 4.9679e-02 -1.5847e-02 3.8854e-03 2.5819e-03 -6.0000e+00 2.0744e-02 1.3451e-04 -6.8871e-04 1.7959e-04 2.7049e-05 -6.0000e+00 1.4434e-03 3.5828e-02 -2.1675e-04 11 8 0 10 0 0 99.99 20.79 0.23 0.03583 0.03065 15 3 1 5 0 3298.036 26.00 20.02 20.79 23.09 35.3 943.61 -14801 10357 -1447 19450 6488 9838 -16503 -20735 16147 -30281 23483 2188 -13912 13050 -4646 4955 4228 -2600 -2362 -591 3747 -1260 5503 -2097 2949 -6486 6527 -4072 -1684 10882 3305 7526 -5534 1965 -6016 -4776 -6158 4346 2557 -1768 1068 -2020 -1928 -1168 -931 1125 -2943 -1104 629 1458 -223 816 84 938 -1023 -316 2242 220 1539 1429 1223 777 552 2760 571 262 722 -1534 626 54 -35 0 719 441 -79 -240 847 270 -2892 -861 274 -11 -586 -1196 -1084 409 -505 -40 748 -57 390 -514 260 11 -1100 -92 -742 811 -1 -606 -90 -533 -12 238 283 -1019 27 -765 622 64 976 182 624 694 -978 -458 557 64 -222 -558 -1338 -690 816 299 1000 41 -304 1282 195 -175 382 -104 -122 405 462 -332 -200 -16 578 -106 -140 -182 -633 -559 351 -57 605 204 290 -661 -992 610 -1912 887 106 -888 771 -377 413 378 -263 -251 -64 402 -141 590 -262 376 -957 851 -558 -211 1222 436 1060 -965 333 -1032 -803 -1123 842 616 -527 342 -702 -693 -421 -335 398 -1073 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