File name: Pandora119s1_Athens-NOA_20250129_L2Fit_fout2c1d20210110p1-8.txt File generation date: 20250130T001200.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v1d20201201.txt Level 1 file used: Pandora119s1_Athens-NOA_20250129_L1_smca1c1d20210110p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20250129 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250129T061929.4Z 9160.263535 321 1 47.79 2 82.37 119.80 85.13 124.80 0.00 1 0.00 1 0 17 6.262e-01 3.646e-02 4.402e-01 2.725e-02 8.514167e-01 1.549267e-02 9.344266e-03 -6.000000e+00 3.542521e-01 224.44 -2.00 3.45 -2.00 321.90 0.00e+00 6.628780e-03 6.182588e-03 9.758437e-04 -6.000000e+00 1.571775e-02 277.07 -2.00 20.00 -2.00 321.56 0.00e+00 7.006 0.006 302.00 328.00 3 2.3086e+00 4.8907e-02 8.1729e-02 -6.0000e+00 8.8022e-01 1.0461e+00 6.1319e-02 4.4328e-02 -6.0000e+00 9.6255e-01 -1.3662e+00 5.8609e-02 2.4607e-02 -6.0000e+00 5.6415e-01 5.6710e-01 3.0715e-02 8.5210e-03 -6.0000e+00 2.4365e-01 2.0482e-05 -1.8940e-03 7.7000e-04 1.1516e-04 -6.0000e+00 1.6524e-02 5.2772e-02 -1.7263e-04 12 8 8 10 0 0 85.90 19.90 0.54 0.05277 0.03854 16 4 1 5 0 2986.045 25.39 20.01 19.90 18.12 34.8 915.49 900000 87498 -58580 900000 -63603 900000 -168244 -3062 -87029 -86638 121442 -120154 900000 -75470 255047 -3618 12934 192578 355600 900000 900000 72446 228 108905 100030 900000 4867 -63441 -5376 2472 47998 -42088 161671 -26329 107400 900000 -46770 151057 23358 107917 10050 17844 8323 37061 164633 22698 49166 -39076 59361 14610 7016 48304 31260 88062 49670 44301 38428 11344 20166 -1470 48667 1930 39258 3170 28341 37059 12510 14348 -9684 22458 -1030 24717 -8890 -3898 23266 -6966 7303 6554 13366 -14601 22075 5980 208 -1796 -772 10840 4592 11829 3923 200 -4715 -5594 -1975 -9053 177 -4898 -856 -4977 -3967 -1014 -2372 3913 -8420 -4124 -4494 -3336 -2076 -5097 -251 -3658 157 -545 2067 -1216 -3864 2768 -1601 3944 1663 -555 3486 2654 2938 -1555 4437 2012 371 -1060 2449 2507 -407 2587 -820 1483 -435 -510 -1346 -381 1052 -2492 1774 -1854 900000 900000 2321 -2383 900000 -1987 900000 -12421 -81 -3096 -3030 3222 -6022 900000 -4005 6767 -135 455 5109 9435 900000 900000 1922 8 2889 2654 900000 162 -3875 -180 83 1273 -3071 4289 -1937 2850 900000 -3838 4008 1283 3073 788 1343 704 2388 4368 1625 2795 -5302 3300 1325 762 3936 3183 5563 4658 4456 4102 1526 2327 -201 4212 288 4651 600 4494 5259 2269 2674 -2511 4848 -304 5738 -2766 -1053 4335 -1552 1343 1286 2878 -4948 6266 2239 90 -835 -377 4974 2337 5692 2013 101 -2326 -2635 -890 -4749 99 -3367 -667 -4689 -4016 -983 -2142 2914 -6439 -3163 -3651 -2818 -1843 -5087 -271 -4726 221 -821 3065 -1813 -5647 3695 -2295 5651 2575 -892 5167 3749 3993 -2143 5582 2504 464 -1486 3901 4581 -828 5475 -1912 3624 -1159 -1406 -3781 -1065 2835 -6501 4078 -4179 900000 SS 20250129T062141.9Z 9160.265068 323 1 48.11 2 82.00 120.17 84.78 125.15 0.00 1 0.00 1 0 25 5.098e-01 2.353e-02 4.020e-01 1.737e-02 8.122935e-01 9.782659e-03 8.770349e-03 -6.000000e+00 2.856737e-01 224.44 -2.00 3.45 -2.00 321.92 0.00e+00 6.853822e-03 4.112310e-03 1.026660e-03 -6.000000e+00 1.204504e-02 277.07 -2.00 20.00 -2.00 321.58 0.00e+00 6.719 0.005 302.00 328.00 3 2.0244e+00 3.1335e-02 7.8322e-02 -6.0000e+00 7.1020e-01 7.5866e-01 4.1240e-02 4.2769e-02 -6.0000e+00 7.7394e-01 -1.0958e+00 4.2688e-02 2.4160e-02 -6.0000e+00 4.5675e-01 4.6817e-01 2.1582e-02 8.4669e-03 -6.0000e+00 1.9815e-01 4.0668e-05 -1.1893e-03 4.9913e-04 1.1189e-04 -6.0000e+00 1.3346e-02 5.3739e-02 -2.1206e-04 12 8 8 10 0 0 91.32 19.90 0.52 0.05374 0.04480 29 7 1 5 0 1658.843 25.39 20.01 19.90 18.13 34.9 915.70 -166240 900000 -43595 900000 16336 -104036 -111289 -155798 -45935 -96723 62657 -106147 -114067 -14682 -48177 64664 -22616 40292 15075 292288 900000 900000 32036 -84924 106635 -57426 19175 68882 17631 19480 15010 212645 -10242 40389 5072 77434 -13904 10566 21585 27093 117622 29272 86941 52828 62476 11867 22596 22038 5135 45909 23255 43215 59418 22544 27747 9836 31914 24389 31744 23948 14633 6694 14905 13780 2315 31186 21680 -820 8998 1944 2731 2698 5029 6076 2446 4639 -4089 -2278 -4590 11564 -862 6098 -4236 -5666 360 -1117 4071 2305 2603 3145 1812 -3903 -4438 -378 -5718 -3861 -4586 500 -2220 -940 -1531 -3278 7 -6932 -1628 -2443 -1967 -1763 -1768 341 -151 -645 -297 1194 -115 -364 -896 -1598 901 192 947 1193 3150 1864 2033 1745 115 959 -424 1829 1978 740 484 -424 53 -1064 746 614 -387 -240 -773 -2157 900000 -8438 900000 -805 900000 276 -2400 -2739 -6231 -777 -2232 1060 -2939 -4386 -271 -1556 1094 -731 744 371 4945 900000 900000 591 -5225 1804 -2738 413 1165 353 419 416 3598 -504 1242 203 1429 -684 471 1029 1417 2714 1711 2942 2519 2691 858 1495 1525 442 2825 2003 3390 4296 2531 3073 1331 3485 2776 3174 2505 1733 958 2270 2416 477 4701 3601 -179 2007 535 806 813 1423 1561 579 956 -880 -512 -1243 3237 -322 2439 -2046 -2684 171 -570 2061 1209 1343 1674 908 -1963 -2225 -198 -3386 -2667 -3757 450 -2219 -912 -1371 -2630 5 -5464 -1315 -2094 -1789 -1745 -1982 432 -216 -979 -451 1733 -161 -500 -1275 -2422 1411 307 1447 1726 4322 2510 2649 2199 146 1337 -703 3381 4021 1627 1132 -1075 143 -2998 2089 1735 -1080 -626 -1870 -4920 900000 SS 20250129T062352.0Z 9160.266575 325 1 49.29 2 81.63 120.53 84.44 125.49 0.00 1 0.00 1 0 25 4.655e-01 2.156e-02 3.497e-01 1.420e-02 7.975257e-01 7.849714e-03 8.700103e-03 -6.000000e+00 2.624561e-01 224.44 -2.00 3.45 -2.00 321.84 0.00e+00 7.281873e-03 3.256264e-03 9.543875e-04 -6.000000e+00 1.056185e-02 277.07 -2.00 20.00 -2.00 321.50 0.00e+00 6.460 0.005 302.00 328.00 3 1.9310e+00 2.4805e-02 7.5720e-02 -6.0000e+00 6.5293e-01 6.3714e-01 3.3216e-02 4.1756e-02 -6.0000e+00 7.1196e-01 -8.7935e-01 3.5721e-02 2.3364e-02 -6.0000e+00 4.1785e-01 3.6701e-01 1.7905e-02 8.1162e-03 -6.0000e+00 1.7825e-01 5.7704e-05 -1.0956e-03 4.0022e-04 1.0698e-04 -6.0000e+00 1.2146e-02 5.3171e-02 -1.8429e-04 12 8 8 10 0 0 1.67 19.91 0.45 0.05317 0.04494 41 9 1 5 0 1201.917 25.39 20.00 19.91 18.14 34.9 916.08 -103449 -32097 -86360 -147567 104127 -200445 900000 -158608 -125680 -78261 -52120 -119244 -69911 900000 -119217 -16299 7381 -65347 20754 -55143 199076 -93733 -38511 -10180 -43632 -40891 -41067 37676 -10034 -2042 -69223 9419 -966 27241 5951 -25583 59948 42604 67753 45616 9386 47914 3671 110045 19800 46714 38021 30887 26576 25228 18780 26060 43812 8893 22106 29644 20747 18595 9985 28372 17822 10726 10498 -71 10061 9467 23807 3017 20915 15709 8972 10223 3223 3895 -4922 736 -12894 16124 1801 9139 -1939 -869 482 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