File name: Pandora119s1_Athens-NOA_20250205_L2Fit_fout2c11d20241209p1-8.txt File generation date: 20250721T083718.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v11d20241209.txt Level 1 file used: Pandora119s1_Athens-NOA_20250205_L1_smca1c11d20241209p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20250205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0039 305.1451 305.2864 305.4277 305.5690 305.7102 305.8515 305.9927 306.1339 306.2751 306.4163 306.5575 306.6987 306.8399 306.9810 307.1222 307.2633 307.4044 307.5455 307.6866 307.8277 307.9688 308.1099 308.2509 308.3920 308.5330 308.6740 308.8151 308.9561 309.0971 309.2380 309.3790 309.5200 309.6609 309.8018 309.9428 310.0837 310.2246 310.3655 310.5064 310.6472 310.7881 310.9289 311.0698 311.2106 311.3514 311.4922 311.6330 311.7738 311.9146 312.0553 312.1961 312.3368 312.4775 312.6183 312.7590 312.8996 313.0403 313.1810 313.3217 313.4623 313.6029 313.7436 313.8842 314.0248 314.1654 314.3059 314.4465 314.5871 314.7276 314.8682 315.0087 315.1492 315.2897 315.4302 315.5707 315.7111 315.8516 315.9920 316.1324 316.2729 316.4133 316.5537 316.6941 316.8344 316.9748 317.1151 317.2555 317.3958 317.5361 317.6764 317.8167 317.9570 318.0973 318.2376 318.3778 318.5180 318.6583 318.7985 318.9387 319.0789 319.2191 319.3592 319.4994 319.6395 319.7797 319.9198 320.0599 320.2000 320.3401 320.4801 320.6202 320.7603 320.9003 321.0403 321.1804 321.3204 321.4604 321.6003 321.7403 321.8803 322.0202 322.1601 322.3001 322.4400 322.5799 322.7198 322.8597 322.9995 323.1394 323.2792 323.4190 323.5589 323.6987 323.8385 323.9783 324.1180 324.2578 324.3975 324.5373 324.6770 324.8167 324.9564 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250205T074035.5Z 9167.319855 124 1 19.03 2 68.13 133.31 104.97 49.28 0.00 1 0.00 1 0 17 3.338e-02 4.590e-03 1.480e-02 1.483e-03 4.105793e-01 7.391464e-04 4.763849e-03 -6.000000e+00 1.871580e-02 224.67 -2.00 3.45 -2.00 319.05 0.00e+00 5.899687e-04 1.601598e-04 1.631792e-04 -6.000000e+00 7.549840e-04 277.02 -2.00 20.00 -2.00 318.78 0.00e+00 2.662 0.000 302.00 328.00 3 1.8228e+00 1.9957e-03 3.3283e-02 -6.0000e+00 4.6574e-02 2.6382e-02 2.2850e-03 2.0451e-02 -6.0000e+00 5.0741e-02 -7.6288e-03 1.8260e-03 1.0508e-02 -6.0000e+00 2.9880e-02 -3.4132e-03 9.9685e-04 3.2064e-03 -6.0000e+00 1.2791e-02 3.6707e-03 9.2811e-04 4.1365e-05 3.2203e-05 -6.0000e+00 8.5764e-04 5.0832e-02 0.0000e+00 12 1 1 12 1 1 99.98 19.32 0.25 0.05083 0.05781 101 60 1 5 0 186.533 24.86 20.00 19.32 11.76 34.0 881.29 -14054 -13521 -7924 -12762 -11064 -13422 -7926 -12369 -9020 -6337 -7507 -6652 -7167 -3493 -1805 -1603 -2511 -1207 1780 -927 350 -1132 1639 -638 -152 368 -978 -1610 -2292 1557 986 2298 1492 -989 -1482 -2438 -1380 -1517 -715 -658 -1145 -1004 -70 -43 276 -95 -813 -192 -1200 730 1323 996 1494 1228 907 821 640 394 128 759 506 1381 977 1674 137 -49 -185 -810 537 31 199 209 2 671 -379 -257 -52 -1276 -116 -931 -569 -1054 -1556 -1160 -794 -440 -163 114 492 496 480 575 245 477 222 175 645 709 92 -254 -451 -337 -389 -64 -552 -651 -653 -415 -115 50 544 53 379 -15 250 225 223 -152 -157 -331 -447 -247 155 121 680 138 617 825 597 137 -136 -23 -320 74 -58 -102 71 150 -142 -199 -20 -307 900000 -401 -434 -252 -404 -307 -406 -245 -418 -334 -244 -294 -275 -354 -201 -122 -123 -209 -106 161 -90 34 -112 163 -70 -18 45 -122 -191 -260 174 125 324 238 -168 -235 -386 -240 -315 -180 -179 -344 -318 -23 -14 91 -31 -271 -63 -403 249 489 403 646 568 437 408 326 199 63 368 256 759 599 1104 92 -30 -110 -489 355 22 151 164 2 487 -275 -166 -31 -763 -76 -711 -454 -941 -1487 -1162 -851 -466 -180 128 546 523 501 551 221 438 226 187 775 949 130 -347 -569 -383 -423 -74 -689 -852 -898 -601 -167 80 908 89 614 -23 375 325 328 -221 -245 -538 -722 -385 233 174 996 194 831 1173 877 220 -230 -41 -578 132 -110 -201 143 306 -286 -385 -36 -540 900000 SS 20250205T075825.2Z 9167.332237 134 1 3.87 2 65.66 137.11 102.31 52.36 0.00 1 0.00 1 0 17 2.737e-02 5.803e-03 1.695e-02 2.937e-03 3.731409e-01 1.459420e-03 4.393537e-03 -6.000000e+00 1.534601e-02 224.67 -2.00 3.45 -2.00 318.13 0.00e+00 4.326124e-04 2.444496e-04 1.101011e-04 -6.000000e+00 6.190120e-04 277.02 -2.00 20.00 -2.00 317.84 0.00e+00 2.409 0.000 302.00 328.00 3 2.1934e+00 3.8738e-03 3.0157e-02 -6.0000e+00 3.8188e-02 2.5066e-02 4.3585e-03 1.8528e-02 -6.0000e+00 4.1604e-02 -7.4399e-03 3.0024e-03 9.3889e-03 -6.0000e+00 2.4500e-02 -2.5698e-03 1.6100e-03 2.7942e-03 -6.0000e+00 1.0489e-02 3.3916e-03 9.8242e-04 8.0427e-05 2.8030e-05 -6.0000e+00 7.0314e-04 5.0200e-02 0.0000e+00 12 1 1 12 1 1 99.74 19.40 0.14 0.05020 0.05758 12 38 1 5 0 297.607 24.96 20.01 19.40 12.57 34.1 886.30 -2836 -4327 -3686 5165 -16684 9363 -13610 -2164 -2878 -758 -738 -7295 8026 -8841 3983 -4123 596 3026 -3325 4340 -2420 1126 -815 2376 282 891 1247 -2396 44 -2777 1200 1027 2857 543 -1528 767 -4813 -186 -2268 206 -441 -439 -140 -1310 687 -1292 -305 -361 -537 351 964 981 558 1091 -44 966 618 860 531 104 1678 379 1392 1297 409 352 -709 -242 177 592 -179 333 -347 561 270 -649 -366 -1005 -615 -538 -1279 -755 -1748 -1207 -524 -557 -112 553 358 190 692 58 248 -11 209 299 353 1256 -236 -161 -241 105 -535 -83 -685 -659 -291 -955 318 -62 537 120 209 227 -142 323 28 297 -158 -309 -311 -401 428 -465 799 59 731 1132 659 411 -146 24 -645 5 -107 -2 166 -1 -201 -324 179 -394 900000 -145 -251 -221 268 -955 409 -784 -127 -193 -53 -51 -572 633 -961 450 -556 82 429 -517 668 -397 181 -135 410 53 175 244 -457 8 -521 234 225 667 134 -357 177 -1271 -55 -811 82 -190 -195 -64 -612 315 -608 -141 -165 -251 164 485 526 315 651 -27 602 394 542 326 63 1052 258 998 986 312 258 -497 -169 133 491 -159 299 -308 486 218 -490 -258 -703 -462 -449 -1175 -739 -1806 -1282 -575 -642 -133 666 428 220 753 60 244 -11 221 345 436 1663 -322 -214 -305 125 -627 -102 -882 -875 -393 -1347 461 -96 857 190 326 338 -202 444 39 428 -239 -481 -482 -612 638 -676 1126 81 973 1555 971 628 -234 38 -1067 9 -189 -4 305 -2 -367 -582 312 -672 900000 SS 20250205T083012.5Z 9167.354311 160 1 48.73 2 61.69 144.41 97.31 57.55 0.00 1 0.00 1 0 17 1.443e-02 4.571e-03 1.810e-03 3.321e-04 3.247671e-01 1.652888e-04 3.857662e-03 -6.000000e+00 8.095440e-03 224.68 -2.00 3.45 -2.00 318.31 0.00e+00 4.202580e-04 2.841840e-05 9.578880e-05 -6.000000e+00 3.264753e-04 277.02 -2.00 20.00 -2.00 318.01 0.00e+00 2.098 0.000 302.00 328.00 3 3.3212e-01 4.3978e-04 2.6313e-02 -6.0000e+00 2.0146e-02 9.5578e-03 4.9532e-04 1.6224e-02 -6.0000e+00 2.1945e-02 -6.3395e-03 3.4359e-04 8.2297e-03 -6.0000e+00 1.2923e-02 -1.4518e-03 1.8356e-04 2.4555e-03 -6.0000e+00 5.5346e-03 3.1745e-02 8.5677e-04 9.3131e-06 2.5304e-05 -6.0000e+00 3.7077e-04 4.7918e-02 0.0000e+00 10 0 0 10 0 0 99.93 19.56 0.22 0.04792 0.05436 1387 319 1 5 0 35.128 25.07 20.00 19.56 13.16 34.3 889.30 -3669 -3370 -3013 -5856 -6712 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