File name: Pandora119s1_Athens-NOA_20250521_L2Fit_fout2c9d20230501p1-8.txt File generation date: 20250611T143151.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v9d20230501.txt Level 1 file used: Pandora119s1_Athens-NOA_20250521_L1_smca1c9d20230501p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20250521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0070 305.1482 305.2895 305.4308 305.5720 305.7132 305.8545 305.9957 306.1369 306.2781 306.4192 306.5604 306.7016 306.8427 306.9838 307.1250 307.2661 307.4072 307.5483 307.6893 307.8304 307.9715 308.1125 308.2536 308.3946 308.5356 308.6766 308.8176 308.9586 309.0995 309.2405 309.3815 309.5224 309.6633 309.8042 309.9451 310.0860 310.2269 310.3678 310.5086 310.6495 310.7903 310.9312 311.0720 311.2128 311.3536 311.4944 311.6351 311.7759 311.9166 312.0574 312.1981 312.3388 312.4795 312.6202 312.7609 312.9016 313.0422 313.1829 313.3235 313.4642 313.6048 313.7454 313.8860 314.0265 314.1671 314.3077 314.4482 314.5888 314.7293 314.8698 315.0103 315.1508 315.2913 315.4317 315.5722 315.7126 315.8531 315.9935 316.1339 316.2743 316.4147 316.5551 316.6954 316.8358 316.9761 317.1165 317.2568 317.3971 317.5374 317.6777 317.8180 317.9582 318.0985 318.2387 318.3789 318.5192 318.6594 318.7996 318.9397 319.0799 319.2201 319.3602 319.5004 319.6405 319.7806 319.9207 320.0608 320.2009 320.3409 320.4810 320.6210 320.7611 320.9011 321.0411 321.1811 321.3211 321.4611 321.6010 321.7410 321.8809 322.0208 322.1608 322.3007 322.4406 322.5804 322.7203 322.8602 323.0000 323.1398 323.2797 323.4195 323.5593 323.6991 323.8388 323.9786 324.1184 324.2581 324.3978 324.5376 324.6773 324.8170 324.9566 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250521T041550.2Z 9272.177665 174 1 48.25 2 78.79 73.00 50.10 161.34 0.00 1 0.00 1 0 25 5.311e-01 1.467e-02 3.506e-01 9.611e-03 6.875499e-01 5.359634e-03 7.437229e-03 -6.000000e+00 3.092731e-01 231.45 -2.00 3.45 -2.00 321.41 0.00e+00 5.269591e-03 2.089336e-03 7.106627e-04 -6.000000e+00 1.253182e-02 285.31 -2.00 20.00 -2.00 321.09 0.00e+00 4.964 0.002 302.00 328.00 3 2.9042e+00 1.6489e-02 6.1364e-02 -6.0000e+00 7.8223e-01 1.4244e-01 2.3532e-02 3.7386e-02 -6.0000e+00 8.4956e-01 -2.1422e-01 2.7952e-02 2.1053e-02 -6.0000e+00 4.9416e-01 9.3692e-02 1.3805e-02 7.1234e-03 -6.0000e+00 2.1017e-01 1.0088e-04 -1.3575e-04 2.8134e-04 7.8533e-05 -6.0000e+00 1.4249e-02 4.7201e-02 0.0000e+00 12 9 8 11 8 0 93.13 20.75 0.24 0.04720 0.04618 27 6 1 5 0 1786.708 26.00 20.01 20.75 24.72 35.6 965.30 900000 -148343 -150518 900000 -235539 900000 -200507 900000 -136649 -165899 -56767 164138 29884 -153930 900000 -56253 103801 -33528 73608 36425 -77720 40026 -101296 900000 14897 229425 -34636 14385 -7236 28169 53400 -32435 104833 -3530 -6010 15941 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-1171 1173 -24 351 1370 -1267 1512 -1212 1502 44 -771 1097 -2333 1626 -1513 79 -1867 -207 -1469 -1556 324 -1927 1213 -1942 1859 1327 -529 -195 -774 511 -1900 714 879 534 1082 -601 1800 -320 2187 616 456 1357 1289 513 -1415 935 -220 900 -696 -11 -838 -1972 480 -384 900000 SS 20250521T042302.6Z 9272.182669 177 1 48.59 2 77.43 74.02 49.65 163.53 0.00 1 0.00 1 0 25 3.445e-01 6.455e-03 1.947e-01 3.690e-03 6.318882e-01 1.993372e-03 6.863720e-03 -6.000000e+00 1.981366e-01 231.45 -2.00 3.45 -2.00 321.13 0.00e+00 4.980883e-03 7.372733e-04 5.754950e-04 -6.000000e+00 7.792354e-03 285.31 -2.00 20.00 -2.00 320.82 0.00e+00 4.466 0.001 302.00 328.00 3 1.9443e+00 5.9835e-03 5.5452e-02 -6.0000e+00 5.0089e-01 3.7042e-02 8.2346e-03 3.3964e-02 -6.0000e+00 5.4291e-01 -7.6179e-02 9.6635e-03 1.8971e-02 -6.0000e+00 3.1806e-01 3.2941e-02 4.8512e-03 6.3526e-03 -6.0000e+00 1.3430e-01 4.5446e-04 2.3729e-04 1.0596e-04 6.5603e-05 -6.0000e+00 8.8627e-03 4.6618e-02 0.0000e+00 11 8 0 10 0 0 83.49 20.77 0.23 0.04662 0.04840 96 22 1 5 0 505.957 26.00 20.00 20.77 25.16 35.5 967.60 -56889 -157714 -130331 -125295 -151305 -81486 -110274 8176 -108384 -53136 -126759 -77286 -39498 -67942 47389 -62583 -15601 -26870 -14294 10581 -31287 -3529 -26224 7046 -36453 -9494 -13000 -19357 -22415 -32540 31695 -14688 6253 -3954 5996 -790 -15802 9019 -8156 1241 -5917 9280 -1906 1419 6497 173 3810 -2167 7379 1173 3848 7514 2940 4178 201 4220 138 3717 1964 2016 2830 -411 4924 1465 434 -1438 857 -536 -475 2547 67 1459 -798 693 186 -2054 -30 -1254 1427 -852 -385 -1132 -1272 -1830 -1189 -126 -458 631 903 760 264 1206 109 -733 226 -319 475 316 -118 -86 -125 30 -804 20 -1217 -234 -666 -647 -113 -152 496 185 450 120 91 411 6 -161 -720 -404 -709 50 331 16 626 208 1067 537 503 218 -45 204 -194 37 -151 11 80 128 -39 -384 320 -514 900000 -205 -1857 -1279 -1148 -1633 -426 -830 29 -1028 -344 -1617 -683 -310 -933 290 -1269 -225 -483 -248 152 -706 -60 -583 122 -1049 -221 -319 -494 -587 -1033 643 -572 231 -173 226 -32 -817 437 -579 96 -504 795 -177 143 584 17 374 -235 761 138 495 1045 469 715 38 791 28 713 373 380 554 -93 1209 419 130 -423 243 -160 -160 962 28 630 -345 277 68 -686 -9 -404 513 -375 -196 -660 -805 -1230 -853 -95 -365 510 722 580 187 793 70 -498 174 -286 488 371 -137 -98 -141 30 -762 20 -1309 -262 -791 -823 -145 -220 780 303 723 184 130 571 8 -244 -1167 -670 -1155 77 494 23 935 299 1485 812 799 388 -86 412 -413 84 -367 28 205 331 -99 -934 725 -1109 900000 SS 20250521T042822.7Z 9272.186374 180 1 48.65 2 76.41 74.77 49.35 165.18 0.00 1 0.00 1 0 25 2.629e-01 5.265e-03 8.366e-02 2.258e-03 5.941351e-01 1.200528e-03 6.541366e-03 -6.000000e+00 1.512058e-01 231.45 -2.00 3.45 -2.00 320.86 0.00e+00 3.653641e-03 4.154823e-04 4.846426e-04 -6.000000e+00 5.946739e-03 285.31 -2.00 20.00 -2.00 320.56 0.00e+00 4.155 0.001 302.00 328.00 3 1.4942e+00 3.5479e-03 5.1773e-02 -6.0000e+00 3.8225e-01 2.6610e-02 4.6530e-03 3.1668e-02 -6.0000e+00 4.1432e-01 -5.4243e-02 5.2620e-03 1.7215e-02 -6.0000e+00 2.4273e-01 1.9856e-02 2.6921e-03 5.6087e-03 -6.0000e+00 1.0249e-01 9.9543e-04 1.4790e-04 6.4424e-05 6.1218e-05 -6.0000e+00 6.7637e-03 4.6798e-02 0.0000e+00 10 0 0 10 0 0 65.30 20.78 0.23 0.04680 0.04791 169 39 1 5 0 287.798 26.11 20.01 20.78 25.63 35.6 970.62 -93692 -84793 -35715 -90540 -90784 -95785 -117233 -58549 -109220 -73672 -76143 -41456 -47828 -22040 -28585 -41244 -1018 -31684 -23246 248 -4276 -4689 -5828 -12562 -20922 5286 -7549 -16550 -9430 -9810 -1740 -2673 4485 -9955 -1845 -4051 -6325 3328 -1086 4648 -1592 -1363 228 813 2536 982 3082 -1068 577 -1359 4088 3689 3492 1711 639 1884 2115 2011 1994 364 1759 1828 1957 1144 1514 29 1120 390 1165 -105 588 884 -673 360 -1338 -345 -955 -1197 -626 -1694 -748 -1267 -1224 -1527 -1073 -324 -510 732 774 992 895 479 121 -388 15 -108 771 444 92 -249 -380 -244 -212 -256 -883 -833 -516 -473 -127 96 311 -9 473 70 107 320 130 57 -563 -174 -338 -153 136 -157 799 103 699 510 536 53 167 85 -156 21 -204 -118 110 129 -260 -120 79 -164 900000 -743 -728 -204 -877 -800 -865 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