File name: Pandora257s1_AustinTX_20240128_L2Fit_fwvt1c2d20230110p1-8.txt File generation date: 20240129T065223.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 257 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora257_OF_v2d20221216.txt Instrument calibration file used: Pandora257s1_CF_v2d20230110.txt Level 1 file used: Pandora257s1_AustinTX_20240128_L1_smca1c2d20230110p1-8.txt Full location name: St. Edward's University Short location name: AustinTX Country of location: United States Location latitude [deg]: 30.2285 Location longitude [deg]: -97.7544 Location altitude [m]: 205 Local noon date: 20240128 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1653 1803 Nominal wavelengths inside fitting window [nm]: 492.0741 492.1946 492.3152 492.4357 492.5562 492.6767 492.7971 492.9176 493.0380 493.1584 493.2788 493.3992 493.5196 493.6399 493.7603 493.8806 494.0009 494.1211 494.2414 494.3617 494.4819 494.6021 494.7223 494.8425 494.9626 495.0828 495.2029 495.3230 495.4431 495.5632 495.6832 495.8033 495.9233 496.0433 496.1633 496.2832 496.4032 496.5231 496.6430 496.7630 496.8828 497.0027 497.1226 497.2424 497.3622 497.4820 497.6018 497.7215 497.8413 497.9610 498.0807 498.2004 498.3201 498.4398 498.5594 498.6790 498.7987 498.9183 499.0378 499.1574 499.2769 499.3964 499.5160 499.6354 499.7549 499.8744 499.9938 500.1132 500.2326 500.3520 500.4714 500.5907 500.7101 500.8294 500.9487 501.0680 501.1872 501.3065 501.4257 501.5449 501.6641 501.7833 501.9024 502.0216 502.1407 502.2598 502.3789 502.4980 502.6170 502.7361 502.8551 502.9741 503.0931 503.2121 503.3310 503.4500 503.5689 503.6878 503.8067 503.9255 504.0444 504.1632 504.2820 504.4008 504.5196 504.6383 504.7571 504.8758 504.9945 505.1132 505.2319 505.3505 505.4692 505.5878 505.7064 505.8250 505.9436 506.0621 506.1806 506.2992 506.4177 506.5361 506.6546 506.7730 506.8915 507.0099 507.1283 507.2467 507.3650 507.4834 507.6017 507.7200 507.8383 507.9565 508.0748 508.1930 508.3113 508.4295 508.5476 508.6658 508.7839 508.9021 509.0202 509.1383 509.2564 509.3744 509.4925 509.6105 509.7285 509.8465 509.9645 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240128T132954.5Z 8793.562437 232 1 28.63 2 89.65 111.45 68.20 269.90 0.00 1 0.00 1 0 29 1.001e-02 9.884e-03 1.585e-04 1.578e-04 1.223386e+04 1.088112e+01 8.119307e+02 -6.000000e+00 5.684756e+02 283.41 -2.00 20.00 -2.00 505.43 0.00e+00 2.986995e-03 4.427457e-06 1.756204e-04 -6.000000e+00 2.830478e-04 283.41 -2.00 20.00 -2.00 501.18 0.00e+00 8.773459e-01 3.022303e-03 9.082283e-02 -6.000000e+00 1.987275e-01 224.60 -2.00 3.25 -2.00 502.66 0.00e+00 19.991 0.098 489.00 513.00 1 1.4863e+00 2.3158e-04 3.2419e-02 -6.0000e+00 1.5271e-02 -3.6037e-02 5.7526e-05 2.7226e-03 -6.0000e+00 3.9184e-03 2.4166e-02 2.6420e-03 1.5599e-05 1.1100e-04 -6.0000e+00 1.0664e-03 -1.1389e-03 -3.1326e-05 12 8 8 10 0 0 68.26 25.25 5.28 -0.00114 0.01719 510 49 1 4 0 56.120 34.00 20.25 25.25 10.85 0.8 829.30 -1874 -1103 16 794 1147 1626 2003 1954 1688 1137 624 173 -286 -648 -858 -889 -487 327 830 733 535 512 499 741 1028 1015 866 563 -342 -1504 -2001 -1844 -942 303 829 506 102 -215 -558 -731 -597 -266 95 586 865 1000 873 536 155 -520 -1308 -1989 -2298 -1887 -853 137 625 647 542 486 656 904 1043 1048 826 420 -71 -353 -583 -988 -1257 -1226 -833 -221 193 -252 -969 -1415 -1536 -1449 -1430 -1340 -1244 -1031 -696 -593 -668 -701 -839 -791 -431 244 1041 1338 1106 584 77 -402 -874 -1592 -2239 -2240 -1364 -120 539 396 -251 -865 -1078 -741 -142 366 733 963 1106 1242 1631 1978 1884 1401 730 176 125 507 881 947 888 767 749 904 873 300 -380 -857 -984 -669 -146 89 199 422 533 594 601 621 716 612 177 -506 -1188 -1491 -1225 -1620 -967 15 716 1060 1495 1868 1840 1592 1067 581 160 -263 -592 -784 -819 -455 304 786 704 518 486 476 711 991 981 837 539 -324 -1435 -1893 -1756 -891 293 800 495 100 -210 -541 -709 -581 -261 94 587 856 993 867 529 155 -510 -1264 -1940 -2232 -1806 -831 136 620 651 548 492 667 903 1047 1053 827 426 -71 -352 -577 -974 -1236 -1208 -826 -221 194 -254 -968 -1399 -1506 -1416 -1400 -1318 -1234 -1034 -689 -591 -670 -703 -840 -792 -433 247 1057 1354 1104 583 75 -392 -840 -1519 -2146 -2137 -1338 -119 540 405 -259 -893 -1113 -767 -146 378 764 1010 1166 1293 1711 2091 2001 1485 768 183 131 533 910 985 929 805 787 949 913 312 -395 -887 -1025 -705 -156 95 216 455 582 655 667 680 785 669 196 -556 -1295 -1623 -1341 SQ 20240128T133023.2Z 8793.562769 232 2 28.63 2 89.55 111.51 68.30 269.96 0.00 1 0.00 1 0 22 9.574e-03 9.445e-03 1.468e-04 1.462e-04 1.185033e+04 1.007821e+01 7.909989e+02 -6.000000e+00 5.436058e+02 283.41 -2.00 20.00 -2.00 505.43 0.00e+00 2.824787e-03 4.108223e-06 1.665816e-04 -6.000000e+00 2.706537e-04 283.41 -2.00 20.00 -2.00 501.15 0.00e+00 8.976375e-01 2.808343e-03 8.743397e-02 -6.000000e+00 1.900144e-01 224.60 -2.00 3.25 -2.00 502.64 0.00e+00 19.831 0.096 489.00 513.00 1 1.3613e+00 2.1533e-04 3.1996e-02 -6.0000e+00 1.4601e-02 -3.2933e-02 5.3485e-05 2.6555e-03 -6.0000e+00 3.7463e-03 2.8030e-02 2.3340e-03 1.4455e-05 1.0664e-04 -6.0000e+00 1.0196e-03 8.9598e-03 -8.6741e-05 12 8 8 10 0 0 67.15 25.24 5.00 0.00896 0.02515 510 49 1 4 0 56.120 34.00 19.76 25.24 10.93 0.8 829.30 -1813 -1031 20 741 1065 1566 1921 1864 1595 1050 572 166 -283 -620 -825 -867 -495 326 818 718 547 443 456 695 969 940 853 568 -339 -1425 -1917 -1779 -907 328 813 481 67 -198 -549 -713 -550 -259 88 501 853 918 827 515 156 -462 -1256 -1912 -2249 -1843 -743 147 618 629 497 444 575 886 994 995 789 395 -47 -335 -564 -910 -1176 -1164 -774 -181 205 -206 -905 -1376 -1446 -1387 -1338 -1251 -1184 -975 -676 -539 -589 -678 -796 -747 -408 218 1032 1319 1117 598 88 -341 -838 -1525 -2192 -2140 -1302 -103 549 388 -228 -835 -1050 -710 -142 365 691 895 1016 1148 1561 1878 1802 1300 687 179 99 482 833 874 833 727 686 880 880 307 -389 -811 -947 -639 -171 90 165 390 517 531 575 641 687 565 174 -475 -1150 -1455 -1204 -1578 -911 18 674 971 1455 1811 1734 1486 974 538 155 -263 -571 -761 -806 -457 306 783 682 524 426 440 675 944 920 832 549 -324 -1342 -1830 -1670 -866 320 794 476 67 -195 -538 -699 -541 -257 86 496 853 922 830 513 154 -457 -1222 -1837 -2152 -1777 -728 145 619 624 496 444 577 893 1006 1009 797 396 -47 -330 -563 -903 -1164 -1154 -773 -179 203 -204 -891 -1370 -1427 -1363 -1318 -1238 -1158 -964 -674 -542 -594 -685 -804 -754 -413 218 1035 1319 1125 590 87 -328 -794 -1465 -2117 -2056 -1260 -103 554 392 -232 -852 -1071 -726 -147 381 712 928 1060 1207 1653 1966 1895 1364 729 188 103 501 868 918 878 769 714 913 928 323 -407 -845 -992 -664 -180 97 177 424 558 580 633 708 759 623 191 -515 -1240 -1566 -1303 SQ 20240128T133254.2Z 8793.564516 236 1 19.39 2 89.05 111.83 68.84 270.26 0.00 1 0.00 1 0 22 8.037e-03 7.950e-03 1.305e-04 1.301e-04 9.870246e+03 8.802266e+00 6.652102e+02 -6.000000e+00 4.563653e+02 283.41 -2.00 20.00 -2.00 505.41 0.00e+00 2.091208e-03 3.642543e-06 1.255020e-04 -6.000000e+00 2.271992e-04 283.41 -2.00 20.00 -2.00 501.07 0.00e+00 1.021703e+00 2.504484e-03 7.292829e-02 -6.000000e+00 1.594421e-01 224.60 -2.00 3.25 -2.00 502.57 0.00e+00 18.790 0.081 489.00 513.00 1 8.9123e-01 1.9197e-04 2.9519e-02 -6.0000e+00 1.2253e-02 -1.9858e-02 4.7909e-05 2.3232e-03 -6.0000e+00 3.1420e-03 5.2022e-02 1.4415e-03 1.2986e-05 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