File name: Pandora257s1_AustinTX_20240310_L2Fit_fwvt1c2d20230110p1-8.txt File generation date: 20240311T065202.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 257 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora257_OF_v2d20221216.txt Instrument calibration file used: Pandora257s1_CF_v2d20230110.txt Level 1 file used: Pandora257s1_AustinTX_20240310_L1_smca1c2d20230110p1-8.txt Full location name: St. Edward's University Short location name: AustinTX Country of location: United States Location latitude [deg]: 30.2285 Location longitude [deg]: -97.7544 Location altitude [m]: 205 Local noon date: 20240310 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1653 1803 Nominal wavelengths inside fitting window [nm]: 492.0741 492.1946 492.3152 492.4357 492.5562 492.6767 492.7971 492.9176 493.0380 493.1584 493.2788 493.3992 493.5196 493.6399 493.7603 493.8806 494.0009 494.1211 494.2414 494.3617 494.4819 494.6021 494.7223 494.8425 494.9626 495.0828 495.2029 495.3230 495.4431 495.5632 495.6832 495.8033 495.9233 496.0433 496.1633 496.2832 496.4032 496.5231 496.6430 496.7630 496.8828 497.0027 497.1226 497.2424 497.3622 497.4820 497.6018 497.7215 497.8413 497.9610 498.0807 498.2004 498.3201 498.4398 498.5594 498.6790 498.7987 498.9183 499.0378 499.1574 499.2769 499.3964 499.5160 499.6354 499.7549 499.8744 499.9938 500.1132 500.2326 500.3520 500.4714 500.5907 500.7101 500.8294 500.9487 501.0680 501.1872 501.3065 501.4257 501.5449 501.6641 501.7833 501.9024 502.0216 502.1407 502.2598 502.3789 502.4980 502.6170 502.7361 502.8551 502.9741 503.0931 503.2121 503.3310 503.4500 503.5689 503.6878 503.8067 503.9255 504.0444 504.1632 504.2820 504.4008 504.5196 504.6383 504.7571 504.8758 504.9945 505.1132 505.2319 505.3505 505.4692 505.5878 505.7064 505.8250 505.9436 506.0621 506.1806 506.2992 506.4177 506.5361 506.6546 506.7730 506.8915 507.0099 507.1283 507.2467 507.3650 507.4834 507.6017 507.7200 507.8383 507.9565 508.0748 508.1930 508.3113 508.4295 508.5476 508.6658 508.7839 508.9021 509.0202 509.1383 509.2564 509.3744 509.4925 509.6105 509.7285 509.8465 509.9645 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240310T125145.3Z 8835.535941 23 1 34.41 2 89.62 94.60 93.64 93.99 0.00 1 0.00 1 0 29 1.170e-02 1.155e-02 3.966e-04 3.944e-04 1.615229e+04 2.842116e+01 1.054011e+03 -6.000000e+00 6.670837e+02 284.32 -2.00 20.00 -2.00 505.46 0.00e+00 4.632041e-03 1.112030e-05 2.673815e-04 -6.000000e+00 3.315416e-04 284.32 -2.00 20.00 -2.00 501.20 0.00e+00 6.974964e-01 7.591369e-03 1.168864e-01 -6.000000e+00 2.328322e-01 226.68 -2.00 3.25 -2.00 502.67 0.00e+00 19.933 0.097 489.00 513.00 1 3.4377e+00 5.8172e-04 3.3244e-02 -6.0000e+00 1.7892e-02 -3.8623e-02 1.4382e-04 3.2090e-03 -6.0000e+00 4.5935e-03 3.3995e-03 3.2123e-03 3.8149e-05 1.4724e-04 -6.0000e+00 1.2468e-03 -2.1741e-03 -4.2742e-05 12 9 9 12 1 1 97.85 25.60 6.55 -0.00217 0.02011 88 14 1 4 0 386.590 34.25 20.08 25.60 12.65 0.7 842.79 -2026 -1162 35 990 1427 2021 2362 2356 2047 1332 733 257 -289 -619 -953 -992 -607 368 917 763 643 545 567 787 1091 1214 990 603 -433 -1728 -2309 -2101 -1101 213 850 497 120 -206 -640 -793 -605 -210 155 645 1159 1181 994 574 224 -583 -1466 -2224 -2582 -2132 -988 163 700 758 597 647 735 1114 1236 1179 929 529 -98 -494 -736 -1180 -1440 -1493 -1091 -484 6 -466 -1143 -1670 -1771 -1804 -1722 -1722 -1470 -1230 -904 -746 -765 -906 -1107 -926 -492 372 1236 1602 1323 766 40 -537 -1044 -1960 -2604 -2603 -1663 -231 436 294 -258 -957 -1156 -780 -126 473 907 1175 1297 1549 1979 2363 2242 1638 859 354 186 638 1091 1170 1112 883 833 990 912 197 -517 -1032 -993 -642 -199 40 173 447 662 649 688 807 743 704 183 -647 -1313 -1694 -1388 -1745 -1015 31 880 1300 1873 2221 2163 1881 1220 687 239 -268 -569 -877 -921 -554 342 865 730 619 527 535 746 1040 1160 946 572 -406 -1650 -2187 -2001 -1034 204 832 492 119 -203 -631 -782 -599 -203 152 641 1160 1189 1001 575 221 -570 -1412 -2183 -2528 -2042 -962 162 709 756 599 651 742 1128 1258 1203 945 535 -98 -491 -727 -1159 -1411 -1466 -1079 -482 6 -466 -1135 -1642 -1726 -1802 -1720 -1679 -1443 -1219 -904 -750 -771 -913 -1113 -928 -494 375 1249 1610 1309 761 39 -508 -972 -1873 -2428 -2470 -1624 -227 443 297 -263 -980 -1185 -802 -131 482 931 1212 1346 1618 2086 2515 2402 1755 913 372 194 662 1136 1227 1174 936 885 1052 965 208 -543 -1084 -1049 -668 -210 43 189 482 722 715 764 898 828 781 202 -710 -1432 -1846 -1522 SQ 20240310T125436.7Z 8835.537925 27 1 47.82 2 89.01 94.96 93.04 94.32 0.00 1 0.00 1 0 29 8.940e-03 8.826e-03 1.688e-04 1.682e-04 1.460269e+04 1.199496e+01 9.642059e+02 -6.000000e+00 5.096351e+02 284.32 -2.00 20.00 -2.00 505.43 0.00e+00 3.468432e-03 4.733908e-06 2.027063e-04 -6.000000e+00 2.532581e-04 284.32 -2.00 20.00 -2.00 501.06 0.00e+00 9.771049e-01 3.257591e-03 1.024510e-01 -6.000000e+00 1.777831e-01 226.68 -2.00 3.25 -2.00 502.57 0.00e+00 18.682 0.080 489.00 513.00 1 2.2706e+00 2.4983e-04 3.0178e-02 -6.0000e+00 1.3663e-02 -2.7245e-02 6.1973e-05 2.8875e-03 -6.0000e+00 3.5054e-03 1.2956e-02 2.2380e-03 1.6344e-05 1.2450e-04 -6.0000e+00 9.5214e-04 -2.6747e-04 -1.6138e-05 12 9 9 12 1 1 96.25 25.58 4.47 -0.00027 0.01526 394 44 1 4 0 121.040 34.25 20.11 25.58 12.67 0.7 843.17 -1618 -926 62 724 1008 1453 1730 1734 1488 928 481 142 -263 -610 -773 -812 -478 283 772 618 425 375 362 626 892 884 815 568 -334 -1308 -1801 -1689 -848 323 786 449 68 -201 -532 -688 -513 -251 51 487 793 878 773 503 156 -381 -1127 -1753 -2111 -1735 -739 167 591 577 452 394 525 817 939 915 742 393 -76 -318 -512 -888 -1084 -1119 -753 -166 207 -181 -874 -1283 -1338 -1312 -1265 -1183 -1120 -869 -570 -518 -537 -629 -753 -709 -357 296 1095 1340 1046 570 65 -375 -701 -1377 -2056 -2054 -1246 -80 567 410 -210 -793 -998 -686 -121 316 583 757 839 979 1442 1789 1729 1227 614 92 15 411 784 871 793 692 633 820 769 200 -391 -755 -873 -557 -94 63 143 346 520 517 568 614 642 571 203 -421 -1068 -1379 -1092 -1435 -834 56 671 937 1377 1626 1642 1411 875 449 134 -248 -571 -723 -765 -447 269 748 593 411 364 353 614 879 874 803 555 -322 -1241 -1732 -1597 -816 317 773 447 68 -199 -524 -678 -507 -250 50 486 798 888 780 504 155 -379 -1103 -1691 -2030 -1681 -728 164 595 588 454 397 529 826 954 931 752 395 -77 -320 -511 -881 -1072 -1109 -751 -167 209 -183 -876 -1270 -1313 -1281 -1236 -1161 -1108 -868 -562 -515 -535 -627 -748 -703 -356 296 1098 1338 1029 558 63 -357 -655 -1307 -1961 -1950 -1193 -79 569 412 -213 -806 -1014 -699 -125 321 598 781 870 1023 1518 1862 1810 1282 635 96 15 423 810 906 829 727 652 860 804 209 -405 -779 -907 -574 -98 68 152 373 555 559 618 670 701 621 219 -451 -1137 -1493 -1166 SQ 20240310T125717.5Z 8835.539786 31 1 21.84 2 88.43 95.30 92.47 94.63 0.00 1 0.00 1 0 22 7.522e-03 7.435e-03 2.014e-04 2.010e-04 1.278585e+04 1.414588e+01 8.477773e+02 -6.000000e+00 4.288092e+02 284.32 -2.00 20.00 -2.00 505.40 0.00e+00 2.822893e-03 5.647479e-06 1.673346e-04 -6.000000e+00 2.130701e-04 284.32 -2.00 20.00 -2.00 500.97 0.00e+00 1.063058e+00 3.905556e-03 9.025097e-02 -6.000000e+00 1.495070e-01 226.68 -2.00 3.25 -2.00 502.49 0.00e+00 17.211 0.063 489.00 513.00 1 2.0591e+00 2.9957e-04 2.7083e-02 -6.0000e+00 1.1491e-02 -1.5897e-02 7.4557e-05 2.5586e-03 -6.0000e+00 2.9463e-03 1.9743e-02 1.2808e-03 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